The invention discloses a chiral vicinal diamine derivative. The chiral vicinal diamine derivative is a compound as shown in a formula I, or tautomer, enantiomer and diastereoisomer thereof, wherein Ar1 and Ar2 are selected from aryl and ceteroary respectively; the aryl and ceteroary do not have substituent group or have one or more substituent groups; R1 is selected from hydrogen, alkyl, phenyl, esteryl and methylene; when R1 is methylene, an A ring is formed through 0 to 5 methylene; X is selected from N3, NH2, NHBoc and N(Bn)2; B rings are 4 to 7 saturated or unsaturated heterocyclic rings; M is carbon or nitrogen; when M is carbon, G is selected from hydrogen, alkyl, alkoxy and esteryl; when M is nitrogen, G is selected from Ms, Ts, Boc and Bn. The invention further discloses a catalytic asymmetric synthesis method of the chiral vicinal diamine derivative. The method has a wide substrate range, excellent functional group tolerance and mild reaction conditions, is high in yield and good in enantioselectivity, and belongs to a convenient and practical method.