The invention provides a sintering process of a petroleum fracturing propping agent, wherein the sintering process comprises the following steps: removing impurities from potassium feldspar, drying, and pulverizing to obtain potassium feldspar fine powder; uniformly mixing the potassium feldspar, graphite powder and magnesium powder, introducing protective gas, firing for 1-2 h at the temperatureof 600-700 DEG C, heating to 950-1100 DEG C, firing for 1-2 h, cooling, taking out, and crushing again to obtain secondary powder; and mixing the secondary powder with light calcined clay, sodium tripolyphosphate and tuff, carrying out spray mixing granulation and polishing to obtain ceramic primary particles, introducing protective gas, sintering the ceramic primary particles at the temperature of 1150-1210 DEG C for 0.5-1 h, continuously heating to 1250-1350 DEG C, and sintering for 1-2 h to obtain the petroleum fracturing propping agent. The method avoids the application of high-aluminum minerals, ensures the performance of the petroleum fracturing propping agent as much as possible, and has a great application prospect.