24 results about "Nitrogen molecule" patented technology

[Problem] To provide a nitrogen fixation method and a nitrogen fixation device which are capable of significantly reducing energy and cost and are easy to put into practical use. [Solution] According to the present invention, water 14, which is brought into contact with air and has dissolved the air, is brought into contact with a photocatalyst (photocatalyst layer 5), and the photocatalyst is irradiated with ultraviolet rays (light source 91), and thus ammonia, nitric acid, or nitrous acid is generated in the water 14 from nitrogen molecules in the air dissolved in the water 14 by a photocatalytic reaction.

The integrated adsorption tower of the oxygenerator comprises an adsorption tower main body, a gas inlet integrated cover part and a gas outlet integrated cover part which are arranged at two ends of the adsorption tower main body, and a reversing valve arranged on the gas inlet integrated cover part, two molecular sieve cylinders and two air storage tanks are arranged in the adsorption tower main body, the nitrogen removal and noise reduction cylinder is positioned in the middles of the two molecular sieve cylinders and the two air storage tanks, the molecular sieve cylinders are communicated with the air storage tanks, the molecular sieve cylinders can be communicated with the nitrogen removal and noise reduction cylinder under the control of a reversing valve, the reversing valve controls air to alternately enter and remove nitrogen, the molecular sieve cylinders are filled with adsorbents, and the adsorbents are communicated with the nitrogen removal and noise reduction cylinder. The two molecular sieve barrels are integrated on one adsorption tower, so that the assembly difficulty is reduced, the production efficiency is improved, the space utilization rate is improved, and the nitrogen discharge noise is reduced by arranging the silencing barrel.

The invention relates to a granary nitrogen specificity monitoring system and method based on Li-LSX zeolite functionalized optical fiber, and the system comprises a transmitting unit which is used for transmitting an optical signal; the sensing unit is connected with the transmitting unit and is used for measuring a first resonance valley wavelength drift distance of an optical signal along with the change of the nitrogen concentration and the change of the environment temperature and pressure by utilizing the change of the refractive index after the lithium exchange low-silicon X-type zeolite selectively adsorbs nitrogen molecules; the reference unit is connected with the transmitting unit, is arranged in parallel with the sensing unit, and is used for measuring a second resonance valley wavelength drift distance of the optical signal along with the change of the environment temperature and pressure; and the receiving, demodulating and resolving unit is connected with the sensing unit and the reference unit, and is used for calculating the resonance valley wavelength drift amount caused by the nitrogen concentration according to the first resonance valley wavelength drift amount and the second resonance valley wavelength drift amount, and calculating the nitrogen concentration by using a preset model. The monitoring system has the advantages of high measurement precision, high response speed, stable performance and high reliability.

An air cleaning system (1) has a linear electrode (20) that generates electromagnetic resonance, an electric field probe (40) that measures the intensity of an electric field, and a control unit (70) that controls the power supplied to the linear electrode (20). The control unit (70) operates the frequency of the power supplied to the linear electrode (20) and the position at which the power is supplied to the linear electrode (20) to control the output value of a signal representing the intensity of the electric field to be maximum. The amount of generated ozone is monitored, and the control unit (70) operates in a manner to modulate the amplitude of the supplied power to perform feedback control so that the amount of ozone is always fixed, so that ozone that gives energy above the dissociation energy of oxygen molecules and below the dissociation energy of nitrogen molecules to gas molecules contained in the gas flowing in to decompose viruses is generated but harmful nitrogen oxides are not generated.

The invention discloses a carbon molecular sieve and a process for preparing high-purity oxygen by using the carbon molecular sieve, the surface of the carbon molecular sieve is provided with three types of micropores, the diameter of the first type of micropores is greater than the diameter of nitrogen molecules, and the diameter of the second type of micropores is between the diameter of oxygen molecules and the diameter of nitrogen molecules. The diameter of the third kind of micropores is smaller than that of oxygen molecules, the proportion of the first kind of micropores in the total amount of the micropores is smaller than 5%, and the proportion of the second kind of micropores in the total amount of the micropores is larger than 60%; according to the process for preparing high-purity oxygen by using the carbon molecular sieve, oxygen in air is adsorbed in a high-pressure environment, and then decompression and desorption are performed to obtain the high-purity oxygen. The method has the advantage that high-purity oxygen can be obtained at low cost.

The present invention relates to a method for measuring the coefficient of restitution of nano-sphere particle collision based on molecular dynamics, comprising: establishing two nano-sphere Al2O3 particle models using OVITO software; placing a nitrogen molecule model, an oxygen molecule model, and the two particle models in a simulation box to form a simulation object system, and importing the LAMMPS software; using comb3 and lj / cut mixed potential; setting simulation parameters, performing molecular dynamics simulation, obtaining parameter data during the movement of the particle model, and observing the deformation of the particle model during the collision process; post-processing the parameter data to obtain a force-displacement curve of the particle model, judging the collision occurrence and end time of the particle model, and determining the collision velocity of the particle model and the separation velocity during rebound, and calculating the collision coefficient of restitution of the particle model based on the velocity changes before and after the collision. The present invention overcomes the limitations of traditional methods and improves measurement accuracy.

The present disclosure provides a method of processing a liquid containing ammonia nitrogen from a first semiconductor fabrication machine. The method includes: adsorbing a plurality of ammonium (NH4+) ions in the liquid; desorbing the plurality of NH4+ ions to a solution; converting a fraction of the plurality of NH4+ ions into a plurality of ammonia (NH3) molecules; and electrolyzing the plurality of NH3 molecules to become a plurality of hydrogen (H2) molecules and a plurality of nitrogen (N2) molecules.

The application provides a preparation method and application of high-nucleus cobalt cluster-based MOFs and derivatives thereof, including Co 16 -MOF-BDC-X, Co 16 -MOF-BPDC, crystallized in a tetragonal system, and a space group is P42 / nmc, wherein Co 16 The cell parameter of the MOF-BDC-X is: alpha=beta=gamma=90°, Co 16 The cell parameter of the MOF-BPDC is: alpha=beta=gamma=90°, the application adopts a strategy of assisted synthesis of double small molecules (azide molecules and formic acid molecules), and successfully constructs a series of novel high-nucleus cobalt cluster-based MOFs, including Co 16 -MOF-BDC, Co 16 -MOF-BDC-X (X=NH2, NO2, OH, Br) and Co 16 -MOF-BPDC, the application realizes a great improvement of solar energy conversion efficiency by regulating functional groups on the MOF ligand and modifying strong absorption photosensitive centers on the MOF metal node, and exhibits application in the field of photocatalysis.

This invention relates to the field of automatic control for ozone generation, specifically disclosing an optimized ozone generation control method and system based on improved fuzzy control. The method includes: acquiring the optical emission spectrum of the discharge chamber, extracting the rotational spectrum of nitrogen molecules, decoupling and calculating the instantaneous temperature of the micro-discharge channel, and outputting a thermodynamic mismatch coefficient through a first fuzzy inference; introducing the coefficient into the pulse power supply and the gas flow field loop respectively, and collaboratively adjusting the rise time, pulse width, repetition frequency, and turbulent airflow velocity of the nanosecond pulse; inputting the coefficient and oxygen atom spectral lines into a second fuzzy inference, adjusting the domain and threshold of the main fuzzy controller, and the main controller forming a three-dimensional input vector to output the pulse amplitude adjustment; inputting historical control data into a third fuzzy mining time-series correlation mode to generate a rule confidence correction factor to feed back and optimize the fuzzy rule base. This invention achieves micro-discharge channel thermal state sensing, multi-timescale collaborative control, and strategy self-evolution, significantly improving ozone generation efficiency and electrode lifetime.

The purpose of the present invention is to develop a method for the fermentative production of L-glutamic acid based on nitrogen molecules in the atmosphere using nitrogen-immobilized bacteria. The present invention develops a culture method for maintaining a state in which nitrogen-immobilizing ability is increased in nitrogen-immobilizing bacteria. This culture method is characterized by mixing an organic acid such as citric acid into a nitrogen-restricted medium placed in an open container. A method for producing L-glutamic acid by fermentation depending on nitrogen immobilization can be developed by culturing a gene-altered strain that highly expresses a citrate synthase gene and a citrate transporter gene using this culture method. In this process, a method for producing L-glutamic acid by fermentation that depends on nitrogen immobilization by using a modified strain that highly expresses a citrate synthase gene or a 2-methylcitrate synthase gene can be developed. The present invention relates to a method for producing the microorganism and a method for culturing the microorganism.

The invention belongs to the technical field of oxygen generation systems, and particularly relates to a system and a method for purifying oxygen in a molecular sieve oxygen generation process. The system comprises a carbon dioxide filter, a moisture filter, an air temporary storage tank, an air compressor, an oil vapor filter, a plurality of adsorption towers, an oxygen storage tank, a nitrogen storage tank and a heat recovery device which are sequentially connected through pipelines and valves, each adsorption tower is filled with the modified molecular sieve material. The MOR molecular sieve structure is modified, so that the anti-aging and anti-pulverization performance of the modified molecular sieve material is improved, the modified MOR molecular sieve structure has the optimal pore structure and adsorption performance, the pore diameter and pore distribution uniformity are improved, a stable state can be kept for a long time, and the adsorption efficiency on nitrogen molecules is improved; the adsorption performance and the adsorption effect are improved, the adsorbent can be recycled, and the service life is prolonged. The heat effect influence and the pressure drop influence are reduced, and the stability and the adsorption efficiency of the system are improved.

The invention discloses a method for synthesizing ammonia, which is characterized in that nitrogen and hydrogen are used as reaction gases, and ammonia is synthesized under the normal pressure or low pressure condition under the action of a gaseous molecular accelerator and a catalyst, wherein the gaseous molecule accelerant is nitrogen oxide. Nitrogen oxide can react with hydrogen to generate ammonia, and active oxygen atoms generated by the reaction can activate nitrogen molecules, so that the ammonia synthesis reaction of nitrogen and hydrogen is greatly promoted, and efficient ammonia synthesis of nitrogen and hydrogen under normal pressure is realized. The synthesis ammonia reaction under the molecular accelerator can also be carried out at low pressure, and the synthesis ammonia rate and conversion rate can be improved by properly increasing the reaction pressure. Besides, a reaction system is optimized, such as reaction process parameters of a catalyst, air speed, composition, pressure, temperature and the like, so that the rate and the conversion rate of ammonia synthesis are also favorably improved, and the rate and the conversion rate of ammonia synthesis close to or exceeding those of traditional industrial Have-Bosch high-temperature and high-pressure ammonia synthesis are realized.

The present invention relates to the field of optical technology, and discloses a vortex beam generation system. The system comprises: a femtosecond laser light source, for generating a laser beam, wherein after the laser beam is split into two, one beam is used as a pump beam and the other beam is used as a probe beam; a pump light shaping module, for shaping the pump beam into a vector beam; a probe light shaping module, for shaping the probe beam into a circularly polarized beam; and a vortex light generation module, for focusing the vector beam and the circularly polarized beam together into a nitrogen-filled gas chamber, inducing a non-adiabatic arrangement of nitrogen molecules in the gas chamber by the vector beam, so that the nitrogen molecules are arranged according to the polarization direction of the vector beam during the recovery period, forming multiple molecular wave plates. After the circularly polarized beam passes through the multiple molecular wave plates, it is modulated into a vortex beam having a hand-direction opposite to that of the circularly polarized beam, thereby improving the quality of the generated vortex beam.

This makes it possible to predict the behavior of oxygen molecules within the pores of a carbon support. [Solution] The analysis method comprises a modeling step, a setting step, a simulation step, and a calculation step. In the modeling step, the carbon support of the hydrogen fuel cell is modeled as a cylindrical carbon nanotube model. In the setting step, the number of water molecule models, oxygen molecule models, and nitrogen molecule models to be placed within the carbon nanotube model is set. In the simulation step, a simulation is performed on the diffusion of water molecule models, oxygen molecule models, and nitrogen molecule models within the carbon nanotube model. In the calculation step, the diffusion coefficient of the oxygen molecule model is calculated based on the simulation results.

The invention discloses an oxygen enrichment membrane assembly and an oxygen enrichment machine, the oxygen enrichment membrane assembly comprises a shell and a membrane layer, the membrane layer is an oxygen enrichment membrane, a mounting cavity is formed in the shell, the membrane layer is arranged in the mounting cavity of the shell, and the membrane layer is connected with the shell and divides the mounting cavity into a membrane inner cavity and a membrane outer cavity; a first vent hole and a second vent hole which are communicated with the membrane outer cavity are formed in the shell, and an airflow channel flowing through the outer surface of the membrane layer is formed between the first vent hole and the second vent hole, so that nitrogen molecules attached to the outer surface of the membrane layer are discharged out of the membrane outer cavity along the airflow channel; the membrane inner cavity is communicated with a negative pressure device in a sealed mode, and the negative pressure device is used for driving air to enter the membrane inner cavity from the membrane outer cavity through the membrane layer. The airflow channel flowing through the outer surface of the membrane layer is formed between the first vent hole and the second vent hole which are communicated with the outside of the membrane, nitrogen molecules attached to the outer surface of the membrane layer are discharged through airflow of the airflow channel, and the situation that the oxygen separation efficiency is reduced due to the fact that the nitrogen molecules block the membrane layer is avoided.

The invention relates to the technical field of molecular sieve adsorption materials, in particular to a Li-SAPO-RHO molecular sieve as well as a preparation method and application thereof. The crystal framework of the molecular sieve is silicoaluminophosphate with an RHO topological structure; in the composition of the molecular sieve framework, the molar ratio of SiO2 to Al2O3 is 0.02 to 0.5; the Li-SAPO-RHO molecular sieve has the advantages that the Li content of the Li-SAPO-RHO molecular sieve is as low as 0.2-2.0%, and the relatively low Li is located at a framework orifice of the molecular sieve to form an alkali metal cation hinge gate effect, so that the adsorption effect on nitrogen molecules is increased. The molar ratio of SiO2 / Al2O3 in a molecular sieve framework is as low as 0.02-0.5, the lower molar ratio of silicon to aluminum is beneficial for the molecular sieve to still keep higher crystallinity after high-temperature roasting, the crystallinity is up to 99% or above, the specific surface area is up to 800 m < 2 > / g, and the molecular sieve can be used as an adsorbent for preparing high-purity nitrogen through pressure swing adsorption.

The utility model discloses a gas station oil tank nitrogen injection device which comprises an oil tank body, a gas inlet pipe penetrates through a gas inlet, nitrogen enters the oil tank body along the gas inlet pipe, oil gas in the oil tank body is completely exhausted, and the oil tank body is cleaned. The end, located in the oil tank body, of the gas inlet pipe is connected with a gas acceleration cavity, the gas acceleration cavity is of a circular-truncated-cone-shaped cavity structure, when nitrogen enters the oil tank body through the gas inlet pipe, the nitrogen passes through the gas acceleration cavity, the caliber of the gas acceleration cavity is gradually reduced from top to bottom, and under the equal pressure, the nitrogen injection speed is increased in the gas acceleration cavity; nitrogen molecules can be more rapidly diffused in the tank when obtaining larger kinetic energy, so that the oil gas replacement efficiency is effectively improved; and the side wall of the gas accelerating cavity is evenly connected with the gas outlet pipes, the nitrogen is exhausted into the oil tank body from the multiple gas outlet pipes after being accelerated, exhausting is more uniform, the nitrogen diffusion comprehensiveness is improved, and the oil gas replacement efficiency is further improved.

The application provides an electrode structure for in-situ nitrogen separation, a fuel cell and a preparation method, and belongs to the technical field of fuel cells. The electrode structure comprises an anode gas diffusion layer and an anode catalytic layer, and a nitrogen selective separation adsorption layer is arranged between the anode gas diffusion layer and the anode catalytic layer. The separation adsorption layer is a porous film layer with a pore size between the kinetic diameter of a hydrogen molecule and the kinetic diameter of a nitrogen molecule, and is deposited on the side surface of the anode gas diffusion layer facing the anode catalytic layer in an in-situ growth manner. By adopting the technical scheme provided in the embodiment of the application, the problems in the prior art that the system volume increases sharply, the in-situ nitrogen separation cannot be realized at the electrode level, the nitrogen occupies the active sites of the catalytic layer, hinders the diffusion of hydrogen and accelerates the performance decay of the electrode can be solved.

The invention belongs to the technical field of photocatalytic materials, and particularly relates to a near-infrared light response Bi2S3 / CN photo-thermal catalytic nitrogen fixation catalyst as well as a preparation method and application thereof. In order to provide a photo-thermal catalytic nitrogen fixation catalyst, the invention provides a novel nitrogen reduction system based on a photo-thermal synergistic strategy, a Bi2S3 / S-g-C3N4 heterojunction photo-thermal catalyst (Bi2S3 / CN) is constructed through a solvothermal method, and a nitrogen reduction reaction under efficient driving of solar energy is realized. Wherein Bi2S3 is used as an excellent photo-thermal material and can capture wide-spectrum solar energy and generate high-energy hot carriers, so that nitrogen molecules are effectively activated and the reaction rate is increased; meanwhile, the electronic structure of g-C3N4 is remarkably optimized through S-doped modification, and the visible light absorption and interface charge transfer capacity is enhanced.

The invention discloses a photocatalytic nitrogen fixation fertilization device, and relates to the technical field of agricultural fertilization equipment.The photocatalytic nitrogen fixation fertilization device is characterized in that a first reaction cavity is arranged, the top wall of the first reaction cavity is transparent, so that light is emitted into the first reaction cavity, and a breathable film parallel to the top wall is arranged in the reaction cavity; enabling the first photocatalyst on the gas-permeable membrane to catalyze oxygen molecules and nitrogen molecules to be activated and converted into nitrogen oxides; a second reaction cavity is arranged, the top wall of the second reaction cavity is transparent, light rays are emitted into the second reaction cavity, nitric oxide is introduced into the second reaction cavity to react with water or an aqueous solution containing a second photocatalyst, nitrate nitrogen fertilizer, ammoniacal nitrogen fertilizer or ammonium nitrate fertilizer is generated, light energy is used as driving force in the process, and the light rays are emitted into the second reaction cavity. The method realizes green conversion of nitrogen, oxygen and water, does not need to depend on high-temperature and high-pressure conditions of a traditional ammonia synthesis process or a nitrate synthesis process, and does not discharge a large amount of carbon dioxide in the preparation process, so that the carbon emission is reduced.

To provide a nitrogen fixation method and a nitrogen fixation apparatus that can significantly reduce energy and cost and are easy to put into practical use.SOLUTION: Water 14, in which air is dissolved by contact with the air, is brought into contact with a photocatalyst (photocatalyst layer 5), and the photocatalyst is irradiated with ultraviolet rays (light source 91), thereby generating ammonia, nitric acid, or nitrous acid in the water 14 from nitrogen molecules in the air dissolved in the water 14 by a photocatalytic reaction.SELECTED DRAWING: Figure 1

The present invention discloses a membrane separation oxygen enrichment device, an oxygen-enriched gas supply system, and an oxygen-enriched combustion method. The membrane separation oxygen enrichment device of the present invention improves the oxygen enrichment effect of simple membrane separation by adding a magnetic field outside the membrane separation oxygen enrichment device, coordinating with a magnetic medium filled in the middle of the membrane material, utilizing the different paramagnetism and diamagnetic properties of oxygen molecules and nitrogen molecules, and relying on the mutual cooperation of the magnetic field and the magnetic medium. The oxygen-enriched combustion gas supply system of the present invention selects CO2-rich flue gas as the purge gas of the membrane separation component, directly realizing the mixed combustion of CO2-rich flue gas and O2-rich gas, solving the problems of low oxygen enrichment efficiency of the existing magnetic method and difficulty of oxygen escaping from the enrichment magnetic field. The entire oxygen-enriched gas supply process is continuous and stable.

The application belongs to the technical field of nanometer material preparation, and specifically discloses a method for laser-assisted mass preparation of boron nitride nanotubes, which comprises the following steps: (1) placing a boron source into a container and erecting a metal net above the container; (2) irradiating the container with a laser under a nitrogen-containing atmosphere; and (3) after the irradiation is completed, cooling the container and collecting the product. By using the erected metal net as an activator for the reaction of the boron source with nitrogen, the reactivity of nitrogen molecules is improved, and the introduction of metal impurities in the reaction of the boron source is avoided. The process of the application is suitable for various types of boron sources and metal nets, is simple, has high yield, and can realize high-quality and macro-quantity production of boron nitride nanotubes with complete shape, high crystallinity and good mechanical properties.