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30results about How to "Low slag production" patented technology

Compound dephosphorization agent with converter slag as raw material and preparing method thereof

The invention discloses a molten iron pretreatment compound dephosphorization agent with converter slag as the raw material, and the compound dephosphorization agent contains the following raw materials by weight: 45 to 55 percent of converter slag, 3 to 5 percent of quartz sand, 22 to 34 percent of steel-rolling iron sheet, 3 to 6 percent of bauxite, 10 to 14 percent of soda and 0 to 5 percent of fluorite; the raw materials meeting the ingredient demands are evenly mixed according to the proportions after being crushed, and then the product with the diameter being 20 to 50mm is produced after ball-milling, screen separation, palletizing and drying. The compound dephosphorization agent realizes cyclic utilization of the converter slag which accounts for 45 to 55 percent, thus reducing the produced slag amount in the steel-making process and the environmental load; the converter slag contains plenty of CaO and FeO, which can reduce consumption of lime to a certain degree, thus increasing the metal yield rate and reducing the steel-making cost; the compound dephosphorization agent has low melting point, slag can be formed fast, the liquidity is good, thus shortening the treatment time, the dephosphorizing efficiency is high, and the dephosphorized final slag has low alkalinity and low melting point.
Owner:CHONGQING UNIV

Method for preparing sodium chromate by mixing chromite and ferrochrome and device for method

The invention discloses a method for preparing sodium chromate by mixing chromite and ferrochrome and a device for the method. The method comprises the following steps: measuring and mixing chromite and ferrochrome with sodium carbonate, sodium nitrate and sodium peroxide; pelleting the mixture with extracted liquid sodium chromate in a pelletizer; drying in a drier; returning part of the clinker to a flame kiln after the material is dried and cooled, so that chromite and ferrochrome are decomposed and oxidized in the form of fused liquid phase in molten salts so as to obtain the clinker of sodium chromate; and continuously soaking, filtering and cleaning after the clinker is cooled so that a chromium chemical primary product of liquid sodium chromate is obtained, wherein the flame kiln comprises a U-shaped kiln body, a partition wall and a low-position molten salt suction port, wherein the partition wall and the low-position molten salt suction port are arranged in the U-shaped kiln body; one or more blowing oxygen lances and one or more charging holes are arranged at the top of the kiln body, and a smoke outlet is arranged on the upper side of the kiln; and one or more oxygen lances are arranged at the bottom of the kiln. According to the method disclosed by the invention, the oxidation rate is as high as 98%, the clinker extraction rate is as high as 99.97%, and the chromium yield is 97.96%.
Owner:HUBEI POLYTECHNIC UNIV

Method for treating arsenic in waste smelting acid by using copper slag

The invention discloses a method for treating arsenic in waste smelting acid by using copper slag, and belongs to the field of heavy metal pollution treatment and metallurgical solid waste utilization. The method includes firstly subjecting the copper slag to drying, ball milling and magnetic separation to obtain iron-rich copper slag and other impurities; subjecting the iron-rich copper slag to high-temperature pretreatment at 500-800 DEG C; subjecting the high-temperature iron-rich copper slag to water quenching through high-speed water blowing; then drying and grinding the copper slag afterwater quenching; adding H2O2 into waste acid and mixing to perform oxidation pretreatment at 60-80 DEG C; then adding the copper slag into the waste acid after oxidation pretreatment; performing an arsenic removing reaction at atmospheric pressure under stirring; and finally performing solid liquid separation. The method achieves arsenic removal with cheap copper slag, reduces sludge storage volume in the process of waste acid treatment when compared with a traditional arsenic removal process, and achieves an effect of treating waste with a waste material. The method has characteristics of simple process operation, a low production cost and a wide market prospect.
Owner:KUNMING UNIV OF SCI & TECH

Treatment method of lead-zinc smelting waste acid

ActiveCN111661950AImprove the separation effect of nanofiltrationLow costZinc sulatesWaste water treatment from metallurgical processEngineeringSodium sulfate
The invention provides a treatment method of lead-zinc smelting waste acid. The method comprises the following steps: (1) adding ZnO into the smelting waste acid, and carrying out a neutralization reaction to obtain a neutralized waste acid solution; (2) adding an arsenic removal agent into the neutralized waste acid solution, carrying out an arsenic removal reaction, and filtering after the reaction is completed to obtain arsenic slag and an arsenic-removed mother liquor; (3) mixing the arsenic-removed mother liquor with sodium sulfate and pure water, and carrying out nanofiltration to obtainnanofiltered concentrated water and a fluorine-containing chlorine solution; (4) carrying out RO concentration on the fluorine-containing chlorine solution to obtain RO pure water and RO concentratedwater; and (5) adding a precipitant into the RO concentrated water, and carrying out a defluorination precipitation reaction and solid-liquid separation to obtain a sodium chloride-containing solution and calcium fluoride slag. The treatment method provided by the invention is simple and safe in operation management, can effectively reduce the operation energy consumption and the treatment cost,can recover sulfuric acid in the waste acid at the same time, and ensures that the water quality index of the waste acid reaches the standard and is discharged.
Owner:湖南中金岭南康盟环保科技有限公司

Method for producing electrolytic manganese metal by lixiviating sinter ore by adding ferrous sulphate in replacement of manganese carbonate ore

InactiveCN101709391ALow costStable ore sourceElectrolysisFiltration
The invention discloses a method for producing electrolytic manganese metal by lixiviating sinter ore by adding ferrous sulphate in replacement of manganese carbonate ore. The method comprises the working procedures of lixiviation and oxidation, neutralization, filtration, purification, electrolyzation and the like, and is characterized in that the process of lixiviation and oxidation is implemented by injecting anolyte enough to lead the material to react into the lixiviation vessel, adding concentrated sulfuric acid, adding sinter ore and finally adding ferrous sulphate for lixiviation for 3-4 hours at 70-75 DEG C; adding ammonia water immediately when Fe2+ in the feed liquid is less than or equal to 0.001g/l so as to carry out neutralization, testing the pH value of the feed liquid several times during the process of neutralization, and stopping adding ammonia water when full-valent Fe up to standard is less than or equal to 0.001g/l and the pH value reaches 6.8-7.2. The invention can reduce production cost, and solve the difficulty in purchasing manganese carbonate ore. The sinter ore contains high grade manganese, therefore, ore input quantity is small, and correspondingly the slag quantity and fee liquid carried away by the slag are little. No carbon dioxide gas is exhausted during lixiviation with sinter ore as raw material, thus working environment is improved.
Owner:CITIC JINZHOU METAL

Reverse osmosis recycling device of electrophoresis phosphating wastewater

The invention discloses a reverse osmosis recycling device of electrophoresis phosphating wastewater. The reverse osmosis recycling device of the electrophoresis phosphating wastewater comprises an assembly line area and a processing area, wherein the assembly line area includes a first soaking pool, a second soaking pool, a third soaking pool, a first phosphating water washing pool, a fourth soaking pool, a pure water prewash pool and a shack body workpiece outlet; the processing area includes a pure water washing and soaking pool, a second phosphating water washing pool, a phosphating pool,a meter adjusting pool and a degreasing washing pool; the first soaking pool, the second soaking pool, the third soaking pool and the fourth soaking pool are in through connection, and the first phosphating water washing pool is positioned between the third soaking pool and the fourth soaking pool; and the fourth soaking pool is arranged between the first phosphating water washing pool and the pure water prewash pool. According to the reverse osmosis recycling device of the electrophoresis phosphating wastewater, a cleaning tank communicates with a pipeline, and a circulating water pump is added to make clear water flow at a plurality of stations for multiple use, the water consumption is reduced, and the cleaning process of soaking, spraying, soaking and spraying is used, the extremely low water consumption is realized, and meanwhile, the cleaning effect of a workpiece is controlled, and the quality of electrophoretic coating of the workpiece and the stability of electrophoretic bathare guaranteed.
Owner:襄阳市志达海成科技实业有限公司

A method for extracting copper and removing iron from copper ore acid leaching solution

The invention discloses a method for extracting copper and removing iron from acid leaching liquid of copper ore, which comprises crushing secondary copper oxide ore and secondary copper sulfide ore and mixing them for wet heap leaching; spraying and leaching with dilute sulfuric acid to obtain weak Acidic leaching solution; the leaching solution extracts copper through extraction or ion exchange to obtain copper-enriched solution and copper-poor solution; the copper-rich solution is electrolytically deposited to obtain cathode copper; the copper-depleted solution is continuously deironed at high temperature and high pressure under an oxidizing atmosphere, and the obtained pulp is passed through Hematite slag is obtained by filtration, and part of the copper-poor liquid is acidified and oxidized and sent to the storage yard for circular leaching. The present invention utilizes iron ions and copper sulfide ore to undergo oxidation-reduction in the heap leaching process, and the iron ions in the heap leaching solution mainly exist in the form of divalent iron ions, which eliminates the step of reducing divalent iron ions for the subsequent extraction of copper, and adopts high temperature The high-pressure method of iron removal has a small amount of slag production and low environmental protection pressure, and the iron slag can be reused; the sulfuric acid produced in the iron removal process does not need to be neutralized, and can be directly returned to the heap leaching for recycling, and the comprehensive utilization effect is good.
Owner:HENAN GONGXIN ENVIRONMENTAL PROTECTION & TECH CO LTD

Three-phase catalytic oxidation preparation technology of soluble chromate

ActiveCN102320661BAvoid generatingReduce the difficulty of separation and recoveryChromates/bichromatesCatalytic oxidationOxygen
The invention relates to a preparation technology of chromate, specifically to a three-phase catalytic oxidation preparation technology of soluble chromate. The technology comprises the following steps of: heating alkali liquor with concentration of 20-60% to 50-300 DEG C, then, mixing chromite or carbon ferrochrome with the alkali liquor according to mass ratio of Cr2O3 : alkali liquor = 1 : 1.5-10 to form suspending liquid, and introducing the suspending liquid into a reactor; continuously inputting the air or the oxygen heated to 50-300 DEG C to the bottom of the reactor through a pipeline; setting a catalyst in the reactor according to the mass ratio of catalyst : Cr2O3 = 0.1-1.5 : 100, maintaining the temperature of the suspending liquid in the reactor at 50-300 DEG C, executing gas-liquid-solid three-phase bubbling reaction for 0.5-6 hours to generate soluble chromate raw products and chromium residues; removing impurities through filtering and crystallization to obtain the chromate. With the three-phase catalytic oxidation preparation technology of the soluble chromate, Cr2O3 conversion rate is high, reaction speed is fast, energy consumption is low, residue quantity is low, environment pollution is less, equipment investment is low and corrosion is low.
Owner:CHONGQING MINFENG CHEM

Method for preparing sodium chromate by mixing chromite and ferrochrome and device for method

The invention discloses a method for preparing sodium chromate by mixing chromite and ferrochrome and a device for the method. The method comprises the following steps: measuring and mixing chromite and ferrochrome with sodium carbonate, sodium nitrate and sodium peroxide; pelleting the mixture with extracted liquid sodium chromate in a pelletizer; drying in a drier; returning part of the clinker to a flame kiln after the material is dried and cooled, so that chromite and ferrochrome are decomposed and oxidized in the form of fused liquid phase in molten salts so as to obtain the clinker of sodium chromate; and continuously soaking, filtering and cleaning after the clinker is cooled so that a chromium chemical primary product of liquid sodium chromate is obtained, wherein the flame kiln comprises a U-shaped kiln body, a partition wall and a low-position molten salt suction port, wherein the partition wall and the low-position molten salt suction port are arranged in the U-shaped kiln body; one or more blowing oxygen lances and one or more charging holes are arranged at the top of the kiln body, and a smoke outlet is arranged on the upper side of the kiln; and one or more oxygen lances are arranged at the bottom of the kiln. According to the method disclosed by the invention, the oxidation rate is as high as 98%, the clinker extraction rate is as high as 99.97%, and the chromium yield is 97.96%.
Owner:HUBEI POLYTECHNIC UNIV

Method for producing electrolytic manganese metal by lixiviating sinter ore by adding ferrous sulphate in replacement of manganese carbonate ore

InactiveCN101709391BLow costStable ore sourceElectrolysisFiltration
The invention discloses a method for producing electrolytic manganese metal by lixiviating sinter ore by adding ferrous sulphate in replacement of manganese carbonate ore. The method comprises the working procedures of lixiviation and oxidation, neutralization, filtration, purification, electrolyzation and the like, and is characterized in that the process of lixiviation and oxidation is implemented by injecting anolyte enough to lead the material to react into the lixiviation vessel, adding concentrated sulfuric acid, adding sinter ore and finally adding ferrous sulphate for lixiviation for 3-4 hours at 70-75 DEG C; adding ammonia water immediately when Fe2+ in the feed liquid is less than or equal to 0.001g / l so as to carry out neutralization, testing the pH value of the feed liquid several times during the process of neutralization, and stopping adding ammonia water when full-valent Fe up to standard is less than or equal to 0.001g / l and the pH value reaches 6.8-7.2. The invention can reduce production cost, and solve the difficulty in purchasing manganese carbonate ore. The sinter ore contains high grade manganese, therefore, ore input quantity is small, and correspondingly the slag quantity and fee liquid carried away by the slag are little. No carbon dioxide gas is exhausted during lixiviation with sinter ore as raw material, thus working environment is improved.
Owner:CITIC JINZHOU METAL

A coating control method and its application

The invention discloses a plating control method. In the process that strip steel is separated from the solution surface of a plating solution, plating solution brought out of the solution surface by the strip steel is subjected to ultrasonic vibrating treatment through ultrasonic waves at first, and then jetting treatment is conducted through an air knife device. A curved surface of the plating solution brought out of the solution surface by the strip steel is formed between the strip steel and the solution surface, and the ultrasonic wave acts on plating solution within the range of the curved surface. The viscosity of nonferrous liquid metal is lowered through an ultrasonic device, and the splatter effect of liquid metal adhered to the strip steel surface is produced through the vibration produced by the ultrasonic wave in the liquid metal, so that a part of liquid metal is automatically stripped from the strip steel surface and the weight of nonferrous liquid metal brought out by the strip steel in operation is lowered. The accurate control over the thickness of plating can be achieved through the air knife scraping device with low gas pressure and flow. The slag production amount is greatly reduced; the pollution of noise and dust is also reduced; the design and manufacturing cost of an air knife is reduced; the problem of plating of thin plating in high speed condition is solved.
Owner:CISDI ENG CO LTD

Oxygen blowing and coal injection secondary lead smelting furnace and oxygen blowing and coal injection method

The invention discloses an oxygen blowing and coal injection secondary lead smelting furnace and an oxygen blowing and coal injection method, and belongs to the technical field of non-ferrous metal smelting. A discharge hole in the bottom of a coal injection tank is connected with a coal injection machine; the inlet end of the coal injection machine is connected with the gas outlet port of a gas storage tank, the outlet end of the coal injection machine is connected with a pulverized coal inlet of a coal injection oxygen lance through a coal injection pipe, and the coal injection oxygen lance is inserted into a smelting furnace body; a gas outlet port of the gas storage tank is communicated with the coal injection tank, and a gas inlet port of the gas storage tank is connected with an air compressor through an air storage pressurizing valve; an upper sealing top of the coal injection tank is also connected with a coal feeding valve, a pressure gauge and a gas inlet valve, and the upper inlet end of the coal feeding valve is connected with a coal hopper; an oxygen station is connected with an oxygen inlet of the coal injection oxygen lance; and the gas outlet port of the gas storage tank is connected with a compressed air inlet of the coal injection oxygen lance. The oxygen blowing and coal injection secondary lead smelting furnace has the advantages of simple structure and low manufacturing cost; combustion is more complete, and the smelting efficiency is improved; and the pulverized coal goes deep into molten liquid slag to accelerate the decomposition of lead sulfate, so that the consumption of scrap iron or iron ore is greatly reduced, and the slag yield is reduced.
Owner:JIANGSU NEW CHUNXING RESOURCE RECYCLING CO LTD

Deironing method for reducing accumulated iron ions in electrodeposition solution

The invention discloses a deironing method for reducing accumulated iron ions in an electrodeposition solution. The method comprises the steps of adding the electrodeposition solution obtained by an electrodeposition process into a first deironing reaction tank, oxidizing divalent iron ions in the electrodeposition solution into trivalent iron ions by using a sodium chlorate solution to obtain a first mixed feed liquid, then continuously performing a low-temperature deironing reaction on the first mixed feed liquid, controlling the pH value of the low-temperature deironing reaction to enable the trivalent iron ions in the first mixed feed liquid to generate goethite, obtaining a second mixed feed liquid, and carrying out filter pressing treatment to obtain an electrodeposition solution after deironing. Therefore, the method has the advantages that the temperature requirement is low, the iron content of iron slag is high, the method is suitable for continuous production, the entrainmenteffect on valuable metal cobalt in the deironing process is weak, the removal efficiency of the divalent iron is improved by the deironing process, the energy consumption in the deironing process isreduced, the slag yield is less, and the operation stability is further enhanced by the continuous process.
Owner:GEM JIANGSU COBALT IND CO LTD

A kind of gentamicin fermentation waste liquid solid-liquid separation treatment method

The invention discloses a solid-liquid separation treatment method for gentamicin fermentation waste liquid. After conditioning and modifying the gentamicin fermentation waste liquid, the filtration specific resistance of the fermentation waste liquid is reduced, and then filtered through a plate and frame. It can effectively intercept suspended solids (SS), increase the filtration speed of fermentation waste liquid, and prevent suspended solids in fermentation waste liquid from entering the water treatment biochemical system and causing serious impact on the biochemical system. The key technology of conditioning modification is to add lovastatin fermented bacteria residue, which belongs to the waste of fermented raw materials, and has the characteristics of large particle size, light weight after drying, and water swelling. The water content of the fungus residue obtained after filtration in the invention can reach below 70%, which reduces the amount of residue produced and is beneficial to the subsequent drying and incineration of the fungus residue. At the same time, the filtered filtrate is clarified, free of SS, and COD can be reduced by 50%, which is beneficial to the subsequent entry into the biochemical treatment system.
Owner:福安药业集团烟台只楚药业有限公司

Compound dephosphorization agent with converter slag as raw material and preparing method thereof

The invention discloses a molten iron pretreatment compound dephosphorization agent with converter slag as the raw material, and the compound dephosphorization agent contains the following raw materials by weight: 45 to 55 percent of converter slag, 3 to 5 percent of quartz sand, 22 to 34 percent of steel-rolling iron sheet, 3 to 6 percent of bauxite, 10 to 14 percent of soda and 0 to 5 percent offluorite; the raw materials meeting the ingredient demands are evenly mixed according to the proportions after being crushed, and then the product with the diameter being 20 to 50mm is produced afterball-milling, screen separation, palletizing and drying. The compound dephosphorization agent realizes cyclic utilization of the converter slag which accounts for 45 to 55 percent, thus reducing theproduced slag amount in the steel-making process and the environmental load; the converter slag contains plenty of CaO and FeO, which can reduce consumption of lime to a certain degree, thus increasing the metal yield rate and reducing the steel-making cost; the compound dephosphorization agent has low melting point, slag can be formed fast, the liquidity is good, thus shortening the treatment time, the dephosphorizing efficiency is high, and the dephosphorized final slag has low alkalinity and low melting point.
Owner:CHONGQING UNIV
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