The invention discloses an anionic water-borne
epoxy resin
emulsion and a preparation method thereof. The preparation method comprises following steps: S1, 160-200 parts of
epoxy resin E-44 is added to a reaction vessel, and after heating, 210-250 parts of diisocyanate is added for a reaction; S2, 40-50 parts of
polycaprolactone and 30-50 parts of small-molecule
diol are added, and a heat insulating reaction is performed for a period of time; S3, 30-40 parts of dimethylolbutyric acid is added, a catalyst is dropwise added, and the heat insulating reaction is performed for a period of time; S4,content of NCO in a
system is detected, when content of NCO reaches 1.5%-4.0%, 50-80 parts of
epoxy resin E-51 is added, then 10-20 parts of
hydrogen peroxide is added, the heat insulating reaction is performed for a period of time, and 300-400 parts of
acetone is added for reducing
viscosity; S5, cooling is performed, caustic soda is added for
neutralization, an emulsifier is added for emulsification, and
acetone is removed from the
system through
vacuum pumping. The anionic water-borne epoxy resin
emulsion prepared with the method is milky white and fine in appearance, excellent in storagestability,
mechanical stability and freeze-thaw stability, good in
water resistance, high in
hardness and high in
adhesive force.