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168 results about "Ionization energy" patented technology

In physics and chemistry, ionization energy (American English spelling) or ionisation energy (British English spelling), denoted Eᵢ, is the minimum amount of energy required to remove the most loosely bound electron, the valence electron, of an isolated neutral gaseous atom or molecule.

Radio-frequency discharge VUV composite ionization source used for mass spectrometry

The invention relates to an ionization source, in particular to a composite ionization source which comprises a VUV single-photon ionization source based on radio-frequency voltage discharge and a chemical ionization source obtained by utilizing photoelectron ionization reagent gas in the photoelectric effect. The composite ionization source comprises a radio-frequency VUV source, an ion transmission optical system and an ion source cavity. An ion repulsing electrode, an ion focusing electrode and a difference interface electrode plate are sequentially arranged in the VUV source emergent direction of radio-frequency discharge, the three electrodes are all round sheet electrodes with round holes in the centers, and the three electrodes are spaced through insulation pads and are coaxially arranged in parallel. The VUV light beam of the radio-frequency voltage discharge and coaxial light beams of all the round sheet electrodes penetrate through the center holes of all the electrodes in the axis direction, and finally the beams are irradiated on the surface of the difference interface electrode plate. Chemical ionization is acted on the photoelectrons after reagent gas is added. Soft ionization of sample molecules with ionization energy higher than the photon energy is achieved, the range of analyzable samples is enlarged, and the detection sensitivity of instruments is improved.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Radio-frequency electric field enhanced single photon and chemical ionization source

The invention relates to a mass spectrometer ionization source, in particular to a radio-frequency electric field enhanced single photon and chemical ionization source comprising a vacuum ultraviolet source, an ion generation and transmission area and a vacuum chamber vacuum cavity. A plurality of transmission electrodes and vacuum differential perforated electrodes are disposed in parallel and at intervals in the ion generation and transmission area. Each electrode is axially provided with a through hole. Ultraviolet emitted by the vacuum ultraviolet source enters the perforated electrodes along the axes. Direct-current voltage is applied to all transmission electrodes and perforated electrodes; radio-frequency voltage is superposed to one transmission electrode. Two different ionization ways are switched by controlling start and stop of the radio-frequency voltage. The radio-frequency electric field enhanced single photon and chemical ionization source comprises the single photon ionization source, the chemical ionization source is obtained through photoelectron ionization reagent gas obtained by means of photoelectric effect, radio-frequency electric field is introduced to the ionization area to enhance chemical ionization triggered by photoelectrons, detection sensitivity is improved, soft ionization of sample molecules with ionization energy higher than the energy of ultraviolet photons can be achieved, and range of analyzable samples is widened.
Owner:SHENZHEN BREATHA BIOTECHNOLOGY CO LTD

Composite ionization source based on vacuum ultraviolet light ionization and atmospheric pressure ionization

The invention relates to mass spectrometry instrument, and particularly to a composite ionization source based on vacuum ultraviolet light ionization and atmospheric pressure ionization. The composite ionization source based on vacuum ultraviolet light ionization and atmospheric pressure ionization comprises a vacuum ultraviolet light source, an ionization chamber cavity, an ion funnel and an atmospheric pressure ionization source; a sample gas capillary tube connector, a vacuum gauge connector and a mechanical vacuum pump extraction opening are formed in the wall of the ionization chamber cavity. A direct voltage and a radio-frequency voltage are applied to the ion funnel, so that ions which are not in the axis can be focused on the axis, and the ions are transferred into a mass analyzer below the ion funnel to be analyzed. According to the composite ionization source based on vacuum ultraviolet light ionization and atmospheric pressure ionization, the vacuum ultraviolet light source can ionize polar molecules and nonpolar molecules, the atmospheric pressure ionization source can ionize compounds with the ionization energy higher than the photon energy of vacuum ultraviolet light, and the range of ionizable compounds is widened; in addition, after sample molecules which are not ionized in the atmospheric pressure ionization source enter the ionization chamber cavity, secondary ionization can be conducted on the sample molecules through the vacuum ultraviolet light, and the ionization efficiency and the detection sensitivity are improved.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Atmosphere suspended particulate matter mass concentration detector

The invention relates to an atmosphere suspended particulate matter mass concentration detector based on the national environmental protection HJ618-2011 standard, wherein the atmosphere suspended particulate matter mass concentration detector is suitable for detection of mass concentration of particulate matters from PM2.5 to less than PM 10 in an air environment. In the prior art, PM2.5 fine particles are difficultly interdicted on filtration membranes with the existing quartz, mixed cellulose and other organic filtration membranes; and the oscillation frequency of the existing electronic oscillation balance method is affected by excessive thick dust accumulation, and the filtration membrane weight method has disadvantages of complex operation and difficult calibration accuracy. According to the present invention, based on the aerosol characteristic of the less than PM 10 particulate matters, particularly the PM2.5 fine particulate matters in the ambient air, a suitable microgram scale of a beta-source with a nickel-63 low-energy short-range is selected, the ionization energy absorption principle can be completed provided when the electron is loaded, and the atomic nucleus electron of the dust matter is fixed; and compared with the manual filtration membrane weight method, the method of the present invention can achieve the high accuracy requirement.
Owner:戴艺

Second-order differential flame emission spectrometer

ActiveCN102680454AUnique function of automatically subtracting continuous background interferenceAccurate measurementAnalysis by thermal excitationLinear relationshipWorkstation
The invention provides a second-order differential flame emission spectrometer. The flame emission spectrometer changes a flame atomization temperature by regulating an oxygen gas flow of oxygen-rich air to meet the requirements of elements different in ionization energy for different atomization temperatures, and generates a characteristic spectral line with an extremely low flame background interference; and adopts the automatic scanning second-order differential precise grating monochromator technology, and can automatically subtract various background interferences near the characteristic spectral line of to-be-analyzed elements to obtain a second-order derivative spectrum. The obtained second-order derivative spectrum is converted into a frequency-modulated alternating-current signal by a photomultiplier, the frequency-modulated alternating-current signal is processed by a micro-current lock-in amplifier to obtain a direct-current analog signal having good linear relationship with the analyzed elements, the direct-current analog signal is subjected to data processing by a microprocessor to obtain a digital signal, and the digital signal is transmitted to a computer data workstation for storing, processing and printing, and realizing control on a spectrometer operating process. The invention is simple in operation, high in sensitivity and good in stability, and the detection limit of sodium ion, potassium ion, iron element and copper element is smaller than 0.1mug/L, which reaches the international leading level.
Owner:深圳市沁泓科技有限公司 +1

Novel high-efficiency thermionic power supply

The invention relates to a novel high-efficiency thermionic power supply. The novel high-efficiency thermionic power supply is characterized in that an emitting electrode (1) is made of thermionic emitting material of which the melting point is higher than the temperature of a high-temperature heat source (7); a receiving electrode (2) is made of non-thermionic emitting material of which the melting point is higher than the temperature of the high-temperature heat source (7); the emitting electrode (1) and the receiving electrode (2) are arranged in a heat-insulating casing (6) and are located in a same high-temperature heat chamber (4); the emitting electrode (1) and the receiving electrode (2) are connected with an electric pump direct current power supply (11) in series through a lead (9) and a lead (10); the thermionic emission of the emitting electrode (1) is caused by heating the emitting electrode (1) through the high-temperature heat source (7), so that the electromotive force of the receiving electrode (2) is higher than the electromotive force of the emitting electrode (1) and further extra power is provided for thermions to move to the receiving electrode (2); the thermions fly to the receiving electrode (2) under the push of the driving electromotive force of the receiving electrode (2) and an induced electric field of the electric pump direct current power supply (11), pass through a clearance between the two electrodes, and are captured on the receiving electrode (2). According to the novel high-efficiency thermionic power supply, various energy sources, such as nuclear energy, heat energy and light energy, can be converted into ionization energy as much as possible.
Owner:张维国

Composite ionization source for vacuum ultraviolet light ionization and chemical ionization

The invention relates to a mass spectrometry device and particularly relates to a composite ionization source for vacuum ultraviolet (uv) light ionization and chemical ionization on the basis of increase of an ion tunnel radio frequency electric field. The composite ionization source comprises a vacuum uv light source and an ionization room chamber, multiple transmission electrodes and ion funnels are coaxially arranged with intervals in an ionization room, the transmission electrode far from an uv light inlet is pasted with a metal grid mesh, uv light emitted by the vacuum uv light source irradiates on the metal grid mesh to generate photoelectrons, and a radio frequency voltage is exerted on the ion funnel. The composite ionization source is on the basis of vacuum uv light ionization, a photoelectron ionization reagent gas is utilized, a sample is facilitated by reagent ions to generate chemical ionization, efficiency of chemical ionization triggered by the photoelectrons can be improved through the ion funnel radio frequency electric field, in combination with the ion focusing function of the ion funnel, detection sensitivity is improved, moreover, compounds of which ionization energy is greater than vacuum uv light photon energy can be ionized through chemical ionization, and the ionizable compound scope is expanded.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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