The invention discloses a method for preparing secondary
zinc oxide from
oxygen pressure leached
zinc smelting solid waste residues. The method comprises the following steps that
oxygen pressure leached
zinc smelting solid waste residues are dried until the
water content is 15% or below, and the
solid waste residues are granulated by using a granulator; the solid waste residues are mixed with limestone,
quartz stone and reducing
coal, and are sent to an
oxygen-enriched side-blown furnace; oxygen-enriched air is blown into a furnace during
smelting, and chemical reactions such as
sulfur makingand slagging are completed;
sulfur in the
slag generates SO2, and the SO2 enters an acid making
system through a
flue gas pipeline to produce industrial
sulfuric acid; the
molten slag is blown by a fuming furnace, secondary zinc
oxide products are produced from
smoke dust, and the fuming furnace
slag is subjected to innocent treatment. According to the method, the problems that the smelting solidwaste produced in the zinc-
oxygen pressure leaching process is difficult to stack and transport, valuable
metal in the leaching residues cannot be recycled and the like are solved, and harmless treatment of the zinc-
oxygen pressure leaching smelting solid waste is achieved. The method has the advantages that valuable metals such as lead, zinc,
indium,
germanium and silver can be recovered, industrial-grade secondary zinc
oxide products can be prepared, the technological process is simple, the
recovery rate of the valuable metals is high, and the
energy consumption is low.