The invention relates to a double-doped grouting material for repairing a pavement and a preparation method of the double-doped grouting material. The double-doped grouting material is prepared from the following components in parts by weight: 50 to 70 parts of silicate cement, 20 to 30 parts of aluminate cement, 5 to 8 parts of silica fume, 10 to 15 parts of coal ash, 8 to 12 parts of barite powder, 1 to 3 parts of retarding admixture, 10 to 15 parts of waterborne epoxy resin, 3 to 8 parts of polyurethane, 0.5 to 0.8 part of antioxidant, 0.1 to 0.3 part of defoaming stabilizer, 1 to 4 parts of coupling agent, 0.3 to 0.5 part of surfactant, 3 to 8 parts of waste rubber powder, 0.05 to 0.2 part of cement reinforcing agent, and 0.1 to 0.3 part of water retaining agent. The double-doped grouting material prepared by the invention has high permeability, impact and wear resistance, high strength, high toughness, high temperature resistance and good durability, can solidify loose particles,has good binding property with original pavement concrete and is suitable for repairing various pavements.