The invention discloses a micro-ring resonant cavity electro-optical modulator based on a graphene/molybdenum disulfide heterojunction. The micro-ring resonant cavity electro-optical modulator comprises a substrate layer, a direct-light waveguide, a micro-ring resonant cavity waveguide and a graphene covering layer. The direct-light waveguide and the micro-ring resonant cavity waveguide are embedded into the substrate layer, and a coupling space is reserved between the direct-light waveguide and the micro-ring resonant cavity waveguide. The upper surface of the micro-ring resonant cavity waveguide is covered with a part of the graphene covering layer. The graphene covering layer comprises a first graphene layer, a second graphene layer, molybdenum disulfide, a first electrode and a second electrode, wherein the first graphene layer and the second graphene layer are isolated by the molybdenum disulfide, the first graphene layer stretches outwards from one side of the micro-ring resonant cavity waveguide and is connected with the first electrode, and the second graphene layer stretches outwards from the other side of the micro-ring resonant cavity waveguide and is connected with the second electrode. The micro-ring resonant cavity electro-optical modulator has extremely low optical loss, a low thermo-optical coefficient, low insertion loss, large environment temperature tolerance, a good modulation depth and a high extinction ratio.