91 results about "Zinc atom" patented technology

The invention relates to the technical field of zinc oxide preparation, and in particular relates to a preparation method of a nitrogen-doped zinc oxide film. The preparation method comprises: placing a silicon substrate in the reaction cavity of atomic layer deposition (ALD) equipment; introducing gas containing a zinc source into the reaction cavity of the ALD equipment, wherein the zinc atoms in the gas containing the zinc source are adsorbed to the silicon substrate; conveying hydrogen to the reaction cavity of the ALD equipment based on nitrogen as a carrier gas, and simultaneously carrying out plasma discharge; introducing an oxygen-containing source to the reaction cavity of the ALD equipment, wherein the zinc atoms which do not react with nitrogen atoms form zinc-oxygen bonds withthe oxygen atoms in the oxygen-containing source; and repeating the steps, so as to grow the zinc oxide film containing the nitrogen atoms layer by layer. In the preparation method provided by the invention, nitrogen doping is carried out on the zinc oxide film by utilizing the ALD equipment; the method is simple and practicable; by utilizing the characteristic of atomic layer deposition and single-layer cycle growth, the uniform nitrogen doping in the whole film structure can be achieved in the process of zinc oxide film growth so that the doped film is complete in structure and excellent inproperty.

A method for sputtering a textured zinc oxide coating onto a substrate by reactive-environment hollow cathode sputtering comprises providing a sputter reactor that has a cathode channel and a flow exit end. The cathode channel allows a gas stream to flow therein. This cathode channel is at least partially defined by a channel-defining surface that includes at least one zinc-containing target. A gas is flowed through the channel, such that the gas emerges from the flow exit. A plasma is then generated such that material is sputtered off the channel-defining surface to form a gaseous mixture containing zinc atoms that is transported to the substrate. A reactive gas is then introduced into the sputter reactor so that the reactive gas reacts with the zinc-containing gaseous mixture to form the textured zinc oxide coating.

The invention relates to a copper-zinc alloy current collector for inhibiting lithium dendrites. A conventional current collector is covered with a layer of copper-zinc alloy, the thickness of the copper-zinc alloy is 10 nm to 1 [mu]m, and the zinc atom content of the copper-zinc alloy is 1-5%. The copper-zinc alloy current collector provides more active sites for lithium metal deposition than theconventional current collector, and a button battery is assembled in a glove box full of argon by using a metal lithium-loaded alloy current collector or a common copper foil as a negative electrodeand adopting a Celgard 2325 diaphragm and metallic lithium as a reference electrode and a counter electrode. Deposition/dissolution experiments are carried out with blue electricity. The current density is 0.5 mA cm<-2>, the voltage lag is significantly increased after the copper foil electrode only circulates for 520 h, and a copper-zinc alloy negative electrode still maintains a small voltage lag after 1000 h circulation. The current collector in the invention is applied to a lithium-lithium iron phosphate a battery, and the electrochemical performances of the battery are obviously better than those of a battery using a metallic lithium negative electrode adopting the common current collector.

The semiconductor device includes a first insulating layer; a first oxide semiconductor; a first insulator containing indium, an element M (M is gallium, aluminum, titanium, yttrium, or tin), and zinc; a second oxide semiconductor; a source electrode layer; a drain electrode layer; a second insulator containing indium, the element M, and zinc; a gate insulating layer; and a gate electrode layer. The first and second oxide semiconductors each include a region with c-axis alignment. In the first and second oxide semiconductors, the number of indium atoms divided by sum of numbers of the indium atoms, element M atoms, and zinc atoms is ⅓ or more. In the first insulator, the number of zinc atoms divided by sum of the numbers of indium atoms, element M atoms, and zinc atoms is ⅓ or less.

The invention provides a zinc isomorphism-substituted nano ZSM-5 molecular sieve catalyst and a preparation method thereof. In the method, solution of zinc amine or solution of zinc ammonia is taken as a zinc source, a one-pot method is adopted to directly make zinc atoms enter a framework of a molecular sieve, the prepared molecular sieve is a nano plate crystal with the dimension of 250nm*50nm*25nm, and the molecular sieve has the advantages of high yield, easy product separation, short preparation time and simple preparation method. When the molecular sieve serving as a catalyst is applied to methanol and ethanol aromatization reaction, the molecular sieve has the characteristics of high aromatic selectivity, high BTX proportion, long service life of the catalyst, stable catalytic performance, flexible technical operation, and the like.

The copper-indium-gallium (CuInGa) alloy is in particular to be used for the production of sputter targets, tubular cathodes and similar coating material sources. It has a phase corresponding to a Cu5Zn8 prototype phase in which the lattice sites of the zinc atoms (Zn) are occupied by gallium atoms (gallium-substituted Cu5Zn8 phase) and in which indium is simultaneously introduced into the elementary cell or phase, making up a proportion of up to 26 wt %.

The invention is related to insulin compositions with a high content of zinc atoms per six molecules of acylated insulin. The insulin is an acylated insulin and may be mixed with a further insulin analogue such as the rapid acting insulin Asp B28 human insulin.

Pharmaceutical composition for parenteral administration comprising a basal insulin peptide and an insulinotropic GLP-1 peptide comprising at least 6 zinc atoms per 6 insulin molecules.

The invention discloses a zinc-containing monatomic catalyst as well as a preparation method and application thereof. According to the invention, 2-methylimidazole zinc salt (ZIF8) is used as a zinc precursor, a zinc intermediate is obtained through low-temperature calcination, then the low-zinc intermediate is etched (and loaded), and finally, high-temperature calcination is performed to preparethe zinc-containing monatomic catalyst. The method has the advantages that the process is simple and controllable, the zinc content does not need to be strictly controlled, and carrier materials do not need to be adopted; zinc atom agglomeration can be effectively prevented through low-temperature calcination and etching before high-temperature calcination; the obtained pure zinc monatomic catalyst is good in catalytic activity, high in stability and relatively good in poisoning resistance; and the obtained supported zinc-containing monatomic catalyst can further improve the catalytic activityof a pure zinc monatomic catalyst or meet the requirements of different catalytic systems.

The present invention provides a modified charge control agent composition exhibiting a high charge-imparting effect, and an electrostatic image developing toner containing such a charge control agent composition and having a high electrostatic charge amount and an environmental stability.

A composition comprising a metal compound (A) of aromatic hydroxycarboxylic acid having an aromatic hydroxycarboxylic acid bonded with a metal atom selected from a zirconium atom, a calcium atom, an aluminum atom, a chromium atom, a boron atom and a zinc atom via at least any of ionic bond, covalent bond and coordinate bond; and at least one inorganic pigment (B), wherein the pigment (B) is contained in an amount of from 1 to 20 parts by mass in 100 parts by mass of the composition.

The invention provides a fused zinc erosion resistant coating material for thermal spraying and a preparation method of the coating material. The preparation method comprises the steps of: utilizing an eta phase tungsten carbide as a hard phase to replace the WC labile at a high temperature, and utilizing Fe3Al as an adhesion phase to replace Co, preparing an eta phase tungsten carbide-Fe3Al coating on a hot galvanized submerging roller or on the surface of a shaft sleeve of the hot galvanized submerging roller by a thermal spraying method to prepare a target product. The preparation method of the invention has the advantages that the hard phase, eta phase tungsten carbide can effectively prevent the zinc atoms from dispersing inward the alloy to resist against the fused zinc erosion, the eta phase tungsten carbide is high-temperature resistant and indecomposable to perform a good high-temperature wearing resistance function, and the adhesion phase Fe3Al and the Zn can be used for forming a fused zinc erosion resistant Fe-Al-Zn ternary phase, so that the fused zinc erosion resistance is better than that of a sintered WC-Co coating.

A manganese-activated zinc silicate phosphor according to the present invention satisfies 0<β-α≦0.5 and 1.7≦β, where a value α is a ratio of a number of zinc atoms to a number of silicon atoms in a surface region of a phosphor particle, including a surface of the phosphor particle and a vicinity thereof, and a value β is a ratio of a number of zinc atoms to a number of silicon atoms in a whole of the phosphor particle.

The invention discloses a production method of a copper-zinc alloy foil for preventing a lithium dendrite arm from being produced by lithium ions and belongs to the technical field of copper foil electrolysis. The method comprises the steps of carrying out acid pickling, washing, electric deposition, zinc deposition, washing and passivating, extruding and drying; a lithium dendrite arm copper-zincalloy foil of a lithium-ion battery can be prevented from being produced; zinc atom defects which are uniformly distributed in a current collector of the copper-zinc alloy foil can be used as induction crystal seeds to deposit metal lithium for nucleation, so that the distribution of the lithium ions on the surface of the current collector can be effectively improved; a zinc-layer crystal in thecopper-zinc alloy foil has tight and uniform tissue and the tissues are distributed orderly; the thickness is uniform and the deviation is less than 0.01mum; and the adhesive force is good, and the tensile strength and the elongation percentage reach utilization standards of the lithium-ion battery; and the copper-zinc alloy foil has good surface weldability and good high temperature resistance and corrosion resistance.

The invention relates to the preparation of novel bi- or tri metallic silicate micro-porous and/or meso-porous materials based on cerium, nickel, copper and/or zinc on a porous silicate framework matrix to use its molecular sieve effect to target preferentially the acidic organic molecules present in hydrocarbon feedstocks like crude oil, bitumen, VGO and the like. The chosen metals are selected based on their ability to activate steam and transfer oxygen for completing the oxidation of carboxylic compounds or decarboxylating them. These composite materials can be prepared under hydrothermal synthesis conditions in order to produce suitable porous solids where the metals are well dispersed and preferentially distributed inside the channels of the silicate framework where they can interact only with the molecules that can go inside the channels. According to the invention, the metallo-silicate materials are prepared under hydrothermal synthesis conditions Modification of the physical-chemical properties of the porous silicate materials can be accomplished by partial replacement of the silicon atoms by cerium, nickel, copper and/or zinc atoms in the material by isomorphous substitutions of these elements in a synthesis gel or by post-synthesis modifications like ion-exchange or impregnation/deposition. The materials can be used as prepared catalysts for the steam catalytic reduction of the total acid number (TAN) in acidic crude oil feedstocks and in the presence of steam and/or CO₂ as oxidizing agent to complete decarboxylation and to keep the metal oxide active sites from reducing and deactivating as well as other partial upgrading reactions.

The method for manufacturing an infrared reflecting film comprises, in order: a metal layer forming step of depositing a metal layer on a transparent film substrate; a metal oxide layer forming step of depositing a surface-side metal oxide layer by DC sputtering on the metal layer so as to be in direct contact with the metal layer; and a transparent protective layer forming step of depositing a transparent protective layer on the surface-side metal oxide layer. In the metal oxide layer forming step, a sputtering target used for DC sputtering contains zinc atoms and tin atoms, and is preferably formed by sintering a metal powder and at least one metal oxide among zinc oxide and tin oxide. In the surface-side metal oxide layer forming step, an inert gas and an oxygen gas are introduced into a sputtering chamber. The oxygen concentration in the gas introduced to the sputtering chamber is preferably not more than 8 vol %.

The invention discloses a perovskite solar cell and a preparation method thereof. The perovskite solar cell comprises a conductive glass layer, a compact titanium dioxide film, a porous titanium dioxide film, a methylamine lead iodine polycrystalline film, a hole-transport material layer and a metal electrode layer in sequence. The perovskite solar cell is characterized in that the porous titanium dioxide film is Zn-doped, and after doping, mole ratio between zinc atoms and titanium atoms is 0.1%-0.4%:1. The perovskite solar cell has the advantages that the Zn-doped porous titanium dioxide is utilized as a photo anode of the perovskite solar cell; a titanium dioxide conduction band can be changed through Zn-doping, and the titanium dioxide conduction band is allowed to move down, so that a gap between a methylamine lead iodine conduction band serving as a perovskite light absorption layer and Zn-doped porous titanium dioxide conduction band is enlarged, electrons are allowed to be easier to inject and pass, and photoelectric conversion efficiency of the perovskite solar cell can be improved.

A transparent conductive oxide film and a production method thereof relate to the technical field of production of transparent conductive oxide films. Firstly, a surface photografting modification method is used to modify the surface of a transparent plastic film to form a modified transparent plastic film. Under vacuum conditions, aluminum atoms and zinc atoms are sequentially sputtered on the same surface of the modified transparent plastic film, heated at 120-140°C to set the shape, and then rolled after cooling. The product of the present invention combines the performance advantages of flexible film and metal aluminum and zinc. It not only has high transparency, high gloss, can be curled, and is light in weight, but also has high electrical conductivity, is not easy to break, is easy to produce in a large area, and is convenient for transportation. unique advantages.

In a method of manufacturing a chemical fluid for manufacturing an electronic material, a method of reducing particulate metal in the chemical fluid is selected according to a concentration of particulate metal including an iron atom, a concentration of particulate metal including a copper atom, and a concentration of particulate metal including a zinc atom which are measured by SP ICP-MS in the chemical fluid, and at least one of the concentration of particulate metal including an iron atom, the concentration of particulate metal including a copper atom, or the concentration of particulate metal including a zinc atom is reduced by using the selected reducing method.

A capillaritron ion beam sputtering system and a thin film production method are disclosed. By utilizing reactive capillaritron ion beam sputtering deposition, argon and oxygen are passed through a capillaritron ion source simultaneously. Argon is being ionized and accelerated by a voltage to bombard a zinc target and create zinc atoms, while oxygen atoms are created at the same time. Zinc atom and oxygen atom are combined to form ZnO to deposit on a substrate. The stoichiometric properties, deposition rate, transmission properties, surface roughness and film density of the as-deposited film can be altered by adjusting capillaritron ion beam energy and oxygen partial pressure. Using preferred processing parameters, the root-mean-square surface roughness of the as-deposited film can be smaller than 1.5 nm, while the transmission coefficient at visible range can be greater than 80%.

The present invention provides a method and apparatus for forming a zinc oxide thin film with high transparency and high conductivity on a surface of a flexible substrate such as plastic without the indispensable requirement of doping impurities. In the method of forming a zinc oxide thin film by reacting oxygen radicals and zinc atoms on a surface of a substrate placed in a film-forming chamber evacuated to a vacuum, the density of crystal defects that are defects of the atomic arrangement of the zinc oxide thin film is controlled by the temperature of the substrate, and the zinc oxide thin film is thereby formed. It is suitable to form the film while maintaining the temperature of the substrate at 400° C. or less to intentionally disturb the regularity of the atomic arrangement of the zinc oxide thin film.

Provided is a zinc oxide-based transparent conductive film comprising zinc atoms, oxygen atoms, and M as defined below, wherein the total number of zinc atoms, oxygen atoms, titanium atoms, gallium atoms, and aluminum atoms accounts for 99% or more of the number of all atoms forming the zinc oxide-based transparent conductive film; the ratio of the total number of titanium atoms, gallium atoms, and aluminum atoms per the total number of zinc atoms, titanium atoms, gallium atoms, and aluminum atoms contained in the film ((number of titanium atoms + number of gallium atoms + number of aluminum atoms)/(number of zinc atoms + number of titanium atoms + number of gallium atoms + number of aluminum atoms) x 100)is 1.3% or greater but 2.0% or less; the number of titanium atoms accounts for at least 50% of the total number of titanium atoms, gallium atoms, and aluminum atoms contained in the film; the carrier electron concentration is 3.60 x 1020cm-3 or less, the mobility is 43.0 cm2/Vs or greater and resistivity is 5.00 x 10-4Ω·cm or less. M represents titanium atoms; titanium atoms and gallium atoms; titanium atoms and aluminum atoms; or titanium atoms, gallium atoms, and aluminum atoms.