The invention discloses a halogen-free flame-retardant temperature-resistant polyolefin pyrocondensation material and a preparation scheme thereof. The material is prepared from, by weight, 20-100 parts of linear low-density polyethylene, 10-80 parts of vinyl copolymer, 0.5-5 parts of sensitizer, 5-20 parts of silicone flame retardant, 5-50 parts of inorganic flame retardant, 5-40 parts of phosphorus-nitrogen containing flame retardant, 1-5 parts of antioxidant, 1-5 parts of light stabilizer and 1-20 parts of smoke restraining agent. The halogen-free flame-retardant temperature-resistant polyolefin pyrocondensation material obtained through the preparation method can reach the high temperature resistant level of 150 DEG C or higher, is good in combustion resistant effect, can not release harmful gas, is not prone to spontaneous combustion, reduces potential safety hazards, is low in cost and high in cost performance, and can be widely applied to the fields of locomotives, aviation, electrons, ships, nuclear power, the war industry and the like.