The invention relates to a glass ball, particularly relates to a lead-free potassium barium glass ball and a production process thereof, and belongs to the technical field of glass material. The glass ball comprises the raw materials by the mass percentage: 1.05-1.45% of sandstone, 6.0-10.0% of quartz sand, 8.5-12.5% of bauxite, 10.5-12.50% of limestone, 8.5-10.5% of broken glass, 15.2-16.3% of ascharite, 0.5-1.0% of titanium dioxide, 0.5-2.0% of niobium carbide, 1.52-1.56% of fluorite, 0.45-0.55% of a clarifying agent, and the balance pyrophyllite. While the glass ball is guaranteed to have the advantages of being high in whiteness, glittering and translucent, high in gloss, rich in refractive index, toughness and the like, the chemical stability, the thermal stability and the mechanical strength of the lead-free potassium barium glass ball are improved, and the crystallization tendency of the lead-free potassium barium glass ball is reduced, and the cost of production is greatly reduced.