The invention discloses a heating-free production method of polyaluminum chloride. The heating-free production method comprises the following steps of: firstly, diluting a raw material, i.e. hydrochloric acid, into a needed concentration, then adding bauxite under the condition of continuous stirring, adding a proper amount of calcium aluminate powder till the temperature of a reaction liquid rises to 84-87 DEG C, then automatically raising the temperature to 95-105 DEG C for reaction through heat release, observing the concentration of the reaction liquid after the reaction is ended, diluting the concentration of the reaction liquid to a needed concentration, then adding calcium aluminate powder for polymerization reaction, adjusting the concentration of the reaction liquid to a needed concentration after the reaction is ended, and obtaining a liquid product, i.e. the polyaluminum chloride. According to the heating-free production method of the polyaluminum chloride, steam heating isnot needed, thus heating equipment is omitted, and hydraulic acid steam generated in the reaction process is recycled through an absorbing device. Therefore, the heating-free production method disclosed by the invention has the advantages of being low in investment cost, saving energy, reducing consumption and emission, being beneficial to environmental friendliness and having obvious economic benefits and social benefits.