The invention discloses a method for co-
processing chromium-containing aluminum mud and electrolytic aluminum overhaul
slag, which comprises the following steps of: oxidizing
cyanide in the finely ground overhaul
slag into
carbon dioxide and
nitrogen by using
hexavalent chromium with strong oxidizing property in the
chromium-containing aluminum mud under an acidic condition, and adding
calcium oxide into decyanated
slag to obtain trivalent
chromium precipitate and insoluble villiaumite; and chloridizing the washed and dried
precipitation slag by adopting aluminum
chloride, carrying out multi-stage condensation separation and purification on the chloridized
flue gas to respectively obtain
ferric trichloride and
aluminum trichloride, carrying out heat exchange and washing on the chloridized slag to obtain a chromium trichloride solution, and carrying out alkaline leaching to obtain
sodium aluminate and
tailings. According to the method, oxidation-reduction characteristics of the chromium-containing aluminum mud and the overhaul slag are utilized to cooperate with detoxification, a carbon-based wave-absorbing material in the overhaul slag is subjected to
microwave heating for chlorination
recovery of valuable elements, the heating rate is high, heating is uniform, the reaction efficiency is high, harmless treatment of the two hazardous wastes is achieved, the valuable elements such as chromium and aluminum in the hazardous wastes are effectively recovered, and the method is suitable for industrial production. And the energy
utilization rate is high.