The invention discloses a preparation method of highly pure
quartz sands. The method comprises the following steps: 1, roughing: cleaning a
raw material, and crushing the cleaned
raw material; 2, carrying out calcining and water
quenching: calcining the crushed
raw material, taking out particles, and
quenching the particles in an ice-water mixture; 3, carrying out electric separation and
magnetic separation: milling the quenched particles, carrying out electric separation and
magnetic separation twice, and carrying out
pulse magnetic field treatment; 4,
pickling: immersing a material obtained in step 3 in a
hydrochloric acid solution, filtering the immersed material, dialyzing the obtained first filtrate to recover
hydrochloric acid, preparing a first mixed acid by using the recovered
hydrochloric acid and a
sulfuric acid solution, immersing
quartz sands in the first mixed acid, filtering the immersed
quartz sands, dialyzing the obtained second filtrate to obtain recovered mixed acid, preparing a second mixed acid by using the recovered mixed acid and a
nitric acid solution, immersing the quartz sands in the second mixed acid, adding the immersed quartz sands to a
sodium carbonate solution, and flushing the quartz ands; 5, floating the flushed quartz sands; and 6,
drying the floated quartz sands. The preparation method allows highly pure quartz sands with the SiO2 content to be not lower than 99.995% to be produced, and takes a greatly lower acid amount than traditional methods.