The invention belongs to the technical field of coatings, and particularly relates to a preparation method of 
stain-resistant real stone paint. The carbon nano tubes and the argil are coated, so thatthe 
pigment in the color sand is not radiated by light rays; 
titanium dioxide also has the function of absorbing and converting 
ultraviolet rays, so that the stone-like paint has good 
ultraviolet aging resistance; a layer of fluorosilane molecules is formed on the surface of the 
titanium dioxide nanoparticles in the real stone paint 
coating; 
fluorine atoms in fluorosilane molecules of the coatinglayer are high in 
electronegativity, so that the 
bond energy of a 
single bond formed by the fluorosilane molecules and other elements is larger than that of a 
single bond formed by carbon atoms and other elements, and due to the fact that the carbon chains in the fluorosilane molecules are protected by the original space 
barrier effect, fluorosilane has good 
chemical stability and low surface freeenergy. The fluorosilane 
surface coating layer reduces the Van Der Waals' force of 
titanium dioxide nanoparticles on water and the effect of 
hydrogen bonds and greatly increases the 
contact angle ofthe surface of a paint film, so that the product shows super-hydrophobicity. The preparation method can obviously improve the 
stain resistance of the real stone paint, and has a wide application prospect.