The invention discloses a method for in situ fixation of
vanadium ore polluted soil by modified
charcoal and belongs to the technical field of soil in-situ remediation. The method comprises the following steps: 1, after harvested plants in
vanadium ore polluted sites are pretreated, the pretreated plants are subjected to
pyrolysis at 450-550 DEG C under the
nitrogen protection, the
pyrolysis time lasts for 30 min, then
nitrogen is introduced continuously, the mixture I is cooled to
room temperature to obtain
solid particles, and the
solid particles are cleaned and then dried at 60 DEG C to obtain
charcoal particles for standby application; 2,
calcium hydrophosphate is dissolved in dilute
nitric acid with the
mass concentration being 5%,
calcium hydrophosphate and the dilute
nitric acid are sufficiently mixed according to the the
molar ratio of (1-3):1; 3, the
charcoal particles are added in a
calcium hydrophosphate-
nitric acid mixing
system according to the fact that 1 g of charcoal particles are added into 40-60 ml of calcium hydrophosphate-nitric acid mixing
system, and ultrasonic treatment is performed for 20 min; 4, the mixture II is filtered, and the filtered substance is cleaned and dried at 55 DEG C to obtain modified charcoal; 5, the modified charcoal is sufficiently mixed with soil samples at the
mass ratio of 1%-3%, the soil
field capacity is kept to be 60%, and maintenance is carried out for 30 days. A soil leaching experiment result shows that compared with the leaching toxicities of
heavy metals namely V, Cr and Pb of soil which is not fixed by modified charcoal, the leaching toxicities of
heavy metals namely V, Cr and Pb of the soil fixed by modified charcoal are respectively reduced by 70%, 50% and 35%.