The invention discloses a water-base fluorocarbon imitation marble exterior wall paint, which comprises a white paint and more than one color paint, wherein the white paint comprises the following components in portion by weight: 12 to 20 portions of water-base fluorocarbon emulsion, 0.1 to 1 portion of cellulose, 0.1 to 1 portion of nano silicate, 0.1 to 1 portion of dispersing agent, 0.1 to 1 portion of pH conditioning agent, 0.1 to 1 portion of defoaming agent, 1.0 to 2.0 portions of film-forming agent, 1.0 to 2.5 portions of antiseptic mildew inhibitor, 1.0 to 2.0 portions of antifreezingagent, 10 to 12 portions of titanium pigment, 20 to 25 portions of calcium carbonate, 2.0 to 5.0 portions of barium sulfate, and 35 to 40 portions of water. The color paint is prepared by adding 0.01to 0.03 folds of color pigment paste on the basis of the white paint and stirring the mixture evenly. The invention also discloses a method for preparing the water-base fluorocarbon imitation marble exterior wall paint and a method for spraying an exterior wall with imitation marble effects by using the paint; and the water-base fluorocarbon imitation marble exterior wall paint keeps the same decorative effect as natural marbles, and simultaneously keeps the characteristics of consistent overall colors, energy saving, environmental protection, convenient construction and easy face lifting, andcan completely replace the natural marbles applied to the exterior wall and save two thirds of the cost at present.