45 results about "Over oxidation" patented technology

The invention discloses a preparation method for selectively oxidizing thioether into sulfoxide through photo-initiation, and belongs to the field of synthesis of medical compounds. The preparation method comprises the following steps that in the air atmosphere, a thioether compound is dissolved in an acetonitrile-water mixed solvent, inorganic metal salt catalysts such as ferric chloride and copper sulfate are added, the mixture reacts for 8-48 h at the temperature of 0-45 DEG C under illumination with the wavelength of 295-405 nm, selective oxidation is carried out, and the sulfoxide product is obtained, and the molar ratio of thioether to the catalysts is 5: 1. The method overcomes the problems of excessive oxidation risk, complicated operation, environmental pollution and the like caused by dependence of a noble metal catalyst and use of a strong oxidant in the existing thioether oxidation method, has the advantages of high catalytic efficiency, high yield and excellent selectivity, can greatly reduce the production cost, is suitable for later industrial synthesis and amplification, and has wide application prospects. The method has the advantages of no expensive metal catalyst or oxidant, simple preparation process, high efficiency, environmental protection, safety and cost saving.

The invention belongs to the technical field of water electrolysis hydrogen production catalysis, and particularly relates to a ruthenium molybdenum oxide nanorod electrocatalyst, a preparation method and application. In the electrocatalyst, the molar ratio of Mo to Ru is 1: 1-1: 9, and Mo atoms enter ruthenium oxide crystal lattices in the form of replacing Ru atoms; the method comprises the following steps: adding ammonium-containing molybdenum salt and NaNO3 crystals into a ruthenium salt solution, drying, grinding, calcining in air, cooling, and washing with deionized water to remove the NaNO3 crystals to obtain the electrocatalyst. According to the preparation method of the electrocatalyst, the problems of poor stability, high cost, complicated preparation and the like in the preparation process of an anode end catalyst in a proton exchange membrane water electrolysis hydrogen production technology are solved, the prepared electrocatalyst presents an ultra-small nanorod morphology, and a large number of edge and corner sites are generated for an oxygen production reaction; the Ru-O coordination structure of the electrocatalyst is in an unsaturated state, the Ru-O covalent interaction is significantly weakened, the introduction of Mo with low electronegativity inhibits the excessive oxidation of the electrocatalyst, and the oxygen production stability is high.

The invention provides a preparation method of a Zn-Cr spinel oxide catalyst and application of the Zn-Cr spinel oxide catalyst in CO2-assisted ethane dehydrogenation, and relates to the technical field of composite catalysts. Wherein the Zn-Cr spinel oxide catalyst is prepared by firstly preparing a Zn1Crx oxide carrier by adopting a coprecipitation method and then loading Cr on the surface of the Zn1Crx oxide carrier by adopting an impregnation method, and in the process, strong metal-carrier interaction can be formed between the loading of Cr on the surface of the carrier and the Zn1Crx oxide carrier, so that the oxygen vacancy concentration on the surface of the catalyst is regulated and controlled and the desorption of ethylene is promoted; according to the present invention, the Zn1Crx carrier is used as the catalyst to inhibit the excessive oxidation of the Zn1Crx carrier so as to significantly improve the selectivity of ethylene, and the metal Cr forms the compact covering layer on the surface of the Zn1Crx carrier so as to reduce the number of the strong oxidation active sites, synergistically promote the rapid desorption of ethylene, and inhibit the occurrence of the side reactions such as dry reforming and hydrogenolysis.

The invention discloses application of a cobalt-based catalyst in preparation of ethylene by photocatalytic ethane dehydrogenation with participation of lattice oxygen, the cobalt-based catalyst is Co3O4 with a spinel structure, and due to the coexistence characteristic of Co < 2 + > / Co < 3 + > in the structure and the migration ability of the lattice oxygen, the cobalt-based catalyst can be used as a photocatalyst and an oxygen storage tank; therefore, under the environment-friendly and low-energy-consumption photocatalytic reaction condition, lattice oxygen can be used as a mild oxidizing agent for high-selectivity photocatalytic ethane dehydrogenation to prepare ethylene. Direct participation of oxygen molecules is avoided through utilization of lattice oxygen in the catalyst, generation of COx by-products caused by excessive oxidation can be prevented, ethylene selectivity is improved, the lattice oxygen consumed in the catalyst after the reaction can be regenerated through reaction with air or oxygen, the safety problem that ethane and oxygen are mixed and combustible is solved, and the catalyst is suitable for industrial production. And the feasible photocatalytic oxidation-reduction cycle is realized.

The present invention relates to a method for oxidizing a polysubstituted benzene, which method comprises: in an oxygen-containing atmosphere, bringing the polysubstituted benzene into contact with a catalyst for an oxidation reaction, wherein the catalyst contains a nitrogen-carbon material treated with ammonium chloride. The method of the present invention has a relatively high conversion rate of the reactants and a high selectivity to the target product, effectively avoiding over-oxidation.

The present invention belongs to the field of chemical catalysis technology, and discloses a method for preparing m-methylbenzyl alcohol. The present invention provides a route and corresponding catalyst for directly producing m-methylbenzyl alcohol from low-carbon alcohol aldehydes through hydrogen transfer or dehydrogenation-coupling-aromatization reaction. The selectivity of m-methylbenzyl alcohol is as high as 47.7%, and the selectivity of m-methylbenzaldehyde is 4.6%. m-methylbenzaldehyde can be converted into m-methylbenzyl alcohol by simple hydrogenation. Mild reaction conditions avoid the generation of excessive oxidation products. The reaction route produces hydrogen as a by-product, which is a clean energy source. The route also generates high-carbon chain alcohols, which are easy to separate by distillation and can be used as fuels or oil additives. In addition, the route also generates o- and p-methylbenzyl alcohols and methylbenzaldehyde, which can be used in the fields of spices, medicine, cosmetics, pesticides, etc.

The invention relates to a preparation method and application of an alkaline palladium ruthenium hydroxide-cerium oxide electrocatalyst with a high-activity and wide-potential stability window. According to the preparation method, the non-platinum carbon-loaded ruthenium-based alloy is successfully prepared by adopting a wet chemical reduction and annealing combined method, and uniform dispersion of metal nanoparticles is realized. The palladium ruthenium-cerium oxide electrocatalyst prepared by the invention is small in particle size, uniform in dispersity and relatively high in current density and mass ratio activity, the problem of inactivation caused by over-oxidation of the ruthenium-based electrocatalyst under relatively high potential is also greatly improved, and the palladium ruthenium-cerium oxide electrocatalyst is suitable for an oxidation reaction of hydrogen at an anode side of an alkaline fuel cell.

The invention discloses nanometer graphene oxide and a preparation method thereof. The transverse size of the nanometer graphene oxide is 10-100 nm, and the thickness of the nanometer graphene oxide is 1-2.5 nm. The surface chemical structure meets the following conditions: a C1s peak is analyzed on the basis of X-ray photoelectron spectroscopy, the sum of the atomic percent content of hydroxyl and epoxy groups is not higher than 15%, and the atomic percent content of carboxyl is not lower than 6%. According to the structural design, the structural defect caused by excessive oxidation or reduction in a traditional method is avoided, and the chemical stability and the functionalization potential of the material are improved.

The invention discloses low-defect graphene oxide and a preparation method thereof.The preparation method comprises the steps of pre-expansion treatment, dilution treatment, stripping treatment, mild oxidation and post-treatment, and by means of a step-by-step cooperation strategy of pre-expansion, stripping and mild oxidation, mild pre-expansion of graphite is achieved in a concentrated sulfuric acid system through low-concentration hydrogen peroxide firstly, and then the graphite is subjected to post-treatment; and performing physical stripping to obtain few-layer graphene, performing mild oxidation under a low-temperature condition, and circularly using the filtrate collected in the dilution treatment stage for post-treatment washing. According to the method, the oxidation degree is effectively controlled, lamellar defects caused by excessive oxidation are avoided, and finally the low-defect graphene oxide with the C / O ratio larger than or equal to 10 is obtained; meanwhile, waste liquid recycling is achieved, the environment cost is reduced, the process steps are simple, reaction conditions are easy to control, industrial production is easy, and the method has wide application prospects in the fields of composite materials, energy storage devices and the like.

The invention discloses staphylococcus calves HRB1 with an antioxidant function and application thereof, and belongs to the technical field of food processing. In order to solve the problems that the product quality is reduced due to over oxidation of lipid and protein of a fermented meat product and the safety of a synthesized antioxidant is relatively low, the invention provides staphylococcus calvus HRB1 with an antioxidant function and a leavening agent containing the staphylococcus calvus HRB1 and application of the staphylococcus calvus HRB1 to the fermented meat product. The staphylococcus calf HRB1 provided by the invention has better growth ability under H2O2 stress, has higher scavenging ability and reducing ability on DPPH free radicals, hydroxyl free radicals and superoxide free radicals, and is proved to have higher antioxidant ability; the provided leavening agent has the function of reducing the content of thiobarbituric acid and carbonyl, and the purposes of reducing nutrition loss, poor flavor and spoilage caused by excessive oxidation of lipid and protein are achieved.

The application discloses a preparation method of aromatic aldehyde by oxidizing aromatic hydrocarbon, and the method comprises the following steps: contacting a solution containing aromatic hydrocarbon with a supported catalyst under an oxygen-containing atmosphere, and reacting to obtain the aromatic aldehyde; the reaction is carried out in a fixed bed photocatalytic reaction device; and the supported catalyst is a TiO2 surface supported oxide catalyst. The fixed bed reaction device can keep the activity of the target reaction and the high selectivity of the product for a long time, and effectively overcomes the problem of excessive oxidation of the product.

The invention relates to the technical field of chemical industry, in particular to a method for preparing styrene by oxidative dehydrogenation of ethylbenzene, which comprises the following steps: under the condition of low temperature of 150-300 DEG C, ethylbenzene is contacted with an oxygen storage catalyst in an oxidation state, the catalyst catalyzes ethylbenzene dehydrogenation to generate styrene and hydrogen, and then the hydrogen is selectively oxidized into water by self lattice oxygen, directional movement of reaction balance is realized; the catalyst consuming lattice oxygen is regenerated through oxygen-containing gas flow to recover the oxidation state and is recycled. The oxygen storage catalyst is a composite metal oxide or carbide-oxide composite material with a specific structure, and has the functions of ethylbenzene activation, lattice oxygen storage and release and molecular oxygen activation. The invention also provides two reactor implementation schemes of fixed bed switching and fluidized bed circulation. The problems that traditional high-temperature dehydrogenation is high in energy consumption and limited in selectivity and existing oxidative dehydrogenation uses pure oxygen to cause safety and excessive oxidation are solved, and low-temperature, efficient and safe styrene production is achieved.

This invention discloses a low-temperature, high-efficiency, and highly adaptable chromium-indium-based composite oxide denitration catalyst, its preparation method, and its applications, relating to the field of denitration catalyst technology. This invention utilizes manganese-modified TiO2 to enhance the oxidation capacity of the denitration catalyst while preventing the excessive oxidation of NH3 to N2O by manganese oxide crystals; it also utilizes Cr and In species to coat the surface of the manganese-modified TiO2, constructing an acid-rich environment (Cr-OH and In-OH), thereby reducing HCl adsorption capacity and improving the adaptability of the denitration catalyst. The chromium-indium-based composite oxide denitration catalyst of this invention exhibits high NO content in the temperature range of 150-325℃. x The conversion rate is higher than 80%; at the same time, the catalyst has the ability to resist HCl poisoning and can still maintain good denitrification activity at low temperatures in the presence of HCl.

The application relates to a preparation method of a post-modified metal organic framework material for catalytically oxidizing benzyl alcohol into benzaldehyde and application thereof, and belongs to the technical field of photocatalytic materials. A Zr-based MOF-808 is taken as a matrix framework, organic dye eosin Y (EY) is taken as a functional unit, and the two are coordinated and anchored to prepare a post-modified metal organic framework material EY@MOF-808. The post-modified metal organic framework material EY@MOF-808 has rich unsaturated coordination sites, provides a path for distinguishing the guest binding capacity with different groups, improving reactivity and selectivity, and effectively avoids the excessive oxidation of benzaldehyde. The EY@MOF-808 is suitable for catalyzing benzyl alcohol with various substituents, and corresponding benzaldehyde is obtained with a selectivity of greater than 99%. In addition, the EY@MOF-808 can be recycled for four times and the selectivity is not reduced, and the release of toxic dyes into the environment is prevented.

The invention discloses a method for preparing acetone through photo-thermal catalytic methane conversion, and belongs to the field of methane conversion. The method comprises the following steps: adding a catalyst, water and reaction gas containing methane gas into a reactor, wherein the catalyst is formed by loading an active metal component on a nano semiconductor carrier; and reacting under the coupling condition of illumination and heating at 25-150 DEG C to generate a liquid product containing acetone. The catalyst is prepared by loading transition metal and noble metal on a nano semiconductor material. The metal-loaded nano-particles of the photocatalyst prepared by the method are relatively small in particle size and good in dispersity, and the photocatalyst has relatively strong ultraviolet-visible light absorption capability and is beneficial to activation of methane. Under the illumination of ultraviolet-visible light at 25-150 DEG C, the catalyst can efficiently and highly selectively catalyze methane and water to directly react to generate acetone, and meanwhile, excessive oxidation of a product is remarkably avoided. The prepared catalyst has the characteristics of high catalytic activity, good stability, simple process, low cost and the like.

The invention discloses a synthesis method and device of glyoxylic acid. The synthesis method of glyoxylic acid adopts the synthesis device of glyoxylic acid for continuous operation, is short in retention time and large in treatment capacity, remarkably improves the synthesis rate of glyoxylic acid, and greatly improves the space time yield. A glyoxylic acid synthesis device is used, a good mixing environment is provided for mixing of raw materials, and the utilization rate of the raw materials is increased; meanwhile, the reaction process can be accurately controlled, the use amount of nitric acid is reduced, excessive oxidation is prevented, and byproducts are reduced; in addition, the feeding is more dispersed, the bumping phenomenon caused by overhigh local concentration is avoided, and the stable and sufficient reaction is ensured. The synthesis method of glyoxylic acid is low in production cost and high in yield.

The invention discloses a W-(Co3O4 / RuO2) electrocatalyst as well as a preparation method and application thereof, and belongs to the technical field of hydrogen production by electrocatalytic water decomposition. The W-(Co3O4 / RuO2) electrocatalyst provided by the invention comprises a nanometer heterojunction structure formed by Co3O4 and RuO2, and tungsten atoms doped in the nanometer heterojunction structure. By adjusting doped elements, the electronic structures of tungsten, cobalt and ruthenium are effectively regulated and controlled, charge transfer of Co, Ru and W is promoted, and the covalence of Ru-O is inhibited, so that excessive oxidation of Ru is inhibited, excellent electro-catalytic oxygen evolution performance is given to the material, the number of catalytic active sites is greatly increased through the synergistic composite effect of nano heterojunctions formed by W atoms, Co3O4 and RuO2, and the catalytic activity of the material is improved. The atom utilization rate is effectively improved, the charge transmission path is optimized, the reaction kinetics is improved, and the water electrolysis oxygen evolution performance in the acid environment is greatly improved. Meanwhile, through the strategy of combining a solution combustion method and calcination, the process is simple and controllable, and wide application prospects are created for large-scale production.

The present invention belongs to the technical field of organic synthesis, and relates to a supported catalyst, and the preparation thereof and the use thereof in a reaction of synthesizing methyl glyoxylate from methyl glycolate. The supported catalyst comprises a carrier, and an active metal component and an auxiliary component loaded on the carrier, wherein the active metal component is vanadium; and the auxiliary component is selected from at least one of silver, molybdenum, yttrium, bismuth, tungsten, manganese, niobium, zinc, zirconium, cerium, cobalt, magnesium, calcium, barium, lanthanum, boron, gallium, germanium, or indium. Compared with the prior art, the active metal and auxiliary of the catalyst prepared in the present invention are concentrated on the surface layer of the carrier and distributed in an eggshell form, and methyl glycolate is adsorbed, reacted and desorbed on the surface of the catalyst to avoid the generation of a large amount of over-oxidation products CO and CO2, thereby improving the yield of methyl glyoxylate.

The invention belongs to the technical field of photocatalytic materials, and particularly relates to a preparation method of Pt monatomic modified ZnO and application of the Pt monatomic modified ZnO to photocatalytic oxidation of methane to generate an oxygen-containing liquid product. Nano ZnO is prepared by adopting a precipitation method and a calcination method, then the Pt / ZnO photocatalyst is obtained by adopting a photodeposition method, and the photocatalyst in which atomic-scale dispersed Pt is loaded on ZnO is prepared and can be applied to the field of photocatalytic methane oxidation. Compared with an existing photocatalyst, the Pt / ZnO photocatalyst is good in controllability and high in stability, has the characteristics of high methane adsorbability, hole capture, directional transmission of photo-generated holes to active sites and the like, successfully bypasses a traditional. OH leading way, effectively solves the problem of excessive oxidation, and provides a new strategy for direct and high-selectivity conversion of CH4. The method is simple in reaction environment, environmentally friendly, convenient to operate, low in material preparation cost and wide in application market prospect.

This invention discloses a method for the selective oxidation of methane to oxygen-containing compounds using water as the oxidant. The method employs orthorhombic molybdenum trioxide as the sole catalyst and water as the sole oxidant, allowing methane to react with water in a closed reaction system, resulting in the directional conversion to oxygen-containing compounds. This method eliminates the need for added precious metal catalysts, hydrogen peroxide, or oxygen as external oxidants, and avoids the use of co-catalysts, co-reactants, or reducing agents such as carbon monoxide or hydrogen. The selective oxidation of methane is achieved solely with water and orthorhombic molybdenum trioxide, simplifying the reaction system composition. Furthermore, the preparation process is simple and inexpensive, reducing catalyst costs and oxidant safety risks, while simultaneously achieving the directional conversion of methane to oxygen-containing compounds. This invention solves the problems of high oxidant costs and complex processes caused by co-reactants in existing technologies, and eliminates the generation of excessive CO or CO2 oxidation products.

The invention provides a green and efficient preparation method of an anthelmintic albendazole sulfoxide, which is characterized in that water is used as a green oxygen source, an anodic oxidation reaction is driven by electric energy at room temperature, albendazole sulfoxide is synthesized with high selectivity, and sulfone by-products generated by excessive oxidation are effectively avoided. According to the method, albendazole, cheap electrolyte sodium bromide, dimethyl sulfoxide and water are mixed into homogeneous reaction liquid, inert gas protection is not needed, and the homogeneous reaction liquid is introduced into an electrochemical microchannel continuous reactor to achieve oxidation. Compared with a traditional hydrogen peroxide oxidation method and a low-temperature chemical oxidation method, the method does not need to use a stoichiometric oxidizing agent, is mild in reaction condition, effectively avoids related safety and environmental risks, meets the requirements of green and sustainable development, and has a good industrial application prospect.

The invention discloses a method for efficiently and cleanly preparing 3-methyl-1-phenyl-1, 2, 4-triazoline-5-ketone, which comprises the following steps of: in a water solvent system, reacting 5-methyl-2-phenyl-1, 2, 4-triazolidine-3-ketone serving as a raw material under the action of metal hydroxide serving as a salt forming agent and oxygen to generate the 3-methyl-1-phenyl-1, 2, 4-triazoline-5-ketone; the oxygen-containing gas is used as an oxidizing agent, has the advantages of being clean, low in cost, good in stability, easy to obtain, easy to store and the like, solves the problem that the amount of three wastes is large due to the use of a halogen-containing oxidizing agent, also avoids the problems that peroxide is unstable and is excessively oxidized, and is milder in condition, low in temperature, higher in conversion rate and suitable for industrial production. And the process is clean, the reaction process is safe and environment-friendly, and the environment-friendly pressure is small.

The invention relates to the technical field of organic synthesis and preparation, in particular to a multi-step synthesis process for preparing o-trifluoromethyl benzoyl chloride from o-xylene, which comprises the following steps: oxidation preparation of o-toluic acid: adding o-xylene and a solvent into a reaction container, reacting under the action of an oxidation system, and separating to obtain o-trifluoromethyl benzoyl chloride; after the reaction is finished, carrying out post-treatment to obtain o-toluic acid; by optimizing the process for preparing o-toluic acid through oxidation, selecting an adaptive catalytic system and accurately regulating and controlling reaction conditions, the problems of low oxidation efficiency, more raw material residues and excessive oxidation in the existing process are effectively solved, the yield and purity of o-toluic acid are remarkably improved, a high-quality raw material is provided for subsequent steps, and the method is suitable for industrial production. The efficiency and the product quality of the whole preparation process are guaranteed from the source.

The invention belongs to the technical field of photocatalytic methane conversion, and particularly relates to a preparation method of a Keggin type heteropolyacid, AgNO3 and mesoporous TiO2 compounded photocatalyst and performance research of the Keggin type heteropolyacid, AgNO3 and mesoporous TiO2 compounded photocatalyst. The chemical expression formula of the photocatalyst is Ag-PW12 / TiO2. The preparation process adopts a one-step dipping-calcining method and comprises the following steps: S1, in the dipping process, firstly weighing a certain amount of TiO2, PW12 and AgNO3 (only changing the mass percent of AgNO3 and TiO2 between 0.5%, 1.0%, 1.5% and 2.5%), adding the weighed TiO2, PW12 and AgNO3 into 50ml of water, carrying out ultrasonic dispersion, stirring for 12 hours, washing with deionized water, filtering and collecting a sample; s2, drying the obtained material at 100 DEG C for 12 hours; and S3, heating the obtained material to 300 DEG C in a muffle furnace at a heating rate of 2 DEG C / min, maintaining the temperature of 300 DEG C for 3 hours, cooling to room temperature, and collecting a sample. A sample is marked as TWA-X, wherein X represents the mass percent value (0.5, 1.0, 1.5 and 2.5) of AgNO3 and TiO2. The photocatalyst for photocatalytic methane conversion is synthesized, and high yield and high selectivity of a liquid C1 oxygen-containing compound are realized on the basis of the catalyst.

The invention provides a heterogeneous catalyst COFBMTD-PY as well as a preparation method and application thereof, belongs to the technical field of photocatalysts, and can solve the problems that the current thioether oxidation reaction needs to be operated under a high-temperature condition, the dosage of the catalyst is large, an additional cocatalyst is needed, and in the actual use process, most of the catalysts cannot be recycled and are not easy to recover, so that the cost is low, and the like. The loss of the catalyst is serious, and the reaction waste is increased. The heterogeneous catalyst COFBMTD-PY disclosed by the invention is constructed by taking 1, 3, 6, 8-tetra-(p-aminophenyl)-pyrene and 2 ', 5'-bis ((1H-imidazole-1-yl) methyl)-[1, 1 ': 4', 1 ''-terphenyl]-4, 4''-diformaldehyde as units, and the heterogeneous catalyst COFBMTD-PY has a structural formula shown in the specification. The heterogeneous catalyst COFBMTD-PY disclosed by the invention can be applied to catalysis of oxidation reaction of methyl thioether and derivatives thereof, and has the advantages that efficient conversion of thioether is realized, reaction selectivity is precisely regulated and controlled, sulfone generation caused by excessive oxidation is avoided, a cocatalyst or extra oxygen is not needed, and the catalyst can be repeatedly utilized.

The invention discloses a method for oxidation removal and heavy metal toxicity inhibition of complex chromium in wastewater through iron-based secondary mineral mediated biological Fenton reaction and application. According to the method, Fenton reaction is induced through atmosphere regulation and control biological / mineral action, and oxidative degradation of complex-state chromium and heavy metal toxicity inhibition are achieved. The method comprises the following steps: reducing iron by facultative dissimilatory iron reducing bacteria and iron-based secondary minerals under anaerobic conditions; aeration is carried out, and accumulated ferrous iron and oxygen are utilized to initiate Fenton reaction so as to oxidize the organic complexing agent to realize complex breaking; converting to an anaerobic state, and reducing Cr (VI) generated by excessive oxidation; and circularly executing the aerobic / anaerobic operation until the wastewater reaches the standard. The method realizes advanced treatment of the complex chromium wastewater through a single reactor, and has the advantages of simple process, easily available materials and low operation cost.

The application discloses a kind of defect state carbon nanotubes, preparation method and application, belong to water treatment material technical field, the present application with multi-walled carbon nanotube as carbon base, dicyandiamide is precursor, by high temperature pyrolysis mode makes dicyandiamide etching multi-walled carbon nanotube, obtains defect state carbon nanotube.The defect state carbon nanotube obtained in the application is used as catalyst for free chlorine fenton oxidation process, compared with the widely used single-wavelength ultraviolet light activation technology has the advantages of easy and cheap, reaction efficient etc.And lower catalyst and extremely low oxidant consumption, not only reduce the process operation cost, but also avoid the stability reduction of catalyst due to excessive oxidation of oxidant.The present application has broad application prospect in the field of environmental governance of water body remediation.

This invention relates to a catalyst for photothermal catalytic methane coupling reaction, its preparation method, and its application. The catalyst comprises a titanium dioxide support and metal particles; the titanium dioxide support has anatase phase crystal structure; the metal particles, based on 100% of the total mass of the catalyst, have a mass percentage content greater than 0 and less than or equal to 0.12 wt%; the metal element in the metal particles is selected from Pd or Pt; the metal particles are loaded onto the titanium dioxide support via photodeposition, specifically: under an inert gas atmosphere, using methanol as a sacrificial agent, photogenerated electrons are used to reduce metal ions to zero-valent metal atoms in situ, which are then deposited on reduction sites on the surface of the titanium dioxide support. This invention's catalyst, by controlling the support crystal structure and metal-support interface, achieves efficient conversion of methane to ethane under mild conditions, avoiding over-oxidation, and exhibits excellent catalytic activity and stability.

This invention belongs to the field of pharmaceutical chemical synthesis technology and relates to a method for the catalytic oxidation of acetate tetraenes to synthesize dihydroxy compounds. The method uses acetate tetraenes as a raw material, acetone as a solvent, Ru-X-Y as a catalyst, and sodium hypochlorite as an oxidant. Under alkaline conditions, catalytic oxidation yields the product dihydroxy compound. In Ru-X-Y, X is Pt or Pd, and Y is any one of Fe, Mn, and Cu. This invention uses solid Ru-X-Y as a catalyst, utilizing the synergistic activation and polarization properties of metals. It only requires sodium hypochlorite, which has relatively weak oxidizing power, as an oxidant to catalytically oxidize acetate tetraenes to the target product dihydroxy compound, effectively avoiding the use of strong oxidants such as potassium permanganate. This not only prevents over-oxidation and improves product yield and quality but also increases production efficiency, resulting in significant economic and social benefits.

The invention discloses a method for synthesizing sulfoxide through selective oxidation of thioether under synergistic catalysis of enzyme and metal, and belongs to the technical field of pharmaceutical compound synthesis. The method comprises the following steps: firstly, artificially synthesizing a pyranose 2-oxidase encoding gene, and carrying out vector construction, heterologous expression and separation and purification to prepare a high-purity recombinase solution; and dissolving the thioether compound in a solvent in an oxygen atmosphere, adding D-glucose, FAD and a metal catalyst, adjusting the pH value of the system, and finally adding the recombinase liquid to obtain the sulfoxide product. According to the method, low-concentration hydrogen peroxide is mildly generated in situ, the problems of excessive oxidation, side reaction and the like are avoided, the product selectivity and yield are improved, and the production safety risk is reduced. The introduction of the sodium tungstate dihydrate further enhances the catalytic efficiency and selectivity, accelerates the reaction rate, widens the substrate range, and is mild in reaction condition, environment-friendly and in line with the development direction of green chemistry.