The invention discloses a method for preparing a temperature-resistant type compound bonding agent. The method comprises: a, esterifying reaction, namely adding trimethylolpropane, terephthalic acid, decanedioic acid, diglycol and neopentylene glycol into a polyester synthesis kettle, heating the mixture, and realizing complete esterificaiton after the reaction; b, polycondensation reaction, namely creating a low vacuum of -0.04 to -0.02MPa by pumping in the polyester synthesis kettle by pumping after the esterifying reaction is completed first, then creating a high vacuum of -0.09 to -0.05MPa by pumping in the polyester synthesis kettle with the temperature of the kettle kept between 245 and 255 DEG C during the high-vacuum pumping, and finally creating a volume of-0.094MPa by long-term pumping in the kettle, and after the long-vacuum pumping, completing the polycondensation reaction to obtain polyester polyhydric alcohol; and c, dissolution, namely cooling the prepared polyester polyhydric alcohol, adding acetic ether, and uniformly stirring the mixture to obtain the compound bonding agent. In the method, micromolecular tri-functionality polyhydric alcohol is added in the synthetic process of the polyester polyhydric alcohol, so that the prepared polyester polyhydric alcohol has more than two active end groups, and after the polyester polyhydric alcohol is cured by using a conventional multi-functionality curing agent, the crosslinking density is bigger and the temperature resistance is guaranteed.