The invention discloses a
nest-shaped P, Fe-NiMoO4 self-supporting
electrode material and a preparation method thereof.The
electrode material is composed of NiMoO4 of a
nest-shaped structure formed by a P, Fe-co-doped
nanowire network growing on foamed
nickel in situ, (NH4) 6Mo7O24. 4H2O and FeCl3. 6H2O serve as raw materials, the treated foamed
nickel is placed in a high-pressure kettle, and a Fe-NiMoO4 sample is obtained through a hydrothermal method. The obtained Fe-NiMoO4 sample is placed in a tubular furnace, NaH2PO2.H2O is placed on the upstream of the tubular furnace,
nitrogen is introduced, and P and Fe-NiMoO4 samples are obtained through temperature
programming. P and Fe-NiMoO4 self-supporting
electrode materials grow on foamed
nickel in situ,
material transfer is facilitated, bubble overflow is promoted, and the working stability is improved; and meanwhile, P and Fe-co-
doping can increase the charge transfer capability,
expose more active sites and regulate the
electron configuration, and is beneficial to optimizing the
adsorption energy of an OER intermediate, thereby greatly improving the
catalytic efficiency. The
electrode material not only has excellent water
electrolysis oxygen production performance, but also can be used for electrocatalytic oxidation purification treatment of harmful substances such as H2S, drugs and organic dyes in industrial
wastewater.