32 results about "Ni oxide" patented technology

A multilayer electronic component includes a body including a dielectric layer and an internal electrode alternately disposed with the dielectric layer in a first direction; an external electrode disposed outside the body; and an oxide layer disposed between the body and the external electrode and connecting the internal electrode and the external electrode, wherein the oxide layer includes one or more of an Ni oxide and a Cu oxide.

The invention discloses a preparation method of an Mg / Al co-doped modified layered cobalt-free lithium-rich manganese-based positive electrode material, and belongs to the technical field of lithium ion batteries. The method comprises the following steps: adding excessive Li2CO3, Mn oxide, Ni oxide, Mg compound and Al compound into a ball milling tank of an organic solvent, and fully mixing through mechanical ball milling to obtain uniform mixed powder; drying the mixed powder at 80 DEG C for 3-10 hours; the second-stage roasting temperature is 700-900 DEG C, the second-stage roasting time is 10-20 hours, and the Mg / Al co-doped modified layered cobalt-free lithium-rich manganese-based positive electrode material is obtained. The preparation method comprises the following steps: uniformly mixing the dried powder again, roasting at the room temperature to 350-500 DEG C, preserving heat for 3-6 hours, and roasting at the second-stage roasting temperature of 700-900 DEG C for 10-20 hours. The Mg / Al co-doped layered cobalt-free lithium-rich manganese-based positive electrode material prepared by a high-temperature solid-phase method is subjected to morphology analysis, and it is observed that sample particles are uniform in distribution and appropriate in particle size, which indicates that the Mg / Al co-doped layered cobalt-free lithium-rich manganese-based positive electrode material possibly has good electrochemical performance. Al < 3 + > doping can effectively improve the electrochemical performance of the cobalt-free lithium-rich manganese-based positive electrode material.

Provided are a dielectric powder composition for multilayer ceramic capacitors. The dielectric powder composition includes 93 to 98.5 wt % of a main ingredient composed of dielectric base material powder, 1.0 to 5.0 wt % of a first sub-ingredient including glass powder coated on an outer periphery of the dielectric base material powder to form a core-shell structure, and 0.5 to 2.0 wt % of a second sub-ingredient made of a transition metal oxide mixed with the core-shell structure powder, wherein the main ingredient is non-stoichiometrically represented as [(BaxCaySr1-x-y)O]m[(TizZr1-z)O2](where x: 0.22 to 0.42, y: 0.10 to 0.35, z: 0.03 to 0.08, and m ranges from 0.85 to 1.05), the first sub-ingredient includes an alkaline earth metal compound including (Ba, Sr, Ca), SnO2, B2O3 and SiO2, and the second sub-ingredient includes at least two selected from the group consisting of manganese oxide (Mn3O4), tungsten oxide (WO3), and aluminum oxide (Al2O3).

The invention relates to an ultra black surface (1) comprising, a substrate having the ultra black surface and formed by an Al-base (2) made of an aluminium (alloy), coated with a layer of a NiP or NiB alloy, the ultra-black surface is structured with a multiscale micro and nanotexture formed by a USP-laser treatment, wherein the multiscale micro and nano texture comprises, a microtexture comprising protrusions (4p) arranged side-by-side separated from one another by grooves (4g) defining a height (h) not lower than the layer thickness, wherein a thickness to height ratio (t_Ni / h) is preferably comprised between 30 and 80%, and a nanotexture comprising a nanostructured layer (5) coating the surfaces of the protrusions and comprising Al-Ni oxides with varying values of a molar Al to Ni ratio, and wherein, the ultra-black surface has an absorbance of at least 95% over a wavelength () extending from 300 nm to 20 µm, and an emissivity of at least 0,95 in a wavelength range of 3 to at least 35 µm.

Method for preparing a precursor material for a Li-containing cathode active material for a battery, wherein the method comprises a spray pyrolysis step in which a metal oxide is produced by decomposition in a heated chamber of droplets of an aqueous solution, wherein either the metal oxide is a mixed metal oxide comprising the element Ni and one or both of the elements Co and Mn and the aqueous solution is a mixed solution of salts of Ni and of Co and / or Mn or the metal oxide is a Ni oxide and the aqueous solution is a solution of a salt of Ni, characterised in that the method comprises a spray drying step in which an aqueous slurry comprising said metal oxide is spray dried to form said precursor material.

[Problem] To provide coated particles that, when used as a positive electrode active material for a non-aqueous electrolyte secondary battery, allow a non-aqueous electrolyte secondary battery in which these particles are used to exhibit excellent charge / discharge capacity and cycle characteristics. Coated particles according to the present disclosure have: a lithium metal composite oxide containing at least lithium and nickel in the form of primary particles or secondary particles; a first layer containing nickel (II) oxide on at least a part of the surface of the lithium metal composite oxide; and a second layer comprising an oxide on at least a portion of a surface of the first layer, the oxide containing lithium and one or more selected from the group consisting of boron, phosphorus, and sulfur.

The present application proposes a battery cell, a battery device, and an electrical device. The battery cell includes a positive electrode plate, the positive electrode plate includes a positive electrode film layer, the positive electrode film layer includes a lithium-containing phosphate and a lithium-supplementing additive, the lithium-supplementing additive includes at least one of an Fe oxide or a Ni oxide; a negative electrode plate; and an electrolyte, the electrolyte including a chain carboxylate, the electrolyte having a conductivity of 10mS / cm-18mS / cm at room temperature. Thus, by increasing the conductivity of the electrolyte, the fast-charging performance of the battery cell is improved. At the same time, by adding at least one of an Fe oxide or a Ni oxide to the positive electrode film layer, the stability of the negative electrode electrolyte interface film (SEI film) is improved, the gas production of the battery cell is reduced, and while improving the fast-charging performance of the battery cell, the high-temperature cycle life of the battery cell is also improved.

An electronic device includes an element body. The element body includes at least two internal electrode layers and a dielectric layer laminated between the internal electrode layers. Ni oxide particles exist at a boundary between the internal electrode layers and the dielectric layer. The dielectric layer is in contact with the internal electrode layers at first and second boundaries. The dielectric layer includes a first dielectric large particle and a second dielectric large particle. The first dielectric large particle is in contact with at least one of the Ni oxide particles existing at the first boundary and in contact with one of the internal electrode layers at the second boundary. The second dielectric large particle is in contact with at least one of the internal electrode layers at the first boundary and in contact with at least one of the Ni oxide particles existing at the second boundary.

Disclosed is an engineered coating material decorated on a conductive carbon, comprising: a coating material disposed on a surface of the conductive carbon with a partial coverage or full coverage, wherein the coating material comprises at least one material selected from a group comprising: AlOx, TiOx, SnOx, ZnOx, NbOx, TiNbxOy, AlPxOy, MgOx, LiNbxOy, BOx, CeOx, LiAlxOy, Sn(PO4)x, ZrOx, MgAlxOy, SiOx, NiOx, Pt, Pd, Ir, RuxOy, CeZrxOy, BiOx, TiNx, ZnO, ZnS, MnO2, NbO2, VS2, TiS2, CoS2, and Al2O3.

The invention relates to the field of low-temperature plasma catalyst preparation, and discloses a manganese-based catalyst and a preparation method and application thereof. The manganese-based catalyst comprises manganese oxide and an auxiliary active component; the auxiliary active component is selected from one or more than two of Co oxide, Ce oxide, Cu oxide, Ni oxide and Ti oxide; the manganese oxide is in contact with the auxiliary active component to construct a heterogeneous interface; and the grain size of the manganese oxide and the auxiliary active component is 0.5-5 nm. According to the manganese-based catalyst, the degradation efficiency of VOCs can be remarkably improved, the emission amount of NOx and ozone in tail gas can be effectively reduced, and green degradation of VOCs is achieved.

Disclosed is an engineered coating material decorated on a conductive carbon, comprising: a coating material disposed on a surface of the conductive carbon with a partial coverage or full coverage, wherein the coating material comprises at least one material selected from a group comprising: AlOx, TiOx, SnOx, ZnOx, NbOx, TiNbxOy, AlPxOy, MgOx, LiNbxOy, BOx, CeOx, LiAlxOy, Sn(PO4)x, ZrOx, MgAlxOy, SiOx, NiOx, Pt, Pd, Ir, RuxOy, CeZrxOy, BiOx, TiNx, ZnO, ZnS, MnO2, NbO2, VS2, TiS2, CoS2, and Al2O3.

To provide a method of improving the moisture resistance reliability of a multilayer electronic component and improving the connectivity between an internal electrode and an external electrode.SOLUTION: A multilayer electronic component includes a main body 110 including a dielectric layer 111 and internal electrodes 121 and 122 disposed alternately with the dielectric layer in a first direction, external electrodes 131 and 132 disposed outside the main body, and oxide layers 141 and 142 disposed between the main body and the external electrodes and connecting the internal electrodes and the external electrodes. The oxide layer includes one or more of Ni oxide and Cu oxide. Between one surface of the main body and a terminal of the internal electrode, at least one groove part is disposed and the oxide layer is in contact with the terminal of the internal electrode inside the groove part.SELECTED DRAWING: Figure 2

The invention relates to the field of low-temperature plasma catalyst preparation, and discloses a low-temperature plasma catalyst and a preparation method and application thereof. The low-temperature plasma catalyst comprises a carrier, and an active component and a catalyst auxiliary agent which are loaded on the carrier; the active components comprise a first active component and a second active component; the first active component is manganese oxide, and the second active component is selected from one or more than two of Fe oxide, Cu oxide, Co oxide, Ni oxide and Ce oxide; the catalyst auxiliary agent contains one or more than two of a Pt element, an Ag element, an Au element and a Ru element; the carrier is aluminum oxide. According to the low-temperature plasma catalyst, the loading capacity of the active components in the low-temperature plasma catalyst is large, loading of the active components is more uniform, the degradation efficiency of VOCs is improved, emission of toxic by-products NOx and O3 can be avoided at the same time, and secondary pollution is avoided.

This invention discloses a liquid-liquid doping preparation method for molybdenum oxide-based composite targets. The disclosed method includes heating an ammonium molybdate solution with pH=6-6.5 to 60°C, adding an external dopant to the ammonium molybdate solution while stirring, then adding ammonia water to adjust the pH value to approximately 8.0, followed by rapid cooling to below -10°C while stirring; filtering and drying the crystals containing nickel hydroxide / tantalum hydroxide / niobium hydroxide that crystallize out during cooling, and then performing in-situ decomposition hot pressing sintering under a protected atmosphere to obtain a high-density molybdenum oxide-based composite target doped with Ni, Ta, and Nb oxides. The preparation method of this invention can prepare molybdenum oxide-based composite targets doped with Ni oxide, Ta oxide, and Nb oxides with uniform composition and good material conductivity.

The application discloses in-situ grown Cu-Ni alloy nanowires and a preparation method thereof. The preparation method of the Cu-Ni alloy nanowires comprises the following steps: S1, carbon paper is immersed into a mixed solution of CuSO4, NiCl2 and NiSO4 for electrodeposition to obtain a Cu-Ni film; S2, the Cu-Ni film is reacted under alkaline conditions to obtain Cu-Ni hydroxide nanowires; S3, the Cu-Ni hydroxide nanowires are annealed to obtain Cu-Ni oxide nanowires; and S4, the Cu-Ni oxide nanowires are electrochemically reduced to obtain in-situ grown Cu-Ni alloy nanowires. The method can in-situ grow Cu-Ni alloy nanowires on carbon paper as a gas diffusion electrode, can electrochemically reduce CO2 to prepare C2H4, the faradic efficiency (FE) of producing C2H4 reaches 46.98%, and the current density reaches 231.81 mA / cm 2 2, which is obviously higher than that of bare copper nanowires (Cu NWs, 25.33%). The Cu-Ni alloy nanowires are in-situ constructed on carbon paper, and exhibit excellent stability, and can run for more than 8 hours under a large current.

The invention discloses an in-situ growth Cu-Ni alloy nanowire and a preparation method of the in-situ growth Cu-Ni alloy nanowire. The preparation method of the Cu-Ni alloy nanowire comprises the following steps that S1, carbon paper is immersed in a mixed solution of CuSO4, NiCl2 and NiSO4 to be subjected to electro-deposition, and a Cu-Ni thin film is obtained; s2, the Cu-Ni thin film is subjected to a reaction under the alkaline condition, and a Cu-Ni hydroxide nanowire is obtained; s3, the Cu-Ni hydroxide nanowire is subjected to annealing, and a Cu-Ni oxide nanowire is obtained; and S4, the Cu-Ni oxide nanowire is subjected to electrochemical reduction, and the in-situ growth Cu-Ni alloy nanowire is obtained. According to the method, the Cu-Ni alloy nanowire grows on the carbon paper in situ to serve as a gas diffusion electrode, CO2 can be electrochemically reduced to prepare C2H4, the Faraday efficiency (FE) of C2H4 production reaches 46.98%, the current density reaches 231.81 mA / cm < 2 >, and the Faraday efficiency (FE) of C2H4 production obviously exceeds that of a bare copper nanowire (Cu NWs, 25.33%). The Cu-Ni alloy nanowire disclosed by the invention shows excellent stability by virtue of in-situ construction on the carbon paper, and can operate for more than 8 hours under high current.

The invention discloses a lithium primary battery positive electrode material and a preparation method thereof.The method comprises the steps that Ni oxide, Mn oxide, Co oxide and a sodium-containing compound are evenly mixed according to the proportion of the chemical formula and then subjected to calcination treatment, and P2 type sodium-containing layered oxide is prepared; and dispersing the P2 type sodium-containing layered oxide and Li salt in a mixed solvent of water and ethanol, and carrying out hydrothermal reaction to prepare the layered positive electrode material, and charging the layered positive electrode material to obtain the positive electrode material of the lithium primary battery, and the positive electrode material of the lithium primary battery is O2 type, T2 type or O6 type. According to the lithium primary battery prepared by the method, the rate capability of the battery is improved while the discharge capacity of the battery is not lost, so that the energy density and the discharge rate of the lithium primary battery are both considered, and the weight energy density and the volume energy density of the lithium primary battery are both considered.

The invention relates to an integral structural ammonia decomposition catalyst based on a metal honeycomb carrier as well as a preparation method and application of the integral structural ammonia decomposition catalyst. The preparation method comprises the following steps: firstly, soaking a nickel-containing metal honeycomb carrier in an acid solution to remove surface oxides; then, nickel on the surface of the nickel oxide is oxidized in an oxidizing atmosphere to generate nickel oxide; reducing nickel oxide in a hydrogen reducing atmosphere to form a compact metal nickel film layer on the surface of the carrier; then active metal components and auxiliary metal salt are prepared into mixed slurry, and the mixed slurry is loaded on the carrier; and finally roasting to obtain the monolithic catalyst. A compact nickel protection layer is formed on the surface of the metal carrier through oxidation-reduction treatment, so that chemical reaction between ammonia molecules and carrier bulk phase atoms can be effectively blocked, the corrosion resistance of the catalyst is remarkably improved, and the service life of the catalyst is remarkably prolonged. The obtained catalyst is suitable for ammonia decomposition reaction under the conditions of high space velocity and high ammonia concentration.

The invention belongs to the field of catalysts, and discloses a Pd / NiCoOx catalyst, a preparation method and a method for catalytically hydrogenating furan aldehyde alcohol compounds, in the Pd / NiCoOx catalyst, NiCoOx represents a composite carrier of Ni oxide and Co oxide, and Pd is loaded on the composite carrier; the catalyst can be prepared by an ascorbic acid (VC) assisted solid phase grinding-air atmosphere calcination process; the method for catalytically hydrogenating the furan aldehyde alcohol compound comprises the following steps: adding the furan aldehyde alcohol compound, water and a Pd / NiCoOx catalyst into a reaction container, sealing the reaction container, filling pure hydrogen into the reaction container, and carrying out hydrogenation reaction to obtain a hydrogenation product. By means of the catalyst, a simpler hydrogenation reaction system for catalytic hydrogenation of furan aldehyde alcohol compounds can be constructed, and compared with an alcohol solvent and high-temperature complex reaction conditions needed by an existing process, the reaction system involved in the method is more environmentally friendly and mild, and the catalytic efficiency is higher.

The piezoelectric laminate and the piezoelectric element have, on a substrate in the following order, a lower electrode layer and a piezoelectric film containing a perovskite-type oxide, in which the lower electrode layer includes the metal layer containing Ni and a surface layer containing a Ni oxide or a Ni oxynitride, and in the lower electrode layer, the surface layer is arranged on the side closest to the piezoelectric film.

The invention discloses a wax oil hydrocracking catalyst and preparation and application thereof, and the wax oil hydrocracking catalyst mainly comprises the following components by weight: 1-30 parts of a mesoporous-microporous SBA-15 / HY composite molecular sieve; 15 to 40 parts of amorphous silica-alumina; 5 to 30 parts of mesoporous alumina; 10-30 parts of an oxide of a metal W or Mo; 1-8 parts of oxide of metal Co or Ni; 1.0 to 5.0 parts of an extrusion aid; 3-8 parts of an adhesive; the mesoporous-microporous SBA-15 / HY composite molecular sieve is prepared under the action of ultrasonic emulsification. The wax oil hydrocracking catalyst provided by the invention can stably operate for a long period when being used for processing an inferior wax oil raw material.

The invention discloses a composite oxide hydrogenation catalyst and a preparation method thereof. On the basis of the weight of the catalyst, the total content of W, Mo and Ni oxides is 45%-85%, and the content of Al2O3 is 15%-55%; the pore volume of pores with the diameter of 8-15 nm of the catalyst accounts for 39%-49% of the total pore volume, and the pore volume of pores with the diameter of 30-35 nm accounts for 40%-50% of the total pore volume. The number of particles with the particle size of 20-30 nm of the catalyst accounts for 84%-93% of the total number of particles. The preparation method comprises the following steps: (1) carrying out parallel flow gel formation on a solution containing W, Ni, Mo and Al and a precipitator to obtain slurry, aging a part of the slurry to obtain aged slurry, and mixing the aged slurry with the other part of slurry which is not aged; (2) aging the mixed slurry, adding a W-containing solution in the aging process, carrying out solid-liquid separation to obtain a solid-phase material, carrying out carbon dioxide purging, and washing with water at different temperatures; and (3) preparing the washed material into the composite oxide hydrogenation catalyst. The catalyst provided by the invention is suitable for treating inferior diesel fractions with high aromatic hydrocarbon content and high processing difficulty, and has excellent hydrogenation saturation performance.

An electrode contains electrolyte particles and Ni-based particles. The electrolyte particles contain Gd-doped CeO2 (GDC) and / or Gd- and La-doped CeO2 (La-GDC). The Ni-based particles are composed of core-shell particles in which a surface of a core composed of Ni or a Ni-based alloy is partially or completely covered by a shell composed of a composite oxide containing NiO or Ni.

An electronic device includes an element body. The element body includes a first internal electrode layer, a second internal electrode layer, and a dielectric layer laminated between the first internal electrode layer and the second internal electrode layer. Ni oxide particles exist at a first boundary between the first internal electrode layer and the dielectric layer. The dielectric layer includes a dielectric large particle in contact with both of the Ni oxide particles at the first boundary and the second internal electrode layer.

The invention belongs to the technical field of catalyst preparation, and particularly relates to a catalyst for preparing synthesis gas from lignin driven by solar energy as well as a preparation method and application thereof. The invention relates to a catalyst for preparing synthesis gas from lignin driven by solar energy, which is composed of active components without a carrier, the active components comprise Cd and Cd oxide, Cu and Cu oxide, Ni and Ni oxide, Co and Co oxide, and Fe and Fe oxide, and the molar ratio of the active component elements Cd: Cu: Ni: Co: Ni is 1: (0.5-1.5): (0.5-1.5): (0.5-1.5): (0.5-1.5). The preparation method of the catalyst is simple, the raw materials are cheap and easy to obtain, and the prepared catalyst shows high-yield synthesis gas activity under the irradiation reaction of simulated sunlight.

Disclosed is an engineered coating material decorated on a conductive carbon, comprising: a coating material disposed on a surface of the conductive carbon with a partial coverage or full coverage, wherein the coating material comprises at least one material selected from a group comprising: AlOx, TiOx, SnOx, ZnOx, NbOx, TiNbxOy, AlPxOy, MgOx, LiNbxOy, BOx, CeOx, LiAlxOy, Sn(PO4)x, ZrOx, MgAlxOy, SiOx, NiOx, Pt, Pd, Ir, RuxOy, CeZrxOy, BiOx, TiNx, ZnO, ZnS, MnO2, NbO2, VS2, TiS2, CoS2, and Al2O3.

The invention relates to the technical field of aluminum-iron plated steel plates, in particular to a high-temperature-oxidation-resistant aluminum-iron alloying plated steel plate and a manufacturing method and application of the high-temperature-oxidation-resistant aluminum-iron alloying plated steel plate. The aluminum-iron alloying coated steel plate comprises a substrate, a diffusion layer, an Al-Fe phase, an Al-Fe-Si phase and a composite oxide film multi-layer structure of Al2O3 + Cr and / or Ni oxide, an aluminum-silicon alloy coating is formed on the surface of the substrate through hot dipping, and then the aluminum-silicon alloy coating is converted into an aluminum-iron alloy coating after alloying annealing and Fe element diffusion; the total thickness of the aluminum-iron alloy coating is 6-45 microns, the thickness of the diffusion layer is 1-10 microns, the thickness of the Al2O3 + Cr and / or Ni oxide composite oxide film is 0.2-1.2 microns, the Al-Fe-Si phase accounts for 10%-40% of the sectional area of the aluminum-iron alloy coating, the rest is the Al-Fe phase, and the surface of the aluminum-iron alloy coating is black. The oxidation resistance of the plating layer at the high temperature is improved.

The present invention provides a platinum catalyst and a preparation method and application thereof, belonging to the technical field of catalysts. Porous carbon nanospheres are prepared by an emulsion method followed by carbonization, B / N-doped wrinkled graphene-coated nanospheres are prepared by spray drying and reduction, Sn / Ni oxides are deposited on the surface, and then platinum is loaded to prepare a platinum catalyst. The platinum catalyst prepared by the present invention has a high Pt loading amount and a strong action force, which is conducive to preventing the catalyst from agglomerating and falling off, improving the durability of the catalyst, and has high catalytic activity and good dispersibility, and has broad application prospects.