The invention discloses an SPE (Solid Polymer Electrolyte) electrolysis system used for tritium concentration. The electrolysis system comprises an electrolytic tank system, a tritiated water supply system, a gas-liquid separator, a tritiated water collection system, a hydrogen drying system, an oxygen drying system, a hydrogen collection system, a product oxygen collection and storage tank, a condensation system and a detection and control system. The invention further provides a realization method for the SPE electrolysis system used for tritium concentration. The electrolysis system can meet all process demands of aqueous phase tritium concentration, wherein the processes include a tritiated water circulating concentration process, a hydrogen leakage emergency power-off process, a molecular sieve drying bed continuous treatment process and the like. Meanwhile, due to the tritiated water circulating concentration, the tritiated water concentration can be quantitatively controlled, so that the tritium concentration efficiency is greatly improved and a large amount of tritium-poor hydrogen is obtained.