The invention relates to a light-splitting spectrum greenhouse film which comprises an inner film, a middle film and an outer film, wherein the master batch of the outer film comprises 2.8-3.4 parts of optical stabilizer, 0.8-1.1 part sof antioxidant, 0.8-1.2 parts of polyethylene wax, 0.8-1.2 parts of light-splitting assistant and 48-57 parts of polyethylene-vinyl acetate copolymer; the light-splitting assistant is the mixture of La<3+>, Y<3+> and Gd3<+>; the ratio by weight of the rare earth ions La<3+>, Y<3+> and Gd<3+> is (4-5):(8-9):(5-6); the ingredients comprise EVA (ethylene-vinyl acetate copolymer), LDPE (low-density polyethylene) and LLDPE (linear low density polyethylene); the ratio of parts by weight of the EVA, LDPE and LLDPE of the outer film and the master batch is (23-27):(23-27):(73-77):(11-17); the Eu<3+> ions in the rare earth assistant are partly displaced by non-fluorescent rare ions La<3+>, Y<3+> and Gd<3+> to form a heteronuclear multinuclear coordination compound, so as to strengthen the luminous intensity and overcome acute peaks; the half-width of the emission spectrum is 70nm; the excitation wavelength of the light-splitting spectrum greenhouse film is 290-390nm, the maximum wavelength is 332nm, and the emission spectrum is between 580-660nm; ultraviolet lights in solar radiation can be absorbed and transformed into red orange lights with large emission brightness and good colour purity; and the light conversion rate reaches 98%.