The invention relates to a comprehensive treatment method of high-sulphur high-COD (
Chemical Oxygen Demand) caustic
sludge waste liquid. The comprehensive treatment method comprises the steps of: 1, acidizing high-sulphur high-COD caustic
sludge waste liquid by using an N2 / SO2
mixed gas, when the pH value of the waste liquid reaches 2-6, stopping acidizing; 2, sending
tail gas discharged in the acidizing process in the step 1 to a sulphur production device for preparing sulphur; 3,
settling the waste liquid generated in acidizing treatment in the step 1and recovering an
oil phase; 4, further reducing the COD of the waste liquid by adopting an extraction method when the COD of the waste liquid after the
oil phase is separated in the step 3 is always high; and 5, regenerating the waste liquid extracted in the step 4 by using
lime. The comprehensive treatment method is low in investment, is mild in operation conditions, is capable of recycling the caustic
sludge waste liquid, avoiding the
impact of the high-concentration
wastewater on a
wastewater treatment field, is also capable of recovering
sulfide and crude carbolic acid from the caustic sludge waste liquid, and has a certain economic benefit.