The invention relates to the field of conductive composite materials and discloses a method for preparing a field reversible nonlinear conductive
composite material, the material prepared by the method and application of the material. The method includes weighing AgNWs, adding the AgNWs into absolute
alcohol, adding TGA, stirring the mixture, then adding TBT, fully mixing the mixture, then heatingthe mixture to 180-210 DEG C, reacting the mixture for 9-11 h, performing
centrifugation to obtain precipitate, and washing the precipitate to obtain AgNWs@TiO2; weighing PVA and water, stirring themixture, heating the mixture to 85-95 DEG C and stirring the mixture until the PVA is dissolved to obtain a
solution G; weighting the AgNWs@TiO2, adding the AgNWs@TiO2 into the
solution G, stirring the solution at 60-70 DEG C for 10-15 h to obtain a
composite material fluid, and performing
casting to form film, then the field reversible nonlinear conductive
composite material can be obtained afterthe
solvent is volatilized. The
mass ratio of the AgNWs, the TGA and the TBT is 100:210-220:20; the
degree of polymerization of the PVA is 1750 + / - 50, and the alcoholysis degree is 99%; and the massratio of the PVA to the AgNWs@TiO2 is 60:30-50. The method has characteristics including a simple process, a low cost, short reaction time and easy preparation in a large scale. The prepared composite material is uniform in distribution, good in dispersibility and free of agglomeration, and can be applied in
overvoltage protection,
lightning stroke surge and self-adaption
electromagnetic pulse protection fields.