The invention belongs to the technical field of preparation of a
flame retardant, and particularly relates to a preparation method of modified
aluminium hypophosphite. The preparation method comprises the following steps: dissolving
sodium hypophosphite into water to prepare
sodium hypophosphite solution, adding
phosphate, and stirring at high speed and dissolving; dissolving aluminum
chloride and
polyethylene glycol into water to prepare aluminum
chloride solution; stirring at 10-30 DEG C, normal pressure and high speed, adding the aluminum
chloride solution into the
sodium hypophosphite solution, slowly stirring and reacting to obtain turbid solution containing aluminum hypophosphite; pumping the turbid solution into a centrifugal
machine for centrifuging, washing with water, and
drying to obtain the modified
aluminium hypophosphite. The prepared modified
aluminium hypophosphite can be excellently dispersed into a high-molecular material, the mechanical performance and
flame-retardant property of the high-molecular material can be obviously improved, and the electrical property of resin can be maintained; the preparation is simple in technology, temperature rise and regulation of pH value of the reaction solution are not needed, the yield can achieve up to 98.0%, and the modified aluminium hypophosphite is
pollution-free and environmental friendly.