The invention belongs to the field of electrochemical materials, and discloses a sulfur and nitrogen codoping graphene loaded vulcanized cobalt and nickel catalytic material and preparation and application. A metal cobalt source, a nickel source and thiourea are dissolved in a solvent, a mixture is subjected to ultrasonic stirring and mixing, later, ammonium hydroxide is added dropwise, a mixtureis stirred and mixed, then, graphene oxide is added, a mixture is subjected to ultrasonic stirring and mixing and then subjected to hydro-thermal treatment, next, centrifugal washing and freeze dryingare carried out, and a graphene loaded vulcanized cobalt and nickel composite material is obtained; and then, in a nitrogen atmosphere, calcination treatment is carried out, graphene oxide is furtherreduced to obtain the sulfur and nitrogen codoping graphene loaded vulcanized cobalt and nickel catalytic material. The synthetic method is simple, the cost is low, the energy consumption is relatively low, environmental friendliness is achieved, and the obtained product has good electrical conductivity and electrochemical catalysis performance and is suitable for actual application of a water cracked cathode and anode catalytic material.