The invention discloses stainless steel passivation liquid and a passivation technology thereof. The stainless steel passivation liquid comprises, by weight, 40-50 parts of inorganic acid, 5-15 parts of hydrogen peroxide, 8-12 parts of cyclohexanol, 4-8 parts of 2-ethylhexyl epoxystearate, 4-6 parts of acetic anhydride, 2-4 parts of polyethyleneimine, 3-5 parts of carbomer resin, 2-4 parts of a penetrating agent, 1-3 parts of corrosion inhibitor and 10-20 parts of organic filler. The passivation technology of the stainless steel passivation liquid comprises polishing and rust removal, surface oil removal, first-time water washing, sand blasting, acid pickling passivation, second-time water washing and surface drying. The stainless steel passivation liquid is little in perniciousness, good in passivation effect and not prone to generating corrosive damage on a stainless steel product. The passivation technology is simple, operation is easy, the production cost is low, pollution to the environment is weak, and the standard of green and environment friendliness is met.