The invention discloses a cyanide-free gold electroplating solution and an electroplating process thereof, and belongs to the technical field of electroplating. The electroplating solution disclosed by the invention comprises 30-120 g/L of main complexants, 10-150 g/L of conductive salt, 20-80 g/L of carbonates, 0.1-15 g/L of other additives, 1-20 g/L of chloroauric acid and 0.1-1.0 g/L of stabilizers. According to the cyanide-free gold electroplating solution, hydantoin derivatives are used as the main complexants, and sulfites and tartrate are used as conductive salt; and then the stabilizers are added. In the electroplating process, complex gold ions can be adsorbed by the stabilizers effectively, and the stability of the electroplating solution is improved greatly; meanwhile, the effective coordination between the gold ions and the hydantoin derivatives can be promoted, and the electroplating efficiency is improved effectively. A gold plating prepared with the electroplating solution is fine in crystal, and high in binding force and corrosion resistance, and the electroplating solution is nontoxic, and high in stability, dispersibility and covering ability. Cyanide gold platingsolution can be replaced with the gold electroplating solution, and the gold electroplating solution has broad development prospects.