17 results about "Cobalt atom" patented technology

The invention discloses a method for self-reconstructing Co9S8-Ni3S2 / NCF into NixCo3-xO4-Ov-SO4 < 2-> / NCF to enhance oxygen evolution reaction activity and stability, a self-reconstruction strategy of Co9S8-Ni3S2 / NCF is adopted to prepare partially nickel-doped cobalt spinel (NixCo3-xO4-Ov-SO4 < 2->), compared with the cobalt spinel, the material can enhance the adsorption capacity of leaching SO4 < 2-> from an initial phase so as to realize overall water decomposition for more than 600 hours, and the performance of the material is improved. The current density is 1000mA cm <-2 >, and the catalyst has excellent activity. Co9S8-Ni3S2 / NCF is converted into SO4 < 2-> adsorbed nickel-doped SO4 < 2-> cobalt spinel, and the oxygen evolution reaction (OER) stability of 1000 hours is realized under the condition of 1000 mA cm <-2 >. In-situ Raman spectroscopy and XPS results show that part of nickel atoms replace cobalt atoms to enhance the SO4 < 2-> adsorption capacity of a reconstructed surface, so that formation of high-density active sites is promoted, and interface electron transfer under high current density is accelerated.

The invention discloses a C3N4-based diatomic cobalt catalyst and a preparation method and application thereof, and the catalyst is uniformly dispersed on the surface of a C3N4 carrier in the form of cobalt atom pairs to form a diatomic active center with clear Co-Co coordination. The preparation method comprises the following steps: reacting cobalt salt with 2, 2 '-bipyridine and oxalic acid to generate a cobalt dimer complex, mixing the cobalt dimer complex with a C3N4 dispersion liquid, stirring, evaporating, and calcining in an air atmosphere to obtain a final product. Adjacent cobalt atoms are accurately anchored through a nitrogen coordination environment of C3N4, and diatomic sites with stable structures and electron coordination are constructed on the atomic scale. Structural characterization results prove that cobalt atoms are dispersed in a diatomic form and do not agglomerate. The catalyst shows excellent performance in electrocatalytic oxygen reduction reaction, the current density and H2O2 yield of the catalyst are obviously higher than those of monatomic cobalt and cobalt nanoparticle contrast samples, and the catalyst shows high activity, high selectivity and good structural stability.

An interconnect structure and method for forming the same include forming a recess in a dielectric layer and conformally depositing a barrier layer in the recess. A cobalt-implanted ruthenium liner is formed over the barrier layer. A cobalt-containing ruthenium liner is formed by stacking a second liner over the first liner, the first liner being located over the barrier layer. The first liner comprises ruthenium, while the second liner comprises cobalt. Cobalt atoms migrate from the second liner to the first liner, forming a cobalt-implanted ruthenium liner. A conductive material is deposited over the cobalt-implanted ruthenium liner to fill the recess, followed by a capping layer made of cobalt.

The invention provides a preparation method of a NiFe-LDH surface immobilized cobalt atom modified alpha-Fe2O3 photo-anode catalyst. The preparation method comprises the following steps: putting an FTO / beta-FeOOH photo-electrode into a muffle furnace, and annealing to obtain an FTO / alpha-Fe2O3 photo-electrode; the preparation method comprises the following steps: dissolving nickel nitrate hexahydrate, ferric nitrate nonahydrate, ammonium fluoride and urea in a mixed solvent of ethylene glycol and N 'N-dimethylformamide to obtain a precursor solution; placing the FTO / alpha-Fe2O3 photoelectrode with the conductive surface upward in a hydrothermal reactor, injecting the precursor solution, and performing a reaction after sealing to obtain a NiFe-LDH modified alpha-Fe2O3 photoanode material; and adding cobalt chloride hexahydrate into a sodium borohydride solution, stirring, injecting into a hydrothermal reactor, and carrying out sealed reaction on the cobalt chloride hexahydrate and the NiFe-LDH modified alpha-Fe2O3 photo-anode material to obtain the NiFe-LDH surface immobilized cobalt atom modified alpha-Fe2O3 photo-anode catalyst. The FTO / alpha-Fe2O3 photoelectrode disclosed by the invention is subjected to high-temperature annealing to obtain a more stable crystal form; the NiFe-LDH surface immobilized cobalt atom modified alpha-Fe2O3 photo-anode catalyst is prepared by adopting a hydrothermal method, and the preparation method is simple in process, low in cost, good in repeatability, uniform in size and consistent in morphology.

Methods for forming a connection structure, including: Forming a recess (108) within a dielectric layer (106); shape-adapted deposition of a barrier layer (110) within the recess; Forming a ruthenium lining with cobalt infusion over the barrier layer, the cobalt-containing ruthenium lining comprising: a first lining (120) directly above the barrier layer, wherein the first lining comprises ruthenium; a second lining (130) directly above the first lining, the second lining comprising cobalt; and a third lining (240) directly above the second lining, wherein the third lining contains ruthenium, wherein the ruthenium lining with cobalt infusion is formed by migration of cobalt atoms from the second lining into the first and the third lining; Deposition of a conductive material (242) over the ruthenium lining with cobalt infusion to fill the recess; and Forming a cover layer (256) over an upper surface of the conductive material, wherein the cover layer comprises cobalt.

The application belongs to the technical field of catalytic materials, and discloses a preparation method and application of a double cobalt atom catalyst. The target catalyst Co2-DAC is prepared through the steps of mixed liquid preparation, preheating dropwise adding, constant temperature refluxing and post-treatment purifying, and the reaction condition is mild, inert gas protection is not needed, the process is simple, and the cost is relatively low. The prepared catalyst takes double cobalt atoms as the active center, the atoms are uniformly dispersed, and the structure is stable. With the synergistic effect of the double active sites, the charge transport and CO2 activation performance can be improved, the catalyst shows high activity and stability in the photocatalytic CO2 reduction reaction, can effectively convert CO2 into high value-added products, and provides guidance for designing double atom catalysts with high photocatalytic CO2 reduction activity.

Provided is a cemented carbide comprising a plurality of tungsten carbide particles and a binder phase, the cemented carbide containing the tungsten carbide particles and the binder phase in a total amount of 89-100 vol%, and the binder phase in an amount of 0.5-25 vol%, wherein: the binder phase contains cobalt in an amount of 40 mass% or greater, and further contains at least one first element selected from the group consisting of silicon, phosphorus, germanium, tin, rhenium, ruthenium, osmium, iridium, and platinum; and in a rectangular measurement region, which is provided in a TEM-HAADF image obtained by observing a (110) plane of the cobalt having an fcc structure by a magnification of 5 million times using an atomic resolution transmission electron microscope, and in which 31 cobalt atoms are contained in a first direction and 5 to 10 cobalt atoms are contained in a second direction orthogonal to the first direction, a frequency of mismatch of an atomic array of the cobalt atoms is from 8% to 30.0%.

A cemented carbide including tungsten carbide particles and a binder phase, in which the cemented carbide includes 89 vol % to 100 vol % of the tungsten carbide particles and the binder phase in total, the cemented carbide includes 0.5 vol % to 25 vol % of the binder phase; the binder phase includes 40 mass % or more of cobalt, the binder phase further includes at least one first element selected from the group consisting of silicon, phosphorus, germanium, tin, rhenium, ruthenium, osmium, iridium, and platinum, and a frequency of inconsistency in atomic arrangements of cobalt atoms in a rectangular measurement region provided in a TEM-HAADF image obtained by observing a (110) plane of the cobalt having an fcc structure using an atomic resolution transmission electron microscope, in which the rectangular measurement region contains 31 cobalt atoms in a first direction and 5 to 10 cobalt atoms in a second direction, is 8% or more and 30.0% or less.

A cubic boron nitride sintered material includes: 70 volume % or more and 99 volume % or less of a cubic boron nitride grains; and a binder, wherein the binder includes a first compound including chromium, cobalt and carbon, tungsten carbide, cobalt, and aluminum, and in the first compound, a ratio NCr / (NCr+NCo) of the number NCr of atoms of the chromium to a sum of the number NCr of the atoms of the chromium and the number NCo of atoms of the cobalt is 0.10 or more and 0.90 or less.

A cubic boron nitride sintered body comprising cubic boron nitride particles of 70 volume % or more and 99 volume % or less, and a binder, the binder including a first compound containing chromium, cobalt and carbon, tungsten carbide, cobalt and aluminum, and wherein the number of chromium atoms in the first compound is N Cr and the number of cobalt atoms, N Co The number of chromium atoms, N, relative to the total Cr Proportion of N Cr / (N Cr +N Co ) is a cubic boron nitride sintered body having a modulus of elasticity of 0.10 or more and 0.90 or less.

The present invention belongs to the technical field of lithium ion batteries, and specifically relates to a cobalt-containing two-dimensional conjugated phthalocyanine framework and a preparation method and application thereof, comprising the following steps: using 1,2,4,5-tetracyanobenzene and a soluble cobalt salt as raw materials, and 1,8-diazacyclo (5,4,0) undec-7-ene as a catalyst, a solvothermal reaction is carried out in an organic solvent to obtain the cobalt-containing two-dimensional conjugated phthalocyanine framework. The present invention develops a two-dimensional conjugated phthalocyanine framework containing a single cobalt atom as a new type of artificial solid electrolyte interface. Due to the Lewis acid activity of the Co metal site and the strong electron absorption characteristics of the cyano group, a large amount of charge is transferred to the CPF framework, which greatly enhances the Li + adsorption and regulate Li + distribution toward dendrite-free Li metal batteries, outperforming most reported SEI films.

Provided is a cubic boron nitride sintered compact comprising cubic boron nitride particles in the amount of 70-99 vol%, and a binder. The binder comprises: a first compound containing chromium, cobalt, and carbon; tungsten carbide; cobalt; and aluminum. In the first compound, the ratio NCr / (NCr+NCo) of the number of chromium atoms NCr to the total of the number of chromium atoms NCr and the number of cobalt atoms NCo is 0.10-0.90.

To provide a positive electrode active material for a secondary battery having high capacity and excellent charge / discharge cycle characteristics.SOLUTION: A positive electrode active material includes an aggregate of particles including a first particle group and a second particle group, the aggregate of particles contains lithium, cobalt, nickel, aluminum, magnesium, oxygen, and fluorine, when the number of atoms of cobalt contained in the aggregate of particles is 100, the number of atoms of nickel is 0.05 or more and 2 or less, the number of atoms of aluminum is 0.05 or more and 2 or less, and the number of atoms of magnesium is 0.1 or more and 6 or less, and when the aggregate of particles is subjected to particle size distribution measurement by a laser diffraction / scattering method, the first particle group has a first peak. The second particle group has a second peak, the first peak has a maximum value in a range of 2 μm or more and 4 μm or less, and the second peak has a maximum value in a range of 9 μm or more and 25 μm or less.SELECTED DRAWING: Figure 26

This coated plated steel sheet is provided with a steel sheet, a plating layer, and a protective layer. The plating layer contains aluminum, zinc, and magnesium. The average value of the ratio of the atomic concentration of aluminum to the total of the atomic concentration of magnesium and the atomic concentration of zinc in the outermost layer at the depth of 5 nm in the plating layer is 0.40 to 1.50 inclusive. The ratio of the mass of a resin (A1) in the protective layer to the total mass of the protective layer is 0.6 or more. The ratio of the mass of silicon atoms in terms of SiO2 in the protective layer to the total mass of the protective layer is 0.07 to 0.19 inclusive. The ratio of the mass of phosphorus atoms in the protective layer to the total mass of the protective layer is 0.011 to 0.075 inclusive. The ratio of the mass of cobalt atoms in the protective layer to the total mass of the protective layer is 0.0015 to 0.02 inclusive.

The present invention discloses a method for self-reconstruction of Co9S8-Ni3S2 / NCF into Ni x Co 3‑x O4‑Ov‑SO4 2‑ / NCF enhances the activity and stability of oxygen evolution reaction, and adopts the self-reconstruction strategy of Co9S8‑Ni3S2 / NCF to prepare partially nickel-doped cobalt spinel (Ni x Co 3‑x O4‑Ov‑SO4 2‑ ), which can enhance the leaching of SO4 from the initial phase compared to cobalt spinel 2‑ The adsorption capacity was improved to achieve an overall water splitting time of more than 600 h at a current density of 1000 mA cm ‑2 , and has excellent activity. Co9S8‑Ni3S2 / NCF is transformed into SO4 2‑ Adsorbed nickel-doped SO4 2‑ Cobalt spinel, at 1000mA cm ‑2 Under these conditions, the oxygen evolution reaction (OER) stability of 1000 hours was achieved. In situ Raman spectroscopy and XPS results show that the partial substitution of nickel atoms for cobalt atoms enhances the SO4 2‑ The adsorption capacity is improved, thereby promoting the formation of high-density active sites and accelerating the interfacial electron transfer at high current density.

The invention provides a preparation method of an α-Fe2O3 photoanode catalyst modified with cobalt atoms immobilized on the surface of NiFe-LDH. The method comprises the following steps: placing an FTO / β-FeOOH photoelectrode in a muffle furnace for annealing to obtain an FTO / α-Fe2O3 photoelectrode; dissolving nickel nitrate hexahydrate, ferric nitrate nonahydrate, ammonium fluoride and urea in a mixed solvent of ethylene glycol and N'N-dimethylformamide to obtain a precursor solution; placing the FTO / α-Fe2O3 photoelectrode in a hydrothermal reactor with its conductive surface facing upward, injecting the precursor solution, sealing the reactor and reacting to obtain an α-Fe2O3 photoanode material modified with NiFe-LDH; and adding cobalt chloride hexahydrate into a sodium borohydride solution, stirring the solution, and injecting the solution into the hydrothermal reactor to react with the NiFe-LDH modified α-Fe2O3 photoanode material to obtain an α-Fe2O3 photoanode catalyst modified with cobalt atoms immobilized on the surface of NiFe-LDH. The FTO / α-Fe2O3 photoelectrode of the present invention obtains a more stable crystal form after high-temperature annealing; the present invention adopts a hydrothermal method to prepare the α-Fe2O3 photoanode catalyst modified with cobalt atoms immobilized on the surface of NiFe-LDH. The preparation method is simple, low-cost, reproducible, and has uniform size and consistent morphology.

The application discloses a preparation method of dicarbonyl cyclopentadienyl cobalt, which uses octacarbonyldicobalt, elemental iodine and cyclopentadienyl alkali metal salt as core reaction raw materials to prepare the dicarbonyl cyclopentadienyl cobalt. By introducing the elemental iodine and adopting the feeding sequence of first adding the cyclopentadienyl alkali metal salt and then adding the elemental iodine, the target product can be prepared under the conditions of low-temperature feeding and room-temperature reaction. The method not only avoids directly using the chemically active cyclopentadiene monomer, but also significantly reduces or avoids the generation of a cobalt-containing byproduct, reduces the diversion of part of the cobalt raw material to the byproduct side, improves the cobalt atom utilization rate and process repeatability, and is more convenient for post-processing, so that the target product with high purity can be obtained.