The invention discloses a high-temperature-resistant brake pad. The high-temperature-resistant brake pad comprises a steel plate, a thermal insulation layer and a friction block, wherein the friction block is prepared from a phenol-formaldehyde resin composite, the phenol-formaldehyde resin composite is prepared from raw materials in parts by weight as follows: 15-30 parts of phenol-formaldehyde resin, 3-10 parts of epoxy resin, 3-10 parts of organic silicon resin, 5-10 parts of carbon fibers, 3-10 parts of aramid fibers, 2-8 parts of quartz fibers, 12-30 parts of potassium magnesium titanate lamellas, 5-15 parts of sodium iron titanate lamellas, 15-30 parts of ferrotitanium powder, 2-10 parts of corundum powder, 3-10 parts of barite powder, 2-8 parts of aluminum powder, 1-3 parts of talc powder, 1-5 parts of iron oxide, 2-8 parts of zirconium dioxide, 2-8 parts of petroleum coke, 1-3 parts of natural graphite, 2-5 parts of bamboo charcoal and 2-5 parts of graphene. The provided high-temperature-resistant brake pad has excellent high-temperature resistance, good impact resistance and heat stability, high wear resistance, small thermal expansivity and long service life.