The invention relates to a super-soft superfine polyester fiber and a preparation method thereof. The super-soft superfine polyester fiber is mainly prepared by the steps of melt spinning of polyester through spinneret holes, application of an oiling agent and high-speed winding, wherein the oiling agent at least comprises fluorine-containing polyether, the mass of which is more than or equal to 45% of that of the oiling agent, the fluorine-containing polyether is a random copolymer of ethylene oxide, [(1,1,2,2-tetrafluoroethoxy) methyl] oxirane and propylene oxide, and the structural formula of the random copolymer is shown in the specification. The preparation method comprises the steps of metering, extruding, cooling, oiling, stretching, heat setting and high-speed winding of polyester, thereby obtaining the super-soft superfine polyester fiber. As the filament fineness of the super-soft superfine polyester fiber is very high, a fabric has advantages of specially soft and fine hand feeling, soft luster, comfortableness, breathability and good appearance texture and is easy to care, thus being popular with users more and more.