The invention discloses a preparation method of anhydrous iron phosphate and a preparation method of a lithium iron phosphate carbon composite material, a green vanadium product is purified from titanium dioxide to synthesize an iron phosphate product, and APP is utilized to replace DAP or MAP, so that on one hand, the cost can be reduced to a certain extent, and on the other hand, the pollution can be reduced. In addition, a two-step aging mode or a multi-step aging mode is controlled, and the dehydration temperature and time are adjusted, so that primary particles of iron phosphate can be controlled at a relatively small level of about 100nm, and meanwhile, a relatively normal Fe/P ratio is obtained. The lithium iron phosphate carbon composite material is prepared by adopting the anhydrous iron phosphate, and composite carbon source and composite carbon coating is performed by a rheological phase method, so that the sintering temperature can be reduced, the sanding and sintering time can be shortened, the coating uniformity can be improved, and meanwhile, the electrical property, especially the rate capability, of lithium iron phosphate can be enhanced.