44results about How to "High quality yield" patented technology

The invention discloses a method for preparing levulinic acid and furfural by hydrolyzing biomass. The method comprises the following steps of firstly, mixing the biomass with a catalyst, introducing water vapor to generate primary hydrolysis, discharging a gaseous phase of the primary hydrolysis and condensing to obtain an aqueous solution containing the furfural; secondly, introducing water vapor into the biomass subjected to primary hydrolysis to perform secondary hydrolysis, and discharging a gaseous phase of the secondary hydrolysis; thirdly, performing temperature and pressure reduction on the gaseous phase subjected to the secondary hydrolysis, enabling the gaseous phase to enter into a reaction kettle filled with the biomass, generating primary hydrolysis, discharging the gaseous phase of the primary hydrolysis, and condensing the gaseous phase to obtain an aqueous solution containing the furfural and the levulinic acid; fourthly, supplementing the catalyst into the reaction still in the third step, introducing water vapor for secondary hydrolysis, and discharging a gaseous phase of the secondary hydrolysis; fifthly, repeating the third step and the fourth step; sixthly, purifying and separating the aqueous solution in the first step from the aqueous solution in the third step to obtain the levulinic acid and the furfural. According to the method disclosed by the invention, the yields of the levulinic acid and the furfural are increased; the yield of the furfural reaches 60 percent or above 60 percent, and the yield of the levulinic acid reaches 50 percent or above 50 percent.

The invention relates to a bimetal-modified nano-HZSM-5 molecular sieve catalyst as well as a preparation method and application thereof. An HZSM- molecular sieve catalyst is taken as a carrier and isloaded with metal Zn and metal A, wherein the metal A is selected from any of Ga, Cd, Cu and La. By performing bimetal modification on the HZSM-5 molecular sieve catalyst, the bimetal modified nano-HZSM-5 molecular sieve catalyst which is more suitable for a methanol aromatization reaction is obtained; HZSM-5 is independently synthesized, compared with the prior art, the aspects of the formula ofraw materials, a synthesis method and a process are improved, and the HZSM-5 molecular sieve catalyst which is better than the existing HZSM-5 is obtained; the modified molecular sieve catalyst is moderate in specific surface area and is more suitable for the methanol aromatization reaction.

The invention discloses recombinant escherichia coli in which a phenazine-1-carboxylic acid synthetic gene is introduced and also discloses a construction method of the recombinant escherichia coli and application of the recombinant escherichia coli in succinic acid preparation. The succinic acid yield and conversion rate of the recombinant strain E. coli-phz are obviously higher than those of anoriginal strain E.coli K12(DeltaldhA, DeltapflB, DeltaptsG), fumaric acid is used as a carbon source, and compared with the original strain E.coli K12(DeltaldhA, DeltapflB, DeltaptsG), the succinic acid yield of the recombinant strain E. coli-phz is improved by 68%. Glucose is used as a carbon source, and compared with the original strain E.coli K12(DeltaldhA, DeltapflB, DeltaptsG), the mass yieldof the recombinant strain E. coli-phz is improved by 26%.

The invention relates to a method for controlling the addition amount of a VPO (vanadium phosphorus oxide) catalyst assistant water in the MAH (maleic anhydride) preparation process. The method is characterized in that a water control valve connected to a shell-and-tube fixed bed reactor for preparing MAH is connected with an atmospheric thermohygrograph and a calculating module, the atmospheric thermohygrograph measures the ambient temperature T and the relative humidity RH, measured values are input into the calculating module, and the addition amount of the assistant water is calculated according to a formula and can be accurately controlled. The method realizes the accurate control of the addition amount of the catalyst bed assistant water to make the humidity of a butane mixed gas entering the reactor keep constant and be not affected by the humiture, improves the selectivity of a catalyst by 2.1%, improves the yield by 2.4%, and avoids uneven temperature distribution of the reactor, caused by concentration of phosphide at the feed inlet of the reactor due to too low amount of water, and increase of byproducts, caused by the excessive amount of the water.

The invention discloses a method for constructing the efficient production of microbial oil strains by utilizing metabolic engineering strategies and application thereof. The invention relates to overexpression of acetyltransferase phosphate in oleaginous yeasts. The method can enhance the supply of oil synthesis precursor acetyl coenzymes A, improve the oil yield and effectively improve the economy of microbial oil.

The invention relates to a crystallizing method for preparing high-purity 4-bromomethyl-2-cyanobiphenyl. The crystallizing method comprises the following steps: adding a 4-bromomethyl-2-cyanobiphenyl crude product in a solvent according to 0.4-0.65 g/mL of the solution concentration, stirring and dissolving the crude product at 40-60 DEG C, carrying out cooling and sterilization, reducing the temperature to 5-20 DEG C, keeping the temperature constant for 30-60 minutes, adding an elution agent to carry out solvent dilution crystallization, filtering, washing and drying the crystal mush to obtain the 4-bromomethyl-2-cyanobiphenyl product. The product color is purely white; the high performance liquid chromatography purity is up to 99.5%; the crystal granularity is large, the main granularity is about 100 microns, and the granularity distribution is uniform. During crystallization, the once through yield is high, so that the post treatment cost is saved. The method can provide the high-quality raw material for follow-up synthesis of sartan drug products, reduces unnecessary side reaction during the synthetic process, improves the quality indexes such as impurity and yield of the sartan drug products, and has good industrial application prospect.

The invention relates to an injection molding technology for recycled polypropylene. The injection molding technology comprises seven steps. The injection molding technology for recycled polypropyleneis simple and convenient, waste polypropylene is adopted to produce polypropylene products, wasting is reduced, and the situation that waste polypropylene is thrown all around, and the environment ispolluted is avoided; and the polypropylene products are unified and reliable in quality, high in quality and yield, excellent in performance and not prone to being fragile.

The invention discloses a method for assisting in processing silicon powder and metal powder by using thermal plasma under the condition of micro negative pressure so as to promote continuous reaction of the silicon powder and the metal powder to generate metal silicide powder. The invention also relates to a method for preparing disilane by using the metal silicide powder as a raw material to react with strong acid in a specific solvent, and a reaction system for realizing the method. According to the preparation method, silicon powder and metal powder are instantly melted and vaporized in a plasma core area by utilizing the high energy density of hot plasma, and then are rapidly cooled to finish alloying and chemical reaction and form nanoscale metal silicide powder; under the condition of micro-negative pressure, the formed nano-scale metal silicide powder reacts with strong acid in a specific solvent to generate silane series product gas, and the proportion of disilane is obviously higher than that of disilane in the existing production process; meanwhile, the whole technological process is carried out under the micro-negative pressure condition, operation is safe and easy to control, and continuous production can be achieved.

The invention relates to a method for preparing 4-alkylphenol from lignin or lignin oil by a one-pot method without an external hydrogen source. According to the method, lignin or lignin oil is used as a raw material, and under the action of a metal catalyst loaded by a nickel-aluminum composite material, self-reforming hydrogen production and hydrogenolysis are carried out to obtain 4-alkylphenol. With birch organic lignin and lignin oil as raw materials, the yields of 4-alkylphenol are as high as 17wt% and 25wt% respectively. The lignin is obtained by taking biomass containing a lignin component as a raw material and adopting an acidolysis or biological enzyme depolymerization method. The lignin oil is obtained by taking biomass containing lignin component as a raw material through a hydrogenolysis depolymerization method. Raw materials are wide in source and low in cost. Meanwhile, the process does not need an additional hydrogen source, and is single in product, few in by-product,easy to separate and green in solvent. Besides, the phenolic product involved in the invention is an important chemical product, is suitable for the polyester industry, and has a wide application prospect.