The invention relates to polyester heat-resistant canvas and a preparation method thereof. The preparation method comprises the steps that after modified polyester industrial yarn weaving cloth is padded with RFL impregnation liquid, a rubber layer is calendered on the surface of the modified polyester industrial yarn weaving cloth, then vulcanizing is conducted, and thus the polyester heat-resistant canvas is prepared; the modified polyester industrial yarn is prepared from a modified polyester melt through solid-phase polycondensation viscosity increasing, melting, metering, extruding, cooling, oiling, stretching, thermal shaping and winding; and a preparation method of modified polyester before solid-phase polycondensation viscosity increasing comprises the steps that terephthalic acid,ethylene glycol, dihydric alcohol with a trimethylsilyl pendant group, and dihydric alcohol with a tert-butyl pendant group are mixed evenly and then subjected to esterification reaction and polycondensation reaction successively; and the peeling grade of a prepared product is five, the use temperature range is minus 50 DEG C to plus 150 DEG C, the tear strength is greater than or equal to 7.0 N/mm, and the bonding strength is greater than or equal to 7.0 N/mm. The preparation method is simple in technology and low in cost; and the prepared product is high in bonding strength and good in application prospect.