The invention discloses a high-wear-resistant concrete material as well as a preparation method and application thereof. The concrete material is prepared from the following materials in parts by weight, 45 to 55 parts of silicate cement, 23 to 31 parts of fine sand, 11 to 19 parts of polystyrene resin, 7 to 15 parts of cellulose diacetate, 15 to 25 parts of dimethyl sulfoxide, and 18 to 26 partsof vermiculite. The preparation method comprises the steps that the vermiculite and cellulose diacetate are mixed and crushed, and then mixed with a dimethyl sulfoxide solution, heated and sealed forstirring, a precipitate is collected by centrifugation, pretreated vermiculite is obtained by washing and drying the precipitate; the precipitate is added with a polystyrene resin to conduct ball milling, mixed with silicate cement and fine sand, and evenly mixed; pouring, vibrating, and curing are conducted. The high-wear-resistant concrete material has higher compressive strength and flexural strength, has significant improvement in VC value, impermeability grade, freeze-thaw strength, ultimate tensile, adiabatic temperature rise, chemical attack resistance and the like, effectively improvesimpact resistance, effectively improves resistant to erosion and abrasion, effectively reduces shrinkage deformation of concrete, improves crack resistance, and has excellent overall performance.