2 results about "Zinc fluoride" patented technology

The application relates to the technical field of special optical material preparation, in particular to a full-solid-state three-clad zinc fluoride-based glass optical fiber and a preparation method thereof. The optical fiber comprises, from inside to outside, an optical fiber core layer, an optical fiber inner clad layer, an optical fiber middle clad layer and an outer clad layer; the optical fiber core layer, the optical fiber inner clad layer and the optical fiber middle clad layer are all zinc fluoride-based glass and have the same component types; the refractive index of the optical fiber core layer is greater than that of the optical fiber inner clad layer; the materials of the optical fiber core layer, the optical fiber inner clad layer and the optical fiber middle clad layer all comprise the following components: ZnF2, BaF2, GaF3, SrF2, LiF, YF3, LaF3, PbF2, NaF and 0-12 mol% of rare earth fluoride; and the material of the outer clad layer is polytetrafluoroethylene. The prepared optical fiber has the advantages of high transmittance, low phonon energy, small loss, stable structure, high mechanical strength, simple preparation process, good repeatability, suitability for mass production and application in the fields of communication and the like.

The application discloses high-purity anhydrous scandium fluoride and a preparation method thereof, and belongs to the field of rare earth fluoride preparation. The preparation method comprises the following steps: mixing scandium oxide and zinc fluoride by a mechanical activation treatment method to obtain mixed raw materials, using mechanical activation to induce crystal lattice defects, significantly improving the kinetic conditions of the solid-solid reaction process of scandium oxide and zinc fluoride, and making fluorination more sufficient; roasting the mixed raw materials under an inert atmosphere to obtain roasted materials; putting the roasted materials into a mixed leaching system containing ammonia and ammonium salt for selective leaching, and then filtering and separating to obtain a solid crude product; using an ammonia-ammonium salt complex system, using the high stability of Zn(NH3)4] 2+ complex ions to realize accurate separation of by-products Zn and main products ScF3; and washing and drying the solid crude product to obtain anhydrous scandium fluoride, with a content of 400 ppm or less and a fluorination rate of 99.99%.