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52results about How to "Good degradation activity" patented technology

Carbon-aerogel-carried bimetal organic framework electro-Fenton cathode and preparation method thereof

The invention relates to a carbon-aerogel-carried bimetal organic framework electro-Fenton cathode and a preparation method thereof. The preparation method comprises the following steps: by using a block carbon aerogel as a substrate electrode, carrying out hydrothermal reaction to load a bimetal organic framework onto the substrate electrode, filtering, washing, and carrying out vacuum drying to obtain the carbon-aerogel-carried bimetal organic framework electro-Fenton cathode, wherein the bimetal organic framework is a Fe / Co bimetal organic framework. Compared with the prior art, by combining the photocatalytic technique and electro-Fenton, the carbon-aerogel-carried bimetal organic framework electro-Fenton cathode can degrade organic pollutants by using the higher-efficiency low-energy-consumption advanced oxidation technique, thereby providing a new way for using the electro-Fenton cathode in the photocatalytic / electro-Fenton combined technique for treating nondegradable organic pollutants. The carbon-aerogel-carried bimetal organic framework electro-Fenton cathode has the advantages of simple technical operation, energy saving and high efficiency, and has very wide application range in the field of actual water treatment.
Owner:TONGJI UNIV

Rare earth co-doped BiVO4 photocatalyst with upconversion characteristic and preparing method and application thereof

The invention relates to a rare earth co-doped BiVO4 photocatalyst with upconversion characteristic and a preparing method and application thereof. The preparing method includes the steps that bismuth nitrate pentahydrate and ammonium metavanadate are dissolved in water to prepare mother liquor A and mother liquor B, the mother liquor B is added into the mother liquor A by the molar ratio of Bi:V=1:1 to obtain mixed liquor, the pH value of the mixed liquor is adjusted to be 8, two kinds of rare earth nitrate are sequentially added into the mixed liquor, the molar ratio of total amount of the two rare earth elements: bismuth=(10.52-10.55):100, and finally the rare earth co-doped BiVO4 photocatalyst with upconversion characteristic is prepared through a microwave hydrothermal method in a heat preservation mode. The microwave hydrothermal synthesis technology is adopted for fast synthesizing the rare earth co-doped BiVO4 photocatalyst with high degradation activity and upconversion characteristic, the rare earth co-doped BiVO4 photocatalyst has excellent degradation activity under simulated sunlight, the photocatalysis efficiency of pure-phase BiVO4 powder is greatly improved, and the rare earth co-doped BiVO4 photocatalyst has wide application prospects.
Owner:SHAANXI UNIV OF SCI & TECH

GY2B degrading bacteria immobilizing ball as well as preparation method and application thereof

The invention belongs to the technical field of microbial degradation of organic pollutants, and discloses a GY2B degrading bacteria immobilizing ball as well as a preparation method and application thereof. The GY2B degrading bacteria immobilizing ball is a gel ball formed by embedding GY2B degrading bacteria by taking a crosslinking polymerization product of polyvinyl alcohol, algin and kaolin as a carrier. The preparation method disclosed by the invention comprises the following steps: (1), sequentially adding polyvinyl alcohol and algin into water, heating, stirring and dissolving respectively, adding kaolin, and stirring and mixing uniformly so as to obtain a mixed solution; (2), cooling the mixed solution to room temperature under irradiation of ultraviolet light, adding a GY2B degrading bacteria suspension, and uniformly stirring to obtain a bacteria embedding solution; and (3), dropwise adding the bacteria embedding solution into a crosslinking solution, and crosslinking, solidifying and condensing to obtain the GY2B degrading bacteria immobilizing ball. The GY2B degrading bacteria immobilizing ball has more thorough, rapid and steady degrading effects to phenol; furthermore, a steady degrading environment can be provided; and the GY2B degrading bacteria immobilizing ball is adaptive to a toxic environment.
Owner:SOUTH CHINA UNIV OF TECH

Preparation and application method of special microorganism composite bacterial agent for directly decomposing and fermenting crop straws to generate marsh gas

InactiveCN109957527AIncrease productionInitial gas production time shortenedFungiBacteriaClostridium pasteurianumBacillus licheniformis
The invention discloses preparation and an application method of a special microorganism composite bacterial agent for directly decomposing and fermenting crop straws to generate marsh gas. The special microorganism composite bacterial agent is liquid or solid, and is formed by fermenting, culturing, combining and compositing of one or more of bacillus cereus, bacillus subtilis, bacillus licheniformis, bacillus megaterium, bacillus mucilaginosus, bacillus circulans, bacillus sphaericus, clostridium sporogenes, clostridium acetobutylicum, clostridium pasteurianum, clostridium beijerinckii, clostridium thermocellum, trichoderma viride, trichoderma pseudokoningii and aspergillus niger. Meanwhile, by taking the special microorganism composite bacterial agent as an inoculation bacterial agent,the invention provides the application method for decomposing the crop straws and accelerating the fermentation to generate marsh gas; the crop straws treated by the microorganism composite bacterialagent have fast fermentation speed, large marsh gas generation quantity, low treating cost and no secondary pollution, can be fermented to generate the marsh gas under the condition of no any faeces of poultry and livestock, and the application range is quite wide.
Owner:王旭宁

Visible light responsive nitride photocatalytic material and preparation method

The invention discloses a visible light responsive nitride photocatalytic material and a preparation method. The preparation method comprises: growing multiple layers of GaN-based epitaxial thin films in PIN heterostructures on a sapphire substrate by adopting a MOCVD technology; using an InGaN/GaN multiple quantum well or a superlattice as a light absorption layer; and then transferring the GaN-based epitaxial thin films to a conductive substrate, and peeling the sapphire substrate to obtain the photocatalytic material. By adopting the InGaN/GaN multiple quantum well or a superlattice as the light absorption layer, the difficulty of growing thick InGaN by MOCVD is overcome; by doping the In component, the photocatalytic material has visible light responsiveness; photon-generated carriers can be effectively separated as a result of a built-in electric field in the PIN heterostructures, so that the material has a high photovoltaic conversion efficiency, and the catalytic activity of the material is greatly improved. The photocatalytic material illuminated by visible light shows excellent degradation activity to azo dyes such as methyl orange and the like, so that the photocatalytic material can be used as an electrode of a photoelectrochemical pool for degrading organic pollutants.
Owner:PEKING UNIV

Isoepitaxial-growth gallium-nitride-base photocatalytic material and preparation method thereof

InactiveCN106268906ASolve the problem of poor crystal qualityEfficient separationPhysical/chemical process catalystsLattice mismatchGallium nitride
The invention discloses an isoepitaxial-growth gallium-nitride-base photocatalytic material and a preparation method thereof. The gallium-nitride-base photocatalytic material sequentially comprises an n-type gallium-nitride-base substrate, a gallium-nitride-base epitaxial layer and a metal layer from bottom to top. The GaN-base photocatalytic material isoepitaxial growth on the n-type gallium-nitride-base substrate is adopted to solve the problem of poor epitaxial layer crystal quality of the heteroepitaxy growth due to lattice mismatch and thermal mismatch, thereby omitting the step of growing the buffer layer and other steps for enhancing the heteroepitaxy grown crystal quality. By adopting the n-type gallium-nitride-base substrate, the substrate and GaN-base epitaxial layer grown by MOCVD (metal-organic chemical vapor deposition) together constitute the PIN heterostructure, and the photon-generated carrier can be effectively separated under the action of the built-in field, thereby enhancing the catalytic activity of the material. The nitride photocatalytic material has excellent degradation activity for methyl orange and other azo dyes under the irradiation of light, which indicates that the photocatalytic material has potential application value in the field of photocatalysis and has wide application prospects in the aspect of sewage treatment.
Owner:PEKING UNIV

A rare-earth co-doped bivo with upconversion properties 4 Photocatalyst and its preparation method and application

The invention relates to a rare earth co-doped BiVO4 photocatalyst with upconversion characteristic and a preparing method and application thereof. The preparing method includes the steps that bismuth nitrate pentahydrate and ammonium metavanadate are dissolved in water to prepare mother liquor A and mother liquor B, the mother liquor B is added into the mother liquor A by the molar ratio of Bi:V=1:1 to obtain mixed liquor, the pH value of the mixed liquor is adjusted to be 8, two kinds of rare earth nitrate are sequentially added into the mixed liquor, the molar ratio of total amount of the two rare earth elements: bismuth=(10.52-10.55):100, and finally the rare earth co-doped BiVO4 photocatalyst with upconversion characteristic is prepared through a microwave hydrothermal method in a heat preservation mode. The microwave hydrothermal synthesis technology is adopted for fast synthesizing the rare earth co-doped BiVO4 photocatalyst with high degradation activity and upconversion characteristic, the rare earth co-doped BiVO4 photocatalyst has excellent degradation activity under simulated sunlight, the photocatalysis efficiency of pure-phase BiVO4 powder is greatly improved, and the rare earth co-doped BiVO4 photocatalyst has wide application prospects.
Owner:SHAANXI UNIV OF SCI & TECH

A kind of gy2b degrading bacteria immobilized pellet and its preparation method and application

The invention belongs to the technical field of microbial degradation of organic pollutants, and discloses a GY2B degrading bacteria immobilizing ball as well as a preparation method and application thereof. The GY2B degrading bacteria immobilizing ball is a gel ball formed by embedding GY2B degrading bacteria by taking a crosslinking polymerization product of polyvinyl alcohol, algin and kaolin as a carrier. The preparation method disclosed by the invention comprises the following steps: (1), sequentially adding polyvinyl alcohol and algin into water, heating, stirring and dissolving respectively, adding kaolin, and stirring and mixing uniformly so as to obtain a mixed solution; (2), cooling the mixed solution to room temperature under irradiation of ultraviolet light, adding a GY2B degrading bacteria suspension, and uniformly stirring to obtain a bacteria embedding solution; and (3), dropwise adding the bacteria embedding solution into a crosslinking solution, and crosslinking, solidifying and condensing to obtain the GY2B degrading bacteria immobilizing ball. The GY2B degrading bacteria immobilizing ball has more thorough, rapid and steady degrading effects to phenol; furthermore, a steady degrading environment can be provided; and the GY2B degrading bacteria immobilizing ball is adaptive to a toxic environment.
Owner:SOUTH CHINA UNIV OF TECH
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