14 results about "Sulfohydrazide" patented technology

The invention relates to a thermally expandable composition comprising: a) At least one thermoplastic polymer TP and / or at least one solid rubber R and b) At least one polymeric blowing agent BA selected from the group consisting of sulfonyl hydrazide-functionalized polymers, sulfonyl semicarbazide-functionalized polymers, carbamate-functionalized polymers, and ureido carbamate-functionalized polymers, wherein the polymeric blowing agent BA has a number average molecular weight (Mn) determined by gel permeation-chromatography (GPC) using polystyrene 0 as standard of at least 500 g / mol, preferably at least 750 g / mol.

The invention relates to a method for preparing 1, 2-bis (4-vinylphenyl) ethane, and relates to the technical field of organic chemistry, the preparation method comprises the following steps: (1) mixing a compound 1, p-toluenesulfonhydrazide and an organic solvent 1, and reacting to obtain a compound 2; and (2) reacting the compound 2 in an organic solvent 2 under the action of alkali and a polymerization inhibitor to generate the 1, 2-bis (4-vinyl phenyl) ethane. The method is mild in reaction condition, simple and convenient to operate, high in product purity, high in yield and suitable for industrial production.

The application relates to the technical field of pharmaceutical chemistry, and discloses a sulfuryl hydrazone compound, a preparation method thereof and anti-tumor application. The compound is synthesized from isatin derivatives and sulfuryl hydrazine through two-step nucleophilic substitution-elimination reaction, has a chemical structure as shown in formula (I), and is characterized by 1H NMR, 13C NMR and HRMS. The sulfuryl hydrazone compound has significant inhibitory activity on A549 (lung cancer), HepG2 (liver cancer) and Hela (cervical cancer) three human cancer cell strains, the value of some compounds is as low as 0.03 micromole / L, the compound can induce cell apoptosis by mediating ROS generation in tumor cells, inhibiting the NF-kappa B signal pathway and activating Caspase-3 activity, and can effectively inhibit cancer cell migration and colony formation. The compound has a mild synthesis process, simple operation and wide substrate applicability, can be used as a potential anti-tumor active ingredient, can be used for preparing drugs for resisting lung cancer, liver cancer, cervical cancer and other tumors, and can provide new candidate compounds and technical support for cancer treatment.

This invention discloses a method for preparing high-performance tin-containing perovskite solar cells using bifunctional acylhydrazide small molecules. The method focuses on selecting bifunctional acylhydrazide small molecules such as p-toluenesulfonylhydrazide (PTSH) and oxaloyl dihydrazide (ODZ) as additives to enhance the performance of tin-containing perovskite (ASn) solar cells. x Pb 1‑x X3) Modification of the active layer of solar cells. Compared to traditional Sn 2+ The coordination strategy of the bifunctional hydrazide small molecule selected in this invention can, in addition to coordinating with Sn... 2+ In addition to providing an antioxidant environment through coordination, Sn can also achieve... 4+ To Sn 2+ The reduction of Sn in perovskite films can be minimized. 4+ This leads to the P-type self-doping effect and defect density. The photoelectric conversion efficiency and device stability of the tin-containing perovskite solar cells prepared based on this invention are effectively improved.

The invention relates to a process for producing polyurethanes using a component A comprising a polyhydrazide, a polysemicarbazide, a polysulfonyl hydrazide and / or carbodihydrazide, in particular a polyhydrazide, wherein the component A is employed in the form of a mixture C which further comprises a component B comprising a dispersion medium.

The invention belongs to the technical field of organic synthesis, and particularly relates to a benzenesulfonyl hydrazide derivative, a preparation method and application. Under electrochemical reaction conditions, cheap and easily available ketone, benzenesulfonyl hydrazide and corresponding sodium benzenesulfinate are used as raw materials, acetonitrile (CH3CN) / water (H2O) is used as a solvent, triethylamine (Et3N) is used as alkali, the benzenesulfonyl hydrazide derivative is prepared at room temperature and in an air atmosphere, and the benzenesulfonyl hydrazide derivative has potential medicinal value and is widely applied to the fields of pesticides and medicines. Compared with a previously reported preparation method, the method has the advantages of being green, environmentally friendly, safe, efficient and energy-saving, raw materials are easy to obtain, operation is easy and convenient, and potential industrial application prospects are achieved.

The invention discloses a method for synthesizing a thiosulfonate compound through aerobic oxidative coupling, and relates to the technical field of organic synthesis.The synthesis method comprises the steps that a nitrogen-doped carbon-loaded cobalt-based catalyst is adopted, and in the oxygen or air atmosphere, a sulfydryl-containing compound and sulfonyl hydrazide are catalyzed to be subjected to an oxidative coupling reaction; the preparation process of the catalyst comprises the following steps: reacting cobalt salt with sodium dicyandiamide in a water phase to generate a dicyandiamide cobalt complex; mixing the complex with an ionic liquid containing dicyandiamide anions in proportion, stirring and drying to obtain an ionic liquid precursor of metal cobalt; and carbonizing the obtained precursor at a high temperature of 500-1000 DEG C in an inert atmosphere, etching for 2-10 hours by using a 1-6 mol / L hydrochloric acid solution, washing to be neutral, and drying to obtain the nitrogen-doped carbon-loaded cobalt-based catalyst. The catalyst used in the method is green, economical and recyclable, the reaction process is mild in condition and simple and convenient to operate, the product yield is excellent, and the method has a good application prospect.

The application discloses a method for sulfonylating halogenated quinoline and aryl sulfonohydrazide, wherein the halogenated quinoline compound and the aryl sulfonohydrazide are subjected to a sulfonylating reaction in a solvent to obtain a target compound. The application provides a simple method for forming a sulfonyl quinoline without adding any catalyst and additive, and the method is green and environment-friendly, and the reaction condition is simple and mild, and the method has the characteristics of simple post-treatment, green step, low pollution, high economic benefit and the like.

The application provides a self-repairing stretch silver paste, a preparation method and application thereof.The self-repairing stretch silver paste comprises the following raw materials: conductive silver paste, pore-forming agent and silicon modified resin; and the pore-forming agent is at least one of p-toluenesulfonyl hydrazide, sodium bicarbonate, molecular sieve and 4,4'-oxobenzene sulfonyl hydrazide.The self-repairing stretch silver paste of the application comprises the pore-forming agent and the silicon modified resin in addition to the conventional conductive silver paste, so that the silver paste can form an elastic conductor with porous cavities after gradient curing, the displacement of the conductive filler is reduced through the stress deformation of the cavities, the resistance recovery hysteresis is significantly improved, and the resistance deterioration is reduced; the obtained silver paste has fast resistance recovery speed, low hysteresis and excellent conductive stability under 50% stretch deformation, and is suitable for repeated deformation scenes such as flexible sensors, wearable devices and flexible circuits.

This invention discloses a sulfonylpyridinone compound, its preparation method, and its applications. The compound is prepared by introducing a sulfonyl group at the 4-position of pyridazin-3(2H)one, giving it multiple functional groups such as sulfone, phenyl, and pyridazinone. The sulfonylpyridinone compound of this invention exhibits a certain antibacterial effect against *Escherichia coli* / *Staphylococcus aureus* and can be used to prepare broad-spectrum antibacterial drugs. Due to its multifunctional nature involving flame retardant groups, this compound is expected to be applied in the flame retardant field. This invention also provides a method for preparing the above-mentioned sulfonylpyridinone compound, achieved through a dehalogenation sulfonation reaction of 4,5-dihalo-2-phenylpyridazin-3(2H)one with sulfonylhydrazine. This reaction process not only avoids transition metal catalysis and the addition of oxidizing or reducing agents, but also features a simple reaction system, a wide range of applicable substrates, and a high yield, which is beneficial for industrial production.

The application relates to a method for preparing 1,2-bis(4-vinylphenyl)ethane and relates to the technical field of organic chemistry, wherein the preparation method comprises the following steps: (1) mixing compound 1, p-toluenesulfonyl hydrazide and organic solvent 1, and then performing reaction to obtain compound 2; (2) reacting the compound 2 in organic solvent 2 under the action of alkali and a polymerization inhibitor to generate 1,2-bis(4-vinylphenyl)ethane. The method has the advantages of mild reaction conditions, simple operation, high product purity, high yield and suitability for industrial production.

The invention relates to the technical field of repairing slurry, in particular to composite material repairing slurry and a preparation process thereof. The invention relates to a composite material repairing slurry, which comprises a filler, a thermal expansion agent, a reinforcing fiber, a thermosetting plastic and a solvent according to a mass ratio of (13-15): (4-5): (10-12): (40-45): (40-45), wherein the filler is a carbon nanotube, the thermal expansion agent is selected from one or more of azodiisobutyronitrile, p-toluenesulfonyl hydrazide, N, N '-dinitroso-N, N'-dimethyl terephthalamide and benzenesulfonyl hydrazide, and the reinforcing fiber is selected from one or more of glass fiber, wollastonite fiber, cellulosic fiber and ceramic fiber. The composite material repairing slurry can be heated to expand after being heated at 100 DEG C, cracks are filled, the repairing difficulty of operators is reduced, and the repaired bumper is good in impact resistance.

This invention relates to an electrochemical synthesis method for fully substituted sulfonated pyrazole compounds. The method includes the following steps: mixing acetylacetone, substituted arylsulfonyl hydrazides, and an electrolyte, adding the mixture to a mixed solvent to obtain a mixed solution; subjecting the mixed solution to an electrochemical reaction to obtain a reaction mixture; and separating and purifying the reaction mixture to obtain the fully substituted sulfonated pyrazole compounds. Compared with existing technologies, this invention uses an electrochemical method to prepare fully substituted sulfonated pyrazole compounds. During the reaction, an iodine-containing electrolyte undergoes an oxidation reaction at the anode to generate iodine free radicals. These iodine free radicals then react with arylsulfonyl hydrazides and acetylacetone with different substituents to form the fully substituted sulfonated pyrazole compounds. This method has advantages such as simple preparation, convenient operation, high atom utilization, and mild reaction conditions.

The application discloses a synthesis method of 2,4,5-trifluorophenylacetic acid, and relates to the technical field of organic chemical industry. The method comprises the following steps: starting from 2,4-dichloro-5-fluorobenzoyl chloride, first performing cyanoization to generate 2,4-dichloro-5-fluorobenzoyl cyanide, then performing halogen exchange reaction with potassium fluoride under the condition of a phase transfer catalyst to generate 2,4,5-trifluorobenzoyl cyanide, then reducing under p-toluenesulfonyl hydrazide and sodium borohydride, and finally hydrolyzing under an acidic condition to generate 2,4,5-trifluorophenylacetic acid. The method has high selectivity and purity, and is lower in cost.