30results about How to "Small ionic radius" patented technology

The invention provides a multi-element stable zirconium oxide corrosion-resistant thermal barrier coating material which is prepared by performing mixed ball milling on a main component and stabilizer, wherein the main component is ZrO2; the stabilizer is a mixture of Nb2O5, TiO2 and rare metal oxide; the mol ratio of the Nb2O5 to the TiO2 to the rare metal oxide to the ZrO2 in the multi-element stable zirconium oxide corrosion-resistant thermal barrier coating material is x:1.5x:x:(100-3.5x), and 3<=x<=7; and the rare metal oxide is Lu2O3 or In2O3. The multi-element stable zirconium oxide corrosion-resistant thermal barrier coating material provided by the invention has excellent Na2SO4-V2O5 molten salt corrosion resistance and excellent calcium / magnesium / aluminum silicate molten glass corrosion resistance.

The invention discloses a color changing method of an artificial sapphire crystal. According to the method disclosed by the invention, coloring ions are dispersed into the artificial sapphire crystal through a relatively low temprature heat treatment technology, so that the color and the transparency of the sapphire crystal are improved. When the sapphire crystal treated by the method disclosed by the invention, colorless sapphire crystals can be changed into crystals with a plurality of colors, the color and luster are uniform and the transparency is better; According to the method, the treatment process is simple and equipment is simple, and the pollution to the environment is avoided. The ornamental value and the market economic value of sapphires treated by the method can be greatly improved.

The invention belongs to the technical field of nanometer materials, and in particular relates to a composite material, a preparation method thereof and a quantum dot light-emitting diode. The composite material includes quantum dots and silver ethylenediamine tetraacetate combined on the surface of the quantum dots; wherein, silver ions in the silver ethylenediamine tetraacetate combine with anions on the surface of the quantum dots. In the composite material, the surface plasmon resonance effect of silver on the surface of the quantum dot can induce local electromagnetic field enhancement, thereby increasing the light output coupling of the quantum dot and the recombination luminescence rate, and the composite material is used for the quantum dot luminescence of the quantum dot light-emitting diode layer, which can effectively improve the luminous efficiency of the device, thereby improving the performance of the device.

The invention discloses a fluorine-free slagging agent. Bauxite is taken as a main raw material, silica, a fluorine-free iron-containing compound and quicklime are taken as auxiliary materials, and the content of each of effective ingredients of the bauxite is controlled within the following range through the auxiliary materials: Al2O3 accounts for 43-50% of the weight of the fluorine-free slagging agent, SiO2 accounts for 11-13% of the weight of the fluorine-free slagging agent, Fe2O3 accounts for 15-20% of the weight of the fluorine-free slagging agent and CaO accounts for 2-4% of the weight of the fluorine-free slagging agent. The fluorine-free slagging agent disclosed by the invention can solve the harm to an environment caused by a fluorine-containing slagging agent; when the fluorine-free slagging agent is actually used, no slag blocks exist in poured furnace slag, the slag flows, the furnace slag at an end point has no phenomenon of returning to dry state, the slag flow of the poured slag has no iron openwork, and when the slag is poured, the amount of molten iron entrained in the slag is small; and compared with the conventional fluorine-containing slagging agent, by using the fluorine-free slagging agent disclosed by the invention, consumed steel and iron material per ton of steel can be reduced by 4-5kg / t, and the fluorine-free slagging agent is more environment-friendly.

The invention relates to a cathode material and a preparation method thereof, particularly a moderate-temperature solid oxide fuel battery doped double-perovskit-structure cathode material and a preparation method thereof. The invention aims to solve the problem that the catalytic oxygen reduction reaction capacity of the existing solid oxide fuel battery cathode material La1-xSrxMnO3 acutely reduces under moderate temperature conditions. The moderate-temperature solid oxide fuel battery doped double-perovskit-structure cathode material is an alkaline earth element Sr-doped double-perovskite powder material, and the chemical formula is EuBa1-xSrxCo2O5+delta. The method comprises the following steps: 1. weighing materials according to the chemical formula EuBa1-xSrxCo2O5+delta; 2. grinding to obtain a mixture; and 3. calcining to obtain the alkaline earth element Sr-doped double-perovskite powder material of which the chemical formula is EuBa1-xSrxCo2O5+delta. The invention is mainly used for preparing the moderate-temperature solid oxide fuel battery doped double-perovskit-structure cathode material.

The invention belongs to the technical field of preparation of electrochemical sensors, and specifically discloses an electrochemical sensor with self-cleaning ability, including an electrode core and a new composite material based on MTOF (M refers to doped metal elements), and the composite material is attached to on the surface of the electrode core. The preparation method of the sensor is simple, time-saving, low-cost, and environmentally friendly, especially the polymer and the residue of the detected substance attached to the surface of the electrode core after detection can be oxidized under the conditions of ultraviolet light and visible light. The regeneration and self-cleaning effect of the electrochemical sensor under visible light can be achieved. The electrochemical sensing platform regenerated under visible light not only reduces the cumbersome procedures of electrode grinding and modification, but also saves the cost of modification materials, and the descaling and regeneration of electrodes prolongs the service life of electrodes. It is used for the simultaneous detection of environmental pollutants hydroquinone and catechol, with simple operation, good selectivity, high sensitivity and low detection limit.

The invention discloses a method for hydrogenation regeneration of waste lubricating oil. The method comprises the following steps: (1) distilling the pretreated raw material waste lubricating oil; (2) putting the distilled lubricating oil fraction in step (1) into a protective agent reactor for reaction; (3) distilling the step (2) ) The reacted product enters a hydrogenation reactor equipped with a hydrorefining catalyst for reaction to obtain a lubricating oil base oil. The method of the invention treats the waste lubricating oil to produce the lubricating oil base oil meeting the standard.

The invention provides a multi-component stable thermal-corrosion-resistant zirconia coat material. The coat material is obtained through mixing a main agent with a stabilizer and carrying out ball milling, the main agent is ZrO2, the stabilizer is a mixture of Ta2O5, In2O3, Al2O3 and TiO2, the molar ratio of Ta2O5: In2O3: Al2O3: TiO2: ZrO2 in the multi-component stable thermal-corrosion-resistant zirconia coat material is x:x:x:x:(100-4x), and x is not greater than 4 and not lower than 2. Tetragonal phase ZrO2 is finally obtained through adopting Ta2O5, In2O3, Al2O3 and TiO2 as the stabilizer to stabilize ZrO2 in the invention. The multi-component stable thermal-corrosion-resistant zirconia coat material has an excellent Na2SO4-V2O5 molten salt corrosion resistance, and an excellent calcium magnesium aluminosilicate molten glass corrosion resistance.

The invention relates to a remanufactured electric porcelain material and a manufacturing method thereof by recycling existing electric porcelain waste materials. There is an impurity problem in the reuse of the waste generated in the manufacturing process of electric porcelain products. The present invention weighs 50-73 parts of electric porcelain waste, 15-25 parts of bauxite, 3-17 parts of clay, 1-8 parts of potassium feldspar, 0.5-2 parts of zinc oxide, and 1-1.5 parts of fluorite to form a mixed composition; According to the weight ratio of composition: alumina ball stone: water = 1:1.5:1, the composition, alumina ball stone and water are mixed for ball milling until the balance of the million-hole sieve is less than 0.2%; the raw materials are filtered mud, The mud is practiced and aged for 48 hours, then shaped, dried, glazed, and finally fired at a temperature of 1200-1250°C. The present invention adds zinc oxide and fluorite to the formula for reusing electric porcelain waste to form a low-melting substance with impurities at high temperature, improves sintering performance, and promotes the formation of mullite crystal phase, which not only eliminates the influence of impurities, but also improves Improve the porcelain mechanical strength and hot and cold abrupt change.

The invention discloses a method for recycling stainless steel pickling waste sulfuric acid solution, which specifically comprises the following steps: (1) pretreating stainless steel pickling waste sulfuric acid, and using a filter of 1 micron level to fine filter to remove fine particle impurities to obtain the pretreated treatment fluid. (2) Separation and recovery of sulfuric acid and metal salt solution are performed on the pretreatment solution with periodic reverse pulse power supply diffusion dialysis-electrodialyzer to obtain recovered acid and raffinate respectively. (3) Recover the acid and return it to the production line of the workshop for reuse; add appropriate amount of sodium phosphate and alkaline agent to the raffinate to remove heavy metal impurities such as chromium, and then oxidize to prepare the water treatment agent polyferric sulfate. The method of the invention utilizes a periodic reverse pulse power supply diffusion dialysis-electrodialyzer to realize high-efficiency separation of acid and metal ions. The technical method has low operating costs, fully recycles resources, and has good economic and environmental benefits.