The invention provides high polymer molecule modified waterproof and anticorrosive resin mortar and a preparation method thereof, and relates to the field of resin mortar materials. The composition comprises the following components in parts by weight: 60-80 parts of POSS modified epoxy resin; 5-10 parts of liquid chloroprene rubber, 5-10 parts of liquid polysulfide rubber, 5-10 parts of carboxyl-terminated polybutadiene, 10-15 parts of talcum powder, 10-15 parts of modified clay, 1-5 parts of N550 carbon black, 4-8 parts of expanded and vitrified micro bubbles, 4-8 parts of expanded polyphenyl particles, 5-10 parts of polycrystalline aluminum oxide fibers, 1-3 parts of 2, 4, 6-tri (dimethylaminomethyl) phenol, 1-3 parts of polypropylene glycol diglycidyl ether, 0.1-1 part of aminosilane,0.1-1 part of vinyltriethoxysilane, 3-6 parts of polyethylene wax, 1-3 parts of hydroxyethyl cellulose, 1-3 parts of a thixotropic agent, 5-10 parts of a binding agent, 5-10 parts of a diluent and 1-2parts of a curing agent. The high polymer molecule modified waterproof and anticorrosive resin mortar has excellent mechanical properties and excellent crack resistance, impermeability, compression resistance, alkali resistance, acid resistance and salt corrosion resistance, and all the properties meet the use requirements.