The invention relates to the technical field of conductor materials, in particular to an
electron-
lithium ion mixed conductor material and a preparation method thereof. According to the technical scheme, the
sulfide solid electrolyte comprises a
sulfide solid electrolyte core; the surface of the inner core is coated with the LiMS
coating layer, M is at least one of V, Cr, Fe, Ni and Nb, the
sulfide solid electrolyte is Li < 6-X > PS5-XCl < 1 + X >, x is greater than or equal to 0 and less than or equal to 0.6, and the thickness of the LiMS < 2 >
coating layer is nanoscale. A novel
electron-
lithium ion mixed conductor material is successfully developed through an optimally designed in-situ reaction and preparation process, and the material can provide efficient
ion and
electron transmission paths in a positive
electrode at the same time, significantly reduce
interface impedance, improve the
utilization rate of active substances, and improve the performance of a
lithium ion battery. Therefore, the
discharge capacity and the electrochemical performance of the all-solid-state battery are greatly improved.