This invention discloses a black
radiation-cooling thin film and its preparation method. The thin film comprises, from bottom to top, a substrate Sub, a black reflective module, and a
radiation module. The structure of the black reflective module, from bottom to top, is MD1AD2, where M is a
metal layer, D1 is a first
dielectric layer, A is a visible light
absorption layer, and D2 is a second
dielectric layer. The structure of the
radiation module, from bottom to top, is (A'1A'2A'3). s L, where A'1, A'2, and A'3 are the first, second, and third absorption
layers, respectively, which have absorption in the 8μm-13μm band and
high transmission in the 0.3μm-2.5μm band; L is a low
refractive index protective layer; and s is the number of stacked periods, s≥1. This invention achieves good cooling performance while maintaining a black color.