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91results about How to "Overcome the problems of many processes and heavy workload" patented technology

Process for synthesizing methanol catalyst

The invention discloses a process for synthesizing a methanol catalyst. The process comprises the steps: preparing an aqueous solution, of which the total concentration of copper nitrate, zinc nitrate and aluminum nitrate is 0.5-2.0mol/L, and an aqueous solution, of which the concentration of sodium carbonate/sodium bicarbonate is 0.5-3.0mol/L, controlling the pH value of precipitating mother liquor to 6.5 to 8.5 at the temperature of 50 DEG C to 80 DEG C while carrying out stirring, carrying out a reaction, carrying out aging for 0.5 to 4 hours at the temperature of 60 DEG C to 90 DEG C, then, washing precipitates with deionized water, preparing a suspension, of which the solid content is 5% to 30%, from the washed precipitates by using deionized water, and carrying out spray drying; and finally, roasting the dried precipitates for 1 to 5 hours in an air atmosphere at the temperature of 300 DEG C to 400 DEG C, thereby obtaining the catalyst. According to the process for synthesizing the methanol catalyst, the process is simple, the operating conditions are mild, and particularly, the particle size of the catalyst prepared by adopting spray drying reaches a micron scale; and proven by gas-liquid-solid three-phase slurry-bed reactor tests, the synthesized catalyst is high in activity and good in stability. The bottleneck that a process for synthesis of methanol by a gas-liquid-solid three-phase slurry bed, which has many advantages and very superior economical efficiency, cannot be industrially generalized extensively due to the fact that proper high-stability catalysts capable of being applied to the gas-liquid-solid three-phase slurry-bed methanol synthesis process are absent is thoroughly solved.
Owner:QINGDAO SHOUTAI AGRI SCI & TECH CO LTD

Grain refining casting method for high manganese steel casting

InactiveCN104550877ASolve the coarse grainSolve looseImpuritySteel casting
The invention discloses a grain refining casting method for a high manganese steel casting. The method comprises the following steps: during a smelting process of the high manganese steel, discharging molten steel from a furnace at high temperature, blowing argon and feeding wire for refining after discharging from the furnace, and strictly controlling the content of phosphorus and sulfur in the molten steel; during a pouring process of the high manganese steel casting, adding metallic particles by following the flow, reducing molten metal storage energy and quickening the cooling of the casting, adding the metallic particles into a pouring system of the casting in the middle and later periods of the whole pouring process, uniformly adding at one time or in batches, quickly pouring the casting, and adopting a bottom leakage package for preventing impurities from being involved. According to the method provided by the invention, the defect of the ultrahigh temperature of the molten steel in the prior art is overcome and the nucleation particle refining grains are added, so that the problems of thick grains, loosening, micro-cracks, and the like of the high manganese steel casting are solved, the high manganese steel casting with grain refinement and high strength is produced, and the casting quality is effectively ensured.
Owner:青岛齐力铸钢有限公司

P-nitro tribromotoluene synthesis process

The present invention discloses a p-nitro tribromotoluene synthesis process, which is characterized in that in a first-step reaction, p-nitro toluene is added to a reaction kettle, a tail gas absorption device is opened, hydrogen bromide and excess bromine produced from the reaction are absorbed with water, the reaction temperature is controlled at 130-180 DEG C, bromine is added in a dropwise manner, the reaction time is controlled at 3-8 h, p-nitro dibromotoluene is generated through the reaction, and cooling is performed to a temperature of 60-80 DEG C; and in a second-step reaction, carbon tetrachloride, a catalyst BTEAB, sodium hydroxide and water are sequentially poured into the reaction kettle, the temperature is controlled at 40-80 DEG C, bromine is added in a dropwise manner, the reaction time is 2-6 h, filtering is performed to obtain a crude product, the crude product and ethanol are poured into the reaction kettle, stirring and heating reflux are performed for 20-60 min, cooling is performed to achieve a room temperature, and filtering and drying are performed to obtain the finished product. According to the present invention, the whole production process has characteristics of stable operation, easy control, low cost, high yield, and the like.
Owner:吕艳
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