The invention discloses a synthesis method of a water-soluble triene cross-linking agent. The synthesis method comprises the following steps: adding triaminopropylamine (trpn), water and cationic surfactant into a reactor, evenly stirring and mixing, controlling the
reaction temperature in a range of 30 to 35 DEG C, dropwise adding chloropropene into the reactor within 4 hours, controlling the temperature under 35 DEG C, and keeping on stirring until the solution turns transparent after the adding of chloropropene so as to obtain the triene cross-linking agent. The invention also provides a synthesis method of a high-temperature resistant water-absorbing resin by using the triene cross-linking agent. The synthesis method comprises the following steps: adding a
mixed solution of copolymerization monomers and the triene cross-linking agent into a reactor, introducing
nitrogen gas for 30 minutes, then adding an initiator, stopping introducing
nitrogen gas after 10 minutes, carrying out reactions for 4 hours at a
room temperature so as to obtain a
reaction product, subjecting the
reaction product to an extruding and granulating process,
drying the granules at a temperature of 80 DEG C, and finally
grinding the dried granules so as to obtain the high-temperature resistant water-absorbing resin. The synthesis method of water-absorbing resin has the advantages of simple process and low
energy consumption, the saturated water
absorption rate of the resin in
distilled water with a temperature of 300 DEG C is 150 to 400 g / g, and the saturated water
absorption rate of the resin in a NaCl water solution with a
mass percentage of 0.9% is 50 to 130 g / g.