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31 results about "Fluoroantimonic acid" patented technology

Fluoroantimonic acid is an inorganic compound with the chemical formula H₂FSbF₆ (also written H₂F[SbF₆], 2HF·SbF₅, or simply HF-SbF₅). It is an extremely strong acid, easily qualifying as a superacid. The Hammett acidity function, H₀, has been measured for different ratios of HF:SbF₅. While the H₀ of pure HF is −15, addition of just 1 mol % of SbF₅ lowers it to around −20. However, further addition of SbF₅ results in rapidly diminishing returns, with the H₀ reaching −21 at 10 mol %. The use of an extremely weak base as indicator shows that the lowest attainable H₀, even with > 50 mol % SbF₅, is somewhere between −21 and −23.

Phosphor and optical device using same

A phosphor for converting ultraviolet light or blue light emitted from a light emitting element into a visible white radiation having a high level of color rendering properties, containing a light emitting component prepared from a solid system of an alkaline earth metal antimonate and a system derived from the solid system and exhibiting intrinsic photoemission, such as a fluoroantimonate, a light emitting component prepared from a manganese(IV)-activated antimonate, a titanate, silicate-germanate, and an aluminate, a light emitting component prepared from a europium-activated silicate-germanate or from a system containing a sensitizer selected from a group consisting of europium (II) and manganese (II) as a secondary activator and having an orange color or a dark red color in the spectrum range over 600 nm, or a light emitting component composed of a mixture of eight or less light emitting components having different emission bands and brought to a state of continuous emission of about 380 to 780 nm exhibiting a color temperature of about 10,000 to 6,500 K and a color temperature of about 3,000 to 2,000 K by virtue of the superposition of the light emitting bands.
Owner:TOYODA GOSEI CO LTD +2

Single-component stable luminescent device embedding composition at room temperature

The invention discloses a single-component encapsulating adhesive of a luminescent device with constant room temperature, and the components are: (1) epoxide resin and / or a monomer containing polymerizable double bond of C=C; (2) cation solicitation; (3) accessory ingredient: one or a combination of more than one of silicone adhesive accessory ingredient, foam killer, release agent, toner, antioxidant, and light scattering agent; the cation solicitation is: one of or a combination of more than one of triarylated matte onium based six fluorine antimonite, triarylated matte onium based six fluorine phosphate, phenyl octyloxy iodobenzene onium based six fluorine antimonite, quaternary ammonium group six fluorine antimonite, and quaternary ammonium group triflate. The encapsulating adhesive of the luminescent device is easy to be preserved; the use is convenient; double constituents of encapsulating adhesive are not needed to be blended when the encapsulation is conducted; the polymerization temperature is relatively low; the curing time is short, and the cured colloid is colorless and transparent with high transmittancy; the agglutinated property is constant; the adhesive is applicable to the encapsulating of the luminescent device, particularly for the encapsulating of a luminous diode.
Owner:杨钢

Photosensitive resin composition, method for manufacturing structural body, and liquid discharge head

A photosensitive resin composition includes: a cation polymerizable compound; a photoacid generator having an anion portion represented by the formula 1 and a cation portion,wherein R represents a hydrocarbon group which may be substituted with a fluorine atom and has a total carbon number of 1 to 30; X is selected from the group consisting of a carbon atom and a phosphorous atom; Y is selected from the group consisting of —S(═O)2—, —O—CF2—, —C(═O)—CF2—, —O—C(═O)—CF2—, —C(═O)—O—CF2—, and a single bond; R has at least one fluorine atom when Y is —S(═O)2— or the single bond; m and n are integers selected from the group consisting of m+n=3 and n=0, 1, and 2 when X is the carbon atom; m and n are integers selected from the group consisting of m+n=6 and n=0 to 5 when X is the phosphorous atom; and R and Y may be different from each other when m is equal to or greater than 2; and a salt of an anion portion and a cation portion, wherein an acid strength of an acid derived from the anion portion is equal to or greater than that of hexafluorophosphoric acid and equal to or less than that of hexafluoroantimonic acid.
Owner:CANON KK

Polycarboxylic acid cement grinding aid production method

The present invention relates to a polycarboxylic acid cement grinding aid production method, which comprises: 1, adding maleic anhydride, ethylene glycol, polyethylene glycol, allyl polyethylene glycol, methacrylic acid, a catalyst benzenesulfonic acid, a polymerization inhibitor hydroquinone and an initiator benzoyl peroxide to a reaction kettle, stirring, heating to a temperature of 65-75 DEG C so as to carry out an esterification reaction, maintaining the reaction temperature for 2.5-3 h, and heating to a temperature of 100-120 DEG C so as to carry out a polymerization reaction to obtain a polycarboxylic acid cement grinding aid; and 2, after completing the reaction, adding sulfamic acid and a catalyst fluoroantimonic acid to obtain the modified polycarboxylic acid cement grinding aid. According to the present invention, the efficient polycarboxylic acid cement grinding aid function controlled design method is provided, and the grafting density of the short and long side chains and the molecular weight of the long side chains are adjusted so as to achieve controllability of the key parameters of the cement particle dispersion process and the cement hydration process, achieve the function compounding, and ensure the compatibility of the cement grinding aid and the concrete admixture.
Owner:湖州华仑助剂科技有限公司

Novel fluorocyclopentenone preparation method and product thereof

The invention discloses a novel fluorocyclopentenone preparation method and a product thereof. The novel fluorocyclopentenone preparation method is characterized by comprising the following step: methyl tert-butyl ether, enynic ester, gold (acetonitrile)[(2-biphenyl)di-tert-butylphosphine] hexafluoroantimonate (I) and N-fluorobenzenesulfonimide are added to react, so that fluorocyclopentenone is obtained. The novel method for preparing a fluorocyclopentenone compound which is provided by the invention ensures that an enynic ester compound can be converted into the fluorocyclopentenone compound. The whole reaction is carried out under normal temperature and normal pressure, conditions are mild, and energy consumption is low. The whole reaction is carried out by utilizing a one-pot method, operation is easy, yield is high, and the purity of the product is 98 percent or more. The reaction substrate range is wide, and not only the simple enynic ester compound but also complex compounds containing natural product groups are applicable. The developed fluorocyclopentenone compound has potential bioactivity, and can become a drug by subsequent testing or modification.
Owner:NANJING FORESTRY UNIV

Radiation sensitive material and method for forming pattern

A copolymer expressed by the following structural formulawas obtained by loading adamantyl methacrylate monomer and t-butyl acrylate monomer by 1:1, then conducting polymerization, adding AIBN as a polymerization initiator, and then conducting precipitation purification with methanol. Then to the copolymer, triphenylsulfonium hexafluoroantimonate was added to prepare a cyclohexanone solution. This solution was applied to a wafer, and exposed to a KrF excimer stepper and developed. The threshold energy Eth was 50 mJ / cm2. A 0.45 μm-wide L & S was formed at 130 mJ / cm2. The radiation sensitive material has good transparency and etching resistance, high sensitivity, and little peeling.
Owner:FUJITSU SEMICON LTD

2-(2,6-dicyanophenyl) imidazo [1,2-alpha] pyridine compound and preparation method thereof

ActiveCN106831765AAntiviral Biological ActivityAnti-apoptotic biological activityOrganic chemistrySodium bicarbonateDichloroethane
The invention discloses a 2-(2,6-dicyanophenyl) imidazo [1,2-alpha] pyridine compound obtained through a direct nitrile grouping reaction method of a 2-phenyl-imidazo [1,2-alpha] pyridine compound and N-cyan-N-phenyl p-methylphenyl sulphonylamine (NCTS). The reaction is characterized by utilizing dichloro (pentamethyl cyclopentadienyl) rhodium (III) dimer ([RhCp*Cl2]2) and silver hexafluoroantimonate (AgSbF6) as catalysts, adopting sodium bicarbonate (NaHCO3) as an additive, adopting 1,2-dichloroethane as a reaction solvent, and realizing nitrile grouping reaction of the 2-phenyl-imidazo [1,2-alpha] pyridine compound and the N-cyan-N-phenyl p-methylphenyl sulphonylamine (NCTS). The method is simple and efficient, a functionalization reaction type of the 2-phenyl-imidazo [1,2-alpha] pyridine compound is enriched, and meanwhile, a new reaction mode of the N-cyan-N-phenyl p-methylphenyl sulphonylamine (NCTS) is also realized. The method has significance on research and application of nitrile grouping reaction of the 2-phenyl-imidazo [1,2-alpha] pyridine compound.
Owner:ZHENGZHOU UNIV

Axially chiral biaryl compound with P-stereo center and synthesis method and application thereof

The invention discloses an axially chiral biaryl compound with a P-stereo center and a synthesis method and application thereof. The structural formula of the compound is shown in the specification, chiral trivalent rhodium [CpXRh(III)] is used as a catalyst, diaryl phosphonamide and diaryl acetylene are used as raw materials, and enantioselective coupling is conducted under the assistance of silver trifluoromethanesulfonate or silver hexafluoroantimonate and silver acetate to obtain the compound. Diarylacetylene is taken as an initial raw material, the compound is stable in property and easy to prepare, but the compound is seldom applied to arylation reaction. In the prior art, aryl arylation is mainly carried out by using brominated aromatic hydrocarbon, arylboronic acid and the like. The simple diarylacetylene is adopted as an arylation reagent, the axially chiral biaryl and the P-center chiral compound are stereoscopically and specifically synthesized through double activation of C-H bonds in the aryl phosphonamide and the diarylacetylene, and the method has the advantages of being mild in reaction condition, high in enantioselectivity, good in diastereoselectivity and the like.
Owner:SHAANXI NORMAL UNIV

Platinum(II) ammine selenourea complexes and methods of treating cancer

A platinum(II) complex of formula (I),or a pharmaceutically acceptable solvate or tautomer thereof, wherein R1 and R2 are each independently a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, an optionally substituted arylalkyl, or an optionally substituted aryl; or wherein R1 and R2 together form a five-, six-, or seven-membered ring with the nitrogen atoms to which they are attached; and X is a nitrate anion, a hexafluorophosphate anion, a hexafluoroantimonate anion, a trifluoromethanesulfonate anion, a tetrafluoroborate anion, a perchlorate anion, or a halide anion. A pharmaceutical composition containing the platinum(II) complex of formula (I), and a method of treating cancer are also disclosed.
Owner:KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS +1

Treatment method using flouroantimonic acid for digestion of trace impurity elements contained in high-purity chromic oxide

The invention relates to the field of detection pretreatment, and in particular relates to a treatment method using flouroantimonic acid for digestion of trace impurity elements contained in high-purity chromic oxide. After the chromic oxide is digested with the high-purity flouroantimonic acid, impurities are released from crystal lattices and boundaries, non-volatile impurities are retained after high-temperature volatilization of fluorine and antimony, and non-antimony and non-chromium elements are quantified after reconstitution with nitric acid. The method has an obvious digestion effecton the chromic oxide, has a good enrichment effect on the contained impurities, facilitates use ICP-MS or ICP-AES detection, improves the accuracy of instrument detection results and shortens the detection time.
Owner:DALIAN UNIV OF TECH QINGDAO NEW ENERGY MATERIALS TECH RES INST CO LTD

Chromium-free passivation method for zinc powder

The invention discloses a chromium-free passivation method for zinc powder. The preparation method comprises the following steps: adding a dispersing aid universal for water and oil into a water-soluble organic solvent, and uniformly stirring; adding zinc powder into the uniformly mixed medium, and uniformly stirring; and adding deionized water, a molybdenum-containing compound and silver hexafluoroantimonate, and uniformly stirring to obtain the passivated water-based zinc paste. According to a traditional zinc powder passivation method, zinc powder can be completely wrapped, so that the zinc powder loses the effect of an anti-rust pigment. According to the chromium-free passivation method for the zinc powder, the zinc powder can be stably stored in water for more than 6 months, and the electrochemical protection function of the zinc powder is not lost.
Owner:上海库曜新材料有限公司

Treatment method of trace impurity element content in high-purity chromium trioxide digested by fluoroantimonic acid

The invention relates to the field of detection pretreatment, and in particular relates to a treatment method using flouroantimonic acid for digestion of trace impurity elements contained in high-purity chromic oxide. After the chromic oxide is digested with the high-purity flouroantimonic acid, impurities are released from crystal lattices and boundaries, non-volatile impurities are retained after high-temperature volatilization of fluorine and antimony, and non-antimony and non-chromium elements are quantified after reconstitution with nitric acid. The method has an obvious digestion effecton the chromic oxide, has a good enrichment effect on the contained impurities, facilitates use ICP-MS or ICP-AES detection, improves the accuracy of instrument detection results and shortens the detection time.
Owner:DALIAN UNIV OF TECH QINGDAO NEW ENERGY MATERIALS TECH RES INST CO LTD

Synthesis of 4-oxo-5-(arylformyl acetate-2-yl)naphthalene-sulfoxide ylide hybrids

The invention discloses a method for synthesizing 4-oxo-5-(aroyl acetate-2-yl) naphthalene-sulfoxide ylide hybrid, and belongs to the technical field of organic synthesis. The synthesis method adopts arylformyl sulfoxide ylide 1 and α-diazocarbonyl compound 2 as raw materials, and in the presence of rhodium catalyst and silver hexafluoroantimonate additive, a series reaction is carried out to obtain 4-oxo-5-(arylmethyl) Acyl acetate-2-yl) naphthalene-sulfoxide ylide hybrid 3. Through the series reaction, the present invention has high atom economy; the operation process is simple and efficient; the reaction process does not require the participation of alkali or acid, and is more economical, green, and environmentally friendly; The synthesis of naphthalene-sulfoxide ylide hybrids provides an economical and practical new method.
Owner:HENAN NORMAL UNIV

Production process of curing agent for yarn impregnation

The invention relates to a production process of a curing agent for yarn impregnation. The production process is characterized by specifically comprising the following steps: S1, preparing sodium pyroantimonate; S2, preparing hexafluoroantimonic acid; S3, preparing a silver hexafluoroantimonate mother solution; S4, concentrating, cooling and crystallizing the silver hexafluoroantimonate mother liquor; and S5, recrystallizing and purifying the crude silver hexafluoroantimonate crystal. Antimonous oxide is mixed with an acetic acid solution containing hydrogen fluoride, and compared with a method of mixing antimonous oxide with a hydrofluoric acid aqueous solution or anhydrous hydrofluoric acid, the process has the advantages of mild reaction conditions, simple and easily available raw materials, low equipment requirements, high hexafluoroantimonic acid generation rate, fewer impurities and higher silver hexafluoroantimonate product yield. Hexafluoroantimonic acid reacts with silver carbonate to generate the silver hexafluoroantimonate mother solution, and then silver hexafluoroantimonate is prepared from sodium pyroantimonate and silver carbonate in a hydrogen fluoride aqueous solution in one step. The method has the advantages of mild reaction conditions, low raw material price, small environmental pollution and high impurity removal rate, and the purity of the finally obtainedproduct is high and reaches 99% or above.
Owner:如皋市丹凤纺织有限公司

A method for producing fluoroberyllic acid and ammonium fluoroberyllium from beryllium sulfate solution

The invention discloses a method for producing fluoroberyllium acid and ammonium fluoride beryllium from a beryllium sulfate-containing solution, comprising the following steps: (1) after adjusting the pH value of the beryllium sulfate-containing solution, extracting with an iron extracting agent to obtain extracted iron (2) extracting the post-iron solution with beryllium extraction agent to obtain the beryllium post-extraction solution and beryllium-carrying organic phase; (3) using a mixed solution of oxalic acid and sodium sulfite to extract the beryllium-carrying organic phase (4) back-extracting the washed organic phase with a hydrofluoric acid solution to obtain a fluoroberyllium acid solution; this method shortens the technological process of beryllium production and improves the recovery of beryllium rate, reduce production costs, and stabilize the quality of beryllium.
Owner:HUNAN RES INST FOR NONFERROUS METALS

Production process of cationic curing agent

The invention relates to a production process of a cationic curing agent. The production process is characterized by specifically comprising the following steps: S1, preparing sodium pyroantimonate; S2, preparing hexafluoroantimonic acid; S3, preparing a silver hexafluoroantimonate mother solution; S4, concentrating, cooling and crystallizing the silver hexafluoroantimonate mother solution; and S5, recrystallizing and purifying coarse silver hexafluoroantimonate crystals. According to the present invention, the mixing of the antimony trioxide and a hydrogen fluoride-containing acetic acid solution has advantages of mild reaction condition, simple and easily available raw materials, low equipment requirement, high generation rate of hexafluoroantimonic acid, less impurity content, and high yield of the silver hexafluoroantimonate product compared with the mixing of antimony trioxide and a hydrofluoric acid aqueous solution or anhydrous hydrofluoric acid. Hexafluoroantimonic acid reacts with silver carbonate to generate a silver hexafluoroantimonate mother solution; and then silver hexafluoroantimonate is prepared from sodium pyroantimonate and silver carbonate in a hydrogen fluoride aqueous solution in one step. The method is mild in reaction condition, low in raw material price, small in environmental pollution and high in impurity removal rate, and the purity of the finally obtained product is high and reaches 99% or above.
Owner:NANTONG SYNASIA NEW MATERIAL CO LTD

7-alkyl-n-pyrimidine indoline compound and its synthesis method

ActiveCN109180648BRich types of functionalization reactionsMultiple Feasibility PathwaysOrganic chemistryChromatographic separationBond cleavage
The invention discloses a 7-alkyl-N-pyrimidylindoline compound and a synthesis method thereof. The 7-alkyl-N-pyrimidylindoline compound has a general structural formula shown in the description. The synthesis method comprises: adding an N-pyrimidylindoline compound and a vinyl cyclopropane compound into a reaction tube in an argon environment, adding 1-adamantanecarboxylic acid, [Cp*Rh(CH3CN)3](SbF6)2 and silver hexafluoroantimonate into the reaction tube, then adding methanol into the reaction tube, carrying out a reaction process at 80-120 DEG C for 12h, and then carrying out leaching, thinlayer chromatographic separation and drying to obtain a desired product. The metal ruthenium (III) is used as a catalyst and methanol is used as a reaction solvent so that the carbon-carbon bond cleavage of vinylcyclopropane and activation of a 7-site carbon-hydrogen bond of an indoline compound are realized. The long alkyl chain with double bonds realizes a further functionalization reaction. Thesynthesis method is simple and efficient and has good selectivity. The 7-alkyl-N-pyrimidylindoline compound is easy to purify.
Owner:ZHENGZHOU UNIV

A kind of synthetic method containing 1-indanone skeleton spiro compound

The invention discloses a synthetic method of a spirocyclic compound containing 1-indanone skeleton. The method comprises the following steps: taking aromatic carboxylic acid and alpha, beta-unsaturated ketone as raw materials, taking any of p-cymene ruthenium chloride dimer, pentamethylcyclopetadienyl rhodium chloride dimmer, tris(acetonitrile)(pentamethylcyclopentadienyl)rhodium bis(hexafluoroantimonate) as a catalyst, taking any of anhydrous manganese acetate, manganese acetate tetrahydrate, anhydrous zinc acetate and zinc acetate as an additive, and thus synthesizing the spirocyclic compound containing 1-indanone skeleton by adopting a one-step method. The reaction comprises four steps such as conjugate addition reaction of aromatic carboxylic acid ortho-position C-H bond and alpha, beta-unsaturated ketone, intramolecular dehydration, Michael addition with second molecular alpha,beta-unsaturated ketone and intramolecular aldol condensation. The synthetic method has the characteristics that the raw materials are low in price and easy to obtain, the efficiency is high, the atom utilization rate is high, the reaction operation is simple and four new C-C bonds are constructed by adopting the one-step method.
Owner:SHAANXI NORMAL UNIV

Trivalent chromium ion doped fluoroantimonate near-infrared fluorescent material, preparation method and LED light source of trivalent chromium ion doped fluoroantimonate near-infrared fluorescent material

The invention discloses a trivalent chromium ion doped fluoroantimonate near-infrared fluorescent material and a preparation method thereof, and the preparation method comprises the following steps: dissolving a Sb source and a Cr source in an HF solution, stirring until the Sb source and the Cr source are dissolved, then adding a Na source, and continuously stirring to form a mixed solution; loading the mixed solution into reaction equipment for reaction, and washing and drying to obtain the Cr < 3 + > doped fluoroantimonate near-infrared fluorescent material, the chemical composition of the Cr < 3 + > doped fluoroantimonate near-infrared fluorescent material is NaSbF4: xCr < 3 + >, wherein x is equal to 0.5-5%. The Cr < 3 + >-doped fluoroantimonate near-infrared fluorescent material provided by the invention is high in fluorescence quantum efficiency and absorption efficiency, simple in preparation method and suitable for large-scale industrial production.
Owner:FOSHAN UNIVERSITY
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