The invention belongs to the field of optical film, and more specifically relates to a high reflectivity multilayer heat insulation window film which his high in reflectivity on infrared light, and apreparation method thereof. The high reflectivity multilayer heat insulation window film comprises a PET sealing layer, a first reflecting layer, a second reflecting layer, a third reflecting layer, afourth reflecting layer, a fifth reflecting layer, a sixth reflecting layer, a seventh reflecting layer, an eighth reflecting layer, a ninth reflecting layer, a tenth reflecting layer, an eleventh reflecting layer, a twelfth reflecting layer, a thirteenth reflecting layer, a fourteenth reflecting layer, and a PET substrate layer, which are laminated successively, and is prepared through magnetronsputtering. The high reflectivity multilayer heat insulation window film is invented based on optical interference enhancing principles, reflective constructive interference of light of different wavelengths in infrared light is realized, so that transmission effect is reduced, high reflective effect on infrared light (800 to 1500nm) is achieved, and the transmittance is only 8%.