The invention relates to the technical field of bonding resins, and concretely relates to a preparation method of a low-VOC bonding resin. The preparation method comprises the following steps: preparing a primary bonding resin from a matrix resin, a graft monomer, an initiator, a tackifying resin and a functional assistant through a double screw extruder, feeding the primary bonding resin into a supercritical device, and removing VOCs from the primary bonding resin by a purifying solvent to obtain the low-VOC bonding resin, wherein the purifying solvent is one or more of carbon dioxide, 1,1,1,2-tetrachloroethane, methane, ethane, propane, ethylene and propylene. The supercritical fluid purification of the primary bonding resin in the method greatly reduces the content of the VOCs in orderto effectively improve the use performance and the safety performance of an automobile plastic fuel tank; and the preparation method has the advantages of environmentally-friendly and efficient preparation process, and simple process route, and the tackifying resin and the functional assistant can improve the flowability, the adhesion and the aging resistance of the bonding resin.