The invention discloses a
cobalt-doped
nickel molybdenum sulfide electrode material, a preparation method of the
cobalt-doped
nickel molybdenum sulfide electrode material and application of the
cobalt-doped
nickel molybdenum sulfide electrode material in electro-catalytic synthesis of 3, 4-dihydroisoquinoline. A simple hydrothermal method is adopted to directly grow a cobalt-doped nickel
molybdenum oxide precursor on a foamed
nickel substrate in situ, and then the cobalt-doped nickel
molybdenum oxide precursor is subjected to
vulcanization treatment to prepare the Co-NiMo-S / NF self-supporting
electrode material. The electrode can efficiently catalyze
tetrahydroisoquinoline to be selectively oxidized into 3, 4-dihydroisoquinoline under the normal-temperature and alkaline conditions, the conversion rate is larger than or equal to 85%, the selectivity is close to 100%, and meanwhile generation of deep oxidation product
isoquinoline is effectively inhibited; the
ternary sulfide electrode is applied to the
reaction system for the first time, the catalyst cost is low, the preparation process is simple, the
reaction conditions are mild, and the method has good industrial application prospects.